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Optical monitoring of chemical processes in turbid biogenic liquid dispersions by Photon Density Wave spectroscopy

  • In turbid biogenic liquid material, like blood or milk, quantitative optical analysis is often strongly hindered by multiple light scattering resulting from cells, particles, or droplets. Here, optical attenuation is caused by losses due to absorption as well as scattering of light. Fiber-based Photon Density Wave (PDW) spectroscopy is a very promising method for the precise measurement of the optical properties of such materials. They are expressed as absorption and reduced scattering coefficients (mu (a) and mu (s)', respectively) and are linked to the chemical composition and physical properties of the sample. As a process analytical technology, PDW spectroscopy can sense chemical and/or physical processes within such turbid biogenic liquids, providing new scientific insight and process understanding. Here, for the first time, several bioprocesses are analyzed by PDW spectroscopy and the resulting optical coefficients are discussed with respect to established mechanistic models of the chosen processes. As model systems, enzymaticIn turbid biogenic liquid material, like blood or milk, quantitative optical analysis is often strongly hindered by multiple light scattering resulting from cells, particles, or droplets. Here, optical attenuation is caused by losses due to absorption as well as scattering of light. Fiber-based Photon Density Wave (PDW) spectroscopy is a very promising method for the precise measurement of the optical properties of such materials. They are expressed as absorption and reduced scattering coefficients (mu (a) and mu (s)', respectively) and are linked to the chemical composition and physical properties of the sample. As a process analytical technology, PDW spectroscopy can sense chemical and/or physical processes within such turbid biogenic liquids, providing new scientific insight and process understanding. Here, for the first time, several bioprocesses are analyzed by PDW spectroscopy and the resulting optical coefficients are discussed with respect to established mechanistic models of the chosen processes. As model systems, enzymatic casein coagulation in milk, temperature-induced starch hydrolysis in beer mash, and oxy- as well as deoxygenation of human donor blood were investigated by PDW spectroscopy. The findings indicate that also for very complex biomaterials (i.e., not well-defined model materials like monodisperse polymer dispersions), obtained optical coefficients allow for the assessment of a structure/process relationship and thus for a new analytical access to biogenic liquid material. This is of special relevance as PDW spectroscopy data are obtained without any dilution or calibration, as often found in conventional spectroscopic approaches.zeige mehrzeige weniger

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Metadaten
Verfasserangaben:Roland HassORCiDGND, Dorit Munzke, Salome Vargas Ruiz, Johannes Tippmann, Oliver ReichGND
DOI:https://doi.org/10.1007/s00216-015-8513-9
ISSN:1618-2642
ISSN:1618-2650
Pubmed ID:https://pubmed.ncbi.nlm.nih.gov/25725578
Titel des übergeordneten Werks (Englisch):Analytical & bioanalytical chemistry
Verlag:Springer
Verlagsort:Heidelberg
Publikationstyp:Wissenschaftlicher Artikel
Sprache:Englisch
Jahr der Erstveröffentlichung:2015
Erscheinungsjahr:2015
Datum der Freischaltung:27.03.2017
Freies Schlagwort / Tag:Beer mashing; Enzymatic milk coagulation; Human donor blood; Light scattering; Photon Density Wave spectroscopy; Process analytical technology
Band:407
Ausgabe:10
Seitenanzahl:12
Erste Seite:2791
Letzte Seite:2802
Fördernde Institution:German Federal Ministry of Economics and Technology [16IN0418]; German Federal Ministry of Education and Research [03Z2AN12]
Organisationseinheiten:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer Review:Referiert
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