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Microwave-Promoted Deprenylation: Prenyl Ether as a Thermolabile Phenol Protecting Group
- para-Substituted aryl prenyl ethers undergo a deprenylation reaction upon microwave irradiation. This offers the opportunity to use a prenyl ether as a thermolabile protecting group in the synthesis of natural products with a chromone structure, which proceeds via a tandem deprenylation/6-endo-cyclization sequence.
Author details: | Bernd SchmidtORCiDGND, Martin Riemer |
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DOI: | https://doi.org/10.1055/s-0035-1561366 |
ISSN: | 0039-7881 |
ISSN: | 1437-210X |
Title of parent work (English): | Synthesis |
Publisher: | Thieme |
Place of publishing: | Stuttgart |
Publication type: | Article |
Language: | English |
Year of first publication: | 2016 |
Publication year: | 2016 |
Release date: | 2020/03/22 |
Tag: | Claisen rearrangement; chromenes; microwave irradiation; phenols; protecting groups |
Volume: | 48 |
Number of pages: | 8 |
First page: | 1399 |
Last Page: | 1406 |
Funding institution: | Equal Opportunities Fund of the Faculty of Science, Universitat Potsdam |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
Peer review: | Referiert |