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Core-shell nanostructured organic redox polymer cathodes with superior performance

  • Core-shell nanoparticles stabilized by a cationic surfactant are prepared from the poly(2,2,6,6-tetra-methylpiperidinyloxy-4-yl methacrylate) redox polymer. The nanoparticles are further self-assembled with negatively charged reduced graphene oxide nanosheets and negatively charged mull-walled carbon nanotubes. This results in the formation of a free-standing cathode with a layered nanostructure and a high content of redox polymer that exhibits 100% utilization of the active substance with a measured capacity as high as 105 mAh/g based on the whole weight of the electrode.

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Author details:He Jia, Ting Quan, Xuelian Liu, Lu Bai, Jiande Wang, Fadoi Boujioui, Ran Ye, Alexandru Vald, Yan LuORCiDGND, Jean-Francois GohyORCiD
DOI:https://doi.org/10.1016/j.nanoen.2019.103949
ISSN:2211-2855
ISSN:2211-3282
Title of parent work (English):Nano Energy
Publisher:Elsevier
Place of publishing:Amsterdam
Publication type:Article
Language:English
Year of first publication:2019
Publication year:2019
Release date:2020/11/04
Tag:Energy storage; Lithium ion battery; Nanostructured; Organic electrode; Redox polymer
Volume:64
Number of pages:9
Funding institution:Service Public de Wallonie [SPW-DG06, 1318146]; CfB [14/19-057]
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
DDC classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Peer review:Referiert
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