Stimuli responsive amphiphilic block copolymers for aqueous media synthesised via reversible addition fragmentation chain transfer polymerisation (RAFT)
- A series of RAFT agents was synthesised, and used to prepare various ionic. non-ionic and zwitterionic water- soluble polymers, in organic as well as in aqueous media. The RAFT process proved to be a powerful method to prepare functional polymers of complex structure. such as amphiphilic diblock and triblock copolymers. This includes polymers containing one or even two stimuli-sensitive hydrophilic blocks. Switching the hydrophilic character of a single or of several blocks by changing the PH, the temperature or the salt content demonstrated the variability of the molecular designs suited for stimuli-sensitive polymeric amphiphiles, and exemplified the concept of multiple-sensitive systems. (c) 2005 Published by Elsevier Ltd
Author details: | Murat Mertoglu, Sebastien GarnierGND, André LaschewskyORCiDGND, Katja SkrabaniaGND, J. Storsberg |
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ISSN: | 0032-3861 |
Publication type: | Article |
Language: | English |
Year of first publication: | 2005 |
Publication year: | 2005 |
Release date: | 2017/03/24 |
Source: | Polymer. - ISSN 0032-3861. - 46 (2005), 18, S. 7726 - 7740 |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
Peer review: | Referiert |