First examples of organosilica-based ionogels
- The article describes the synthesis and properties of new ionogels for ion transport. A new preparation process using an organic linker, bis(3-(trimethoxysilyl) propyl) amine (BTMSPA), yields stable organosilica matrix materials. The second ionogel component, the ionic liquid 1-methyl-3-(4-sulfobutyl) imidazolium 4-methylbenzenesulfonate, [BmimSO(3)H][PTS], can easily be prepared with near-quantitative yields. [BmimSO(3)H][PTS] is the proton conducting species in the ionogel. By combining the stable organosilica matrix with the sulfonated ionic liquid, mechanically stable, and highly conductive ionogels with application potential in sensors or fuel cells can be prepared.
| Author details: | Andreas TaubertORCiDGND, Ruben Löbbicke, Barbara Kirchner, Fabrice LerouxORCiD |
|---|---|
| DOI: | https://doi.org/10.3762/bjnano.8.77 |
| ISSN: | 2190-4286 |
| Pubmed ID: | https://pubmed.ncbi.nlm.nih.gov/28487817 |
| Title of parent work (English): | Beilstein journal of nanotechnology |
| Subtitle (English): | synthesis and electrochemical behavior |
| Publisher: | Beilstein-Institut zur Förderung der Chemischen Wissenschaften |
| Place of publishing: | Frankfurt, Main |
| Publication type: | Article |
| Language: | English |
| Date of first publication: | 2017/03/29 |
| Publication year: | 2017 |
| Release date: | 2022/06/13 |
| Tag: | ionic liquids; ionogels; organosilica; proton conductivity |
| Volume: | 8 |
| Number of pages: | 16 |
| First page: | 736 |
| Last Page: | 751 |
| Funding institution: | University of Potsdam; Max-Planck Institute for Colloids Interfaces; DFG [TA571/2-1, TA571/3-1, TA571/13-1, KI 768/12-1, DFG SPP 1708]; COST [MP1202] |
| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
| DDC classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Peer review: | Referiert |
