Olefin metathesis and isomerization : from undesired side reactions to useful synthetic methodology
- Conversion of ruthenium carbene complexes to ruthenium hydride complexes by organometallic transformations in situ opens up interesting synthetic perspectives. In this account the use of Grubbs' catalyst to synthesize pent-4- enals selectively from diallyl- and allyl homoallyl ethers and scope and limitations of a Tandem RCM-isomerization sequence for the synthesis of cyclic enol ethers are discussed. (c) 2006 Elsevier B.V. All rights reserved
| Author details: | Bernd SchmidtORCiDGND |
|---|---|
| URL: | http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TGM-4JT9C6D- 2&_user=1584062&_coverDate=07%2F19%2F2006&_rdoc=1&_fmt=high&_orig=gateway&_origin=gateway&_sort=d&_docanchor=&view=c&_sea rchStr |
| DOI: | https://doi.org/10.1016/j.molcata.2006.03.026 |
| Publication type: | Article |
| Language: | English |
| Year of first publication: | 2006 |
| Publication year: | 2006 |
| Release date: | 2017/03/25 |
| Source: | Journal of molecular catalysis a-chemical. - 254 (2006), 1-2, S. 53 - 57 |
| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
| Peer review: | Referiert |
