Microwave-Promoted Deprenylation: Prenyl Ether as a Thermolabile Phenol Protecting Group
- para-Substituted aryl prenyl ethers undergo a deprenylation reaction upon microwave irradiation. This offers the opportunity to use a prenyl ether as a thermolabile protecting group in the synthesis of natural products with a chromone structure, which proceeds via a tandem deprenylation/6-endo-cyclization sequence.
| Author details: | Bernd SchmidtORCiDGND, Martin Riemer |
|---|---|
| DOI: | https://doi.org/10.1055/s-0035-1561366 |
| ISSN: | 0039-7881 |
| ISSN: | 1437-210X |
| Title of parent work (English): | Synthesis |
| Publisher: | Thieme |
| Place of publishing: | Stuttgart |
| Publication type: | Article |
| Language: | English |
| Year of first publication: | 2016 |
| Publication year: | 2016 |
| Release date: | 2020/03/22 |
| Tag: | Claisen rearrangement; chromenes; microwave irradiation; phenols; protecting groups |
| Volume: | 48 |
| Number of pages: | 8 |
| First page: | 1399 |
| Last Page: | 1406 |
| Funding institution: | Equal Opportunities Fund of the Faculty of Science, Universitat Potsdam |
| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
| Peer review: | Referiert |
