Ordered polyelectrolyte "Multilayers". 7. Hybrid films self-assembled from fluorescent and smectogenic poly(diallylammonium) salts and delaminated clay
- Homopolymers were prepared from diallylammonium monomers bearing 4-methylcoumarin and 4-cyanobiphenyl as fluorescent and mesogenic side groups, as well as their copolymers with diallyldimethylammonium chloride (DADMAC). Organic-inorganic hybrid films were electrostatically self-assembled via the layer-by-layer technique on silicon wafers and quartz plates from the chromophore-bearing polymers and an exfoliated synthetic hectorite. Photophysical studies performed in solution as well as in the self-assembled films demonstrated only a weak tendency for aggregation of the chromophores in the macromolecules. Moreover, assemblies made from the polymers carrying the cyanobiphenyl mesogen were found to exhibit a pronounced internal order
Author details: | F Rullens, Pascal Y. Vuillaume, Alain Moussa, Jean-Louis Habib-Jiwan, André LaschewskyORCiDGND |
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URL: | http://pubs.acs.org/doi/full/10.1021/cm060209x |
DOI: | https://doi.org/10.1021/Cm060209x |
Publication type: | Article |
Language: | English |
Year of first publication: | 2006 |
Publication year: | 2006 |
Release date: | 2017/03/25 |
Source: | Chemistry of materials. - 18 (2006), 13, S. 3078 - 3087 |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
Peer review: | Referiert |