Epoxidized 1,4-polymyrcene
- 1,4-Polymyrcene was synthesized by anionic polymerization and epoxidized using meta-chloroperbenzoic acid. Samples with different degrees of epoxidation (25%, 49%, 74%, and 98%) were prepared and examined according to their chemical and thermal properties. Epoxidation was found to increase the glass transition temperature (T-g = 14 degrees C for the 98% epoxidized 1,4-polymyrcene) as well as the shelf live (>10 months). The trisubstituted epoxide groups were remarkably stable against nucleophiles under basic conditions but cross-linked or hydrolyzed in the presence of an acid. Also, highly epoxidized 1,4-polymyrcene readily cross-linked upon annealing at 260 degrees C to produce an epoxy resin.
| Verfasserangaben: | Aleksandar MaticGND, Andreas HessORCiDGND, Dirk SchanzenbachORCiD, Helmut SchlaadORCiDGND |
|---|---|
| DOI: | https://doi.org/10.1039/c9py01783f |
| ISSN: | 1759-9954 |
| ISSN: | 1759-9962 |
| Titel des übergeordneten Werks (Englisch): | Polymer chemistry |
| Verlag: | Royal Society of Chemistry |
| Verlagsort: | Cambridge |
| Publikationstyp: | Wissenschaftlicher Artikel |
| Sprache: | Englisch |
| Datum der Erstveröffentlichung: | 02.01.2020 |
| Erscheinungsjahr: | 2020 |
| Datum der Freischaltung: | 16.01.2023 |
| Freies Schlagwort / Tag: | comb poly(beta-myrcene)-graft-poly(l-lactide) copolymers; epoxidation; myrcen; polymerization; thermoplastic elastomer synthesis |
| Band: | 11 |
| Ausgabe: | 7 |
| Seitenanzahl: | 5 |
| Erste Seite: | 1364 |
| Letzte Seite: | 1368 |
| Fördernde Institution: | Zentrales Innovationsprogramm Mittelstand (ZIM) of the German Federal; Ministry for Economic Affairs and Energy (BMWi) [ZF4189301SL5] |
| Organisationseinheiten: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
| DDC-Klassifikation: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Peer Review: | Referiert |
