Amino acid-derived N-heterocyclic carbene palladium complexes for aqueous phase Suzuki-Miyaura couplings
- In this work, three ligands produced from amino acids were synthesized and used to produce five bis- and PEPPSI-type palladium-NHC complexes using a novel synthesis route from sustainable starting materials. Three of these complexes were used as precatalysts in the aqueous-phase Suzuki-Miyaura coupling of various substrates displaying high activity. TEM and mercury poisoning experiments provide evidence for Pd-nanoparticle formation stabilized in water.
| Author details: | Elliot Steeples, Alexandra Kelling, Uwe SchildeORCiDGND, Davide Esposito |
|---|---|
| DOI: | https://doi.org/10.1039/c5nj03337c |
| ISSN: | 1144-0546 |
| ISSN: | 1369-9261 |
| Title of parent work (English): | New journal of chemistry |
| Publisher: | Royal Society of Chemistry |
| Place of publishing: | Cambridge |
| Publication type: | Article |
| Language: | English |
| Year of first publication: | 2016 |
| Publication year: | 2016 |
| Release date: | 2020/03/22 |
| Volume: | 40 |
| Number of pages: | 9 |
| First page: | 4922 |
| Last Page: | 4930 |
| Funding institution: | Max-Planck Society |
| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
| Peer review: | Referiert |
