Cellulose-based polyacetals by direct and sensitized photocationic ring-opening polymerization of levoglucosenyl methyl ether
- This study aims to explore the photoinitiated cationic ring-opening polymerization of levoglucosenyl methyl ether (LGME), a chemical obtained from the most abundant biomass - cellulose. Direct and sensitized photopolymerizations of LGME using photoinitiators acting at the near UV or visible range in conjunction with diphenyliodonium hexafluoroantimonate (DPI) yielded unsaturated polyacetals with varying molar masses and distributions.
Author details: | Kerem Kaya, Tapas DebsharmaORCiDGND, Helmut SchlaadORCiDGND, Yusuf YagciORCiD |
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DOI: | https://doi.org/10.1039/d0py01307b |
ISSN: | 1759-9954 |
ISSN: | 1759-9962 |
Title of parent work (English): | Polymer Chemistry |
Publisher: | Royal Society of Chemistry |
Place of publishing: | Cambridge |
Publication type: | Article |
Language: | English |
Date of first publication: | 2020/10/19 |
Publication year: | 2020 |
Release date: | 2024/01/12 |
Volume: | 11 |
Issue: | 43 |
Number of pages: | 6 |
First page: | 6884 |
Last Page: | 6889 |
Funding institution: | Alexander von Humboldt Foundation through a Humboldt Research; AwardAlexander von Humboldt Foundation |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
DDC classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Peer review: | Referiert |