Assisted tandem catalytic RCM-aromatization in the synthesis of pyrroles and furans
- An assisted tandem catalytic transformation of diallyl amines and diallyl ethers into N-aryl pyrroles and furans, respectively, is described. The sequence relies on ring closing metathesis followed by dehydrogenation of the initially formed dihydropyrroles and dihydrofurans. Both steps are Ru-catalyzed, but the sequence requires only one precatalyst, because conversion of the metathesis catalyst into the dehydrogenation catalyst is achieved in situ, triggered by the oxidant tert-butyl hydroperoxide.
| Author details: | Bernd SchmidtORCiDGND, Stefan Krehl, Eric Jablowski |
|---|---|
| DOI: | https://doi.org/10.1039/c2ob25543j |
| ISSN: | 1477-0520 |
| Title of parent work (English): | Organic & biomolecular chemistry : an international journal of synthetic, physical and biomolecular organic chemistry |
| Publisher: | Royal Society of Chemistry |
| Place of publishing: | Cambridge |
| Publication type: | Article |
| Language: | English |
| Year of first publication: | 2012 |
| Publication year: | 2012 |
| Release date: | 2017/03/26 |
| Volume: | 10 |
| Issue: | 26 |
| Number of pages: | 12 |
| First page: | 5119 |
| Last Page: | 5130 |
| Funding institution: | Deutsche Forschungsgemeinschaft (DFG) [Schm 1095/6] |
| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
| Peer review: | Referiert |
