Discrete Polymetallic Arrangements of Ag-I and Cu-I Ions Based on Multiple Bridging Phosphane Ligands and pi-pi Interactions
- A simple and straightforward approach to new polymetallic Ag-I and Cu-I supramolecules is presented. The reaction of N,P,N,P,N ligand 2 with Ag-I ions affords a trimetallic complex bearing a triangular Ag-3 core; metallophilic interactions are stabilized by ligands that display a multiple bridging coordination mode as 10-electron donors. Heteroleptic polymetallic Ag-I and Cu-I complexes based on ligand 2 and the 1,12-diazaperylene (dape) ligand are obtained by an alternative molecular organization of the polymetallic arrays compared to that in homoleptic complexes of ligand 2.
Author details: | Bianca Attenberger, Mehdi El Sayed Moussa, Thomas Martin BrietzkeGND, Volodimir Vreshch, Hans-Jürgen HoldtORCiD, Christophe Lescop, Manfred Scheer |
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DOI: | https://doi.org/10.1002/ejic.201500445 |
ISSN: | 1434-1948 |
ISSN: | 1099-0682 |
Title of parent work (English): | European journal of inorganic chemistry : a journal of ChemPubSoc Europe |
Publisher: | Wiley-VCH |
Place of publishing: | Weinheim |
Publication type: | Article |
Language: | English |
Year of first publication: | 2015 |
Publication year: | 2015 |
Release date: | 2017/03/27 |
Tag: | Heterocycles; N; P ligands; Pi interactions; Polyaromatic fragments; Supramolecular chemistry |
Issue: | 18 |
Number of pages: | 5 |
First page: | 2934 |
Last Page: | 2938 |
Funding institution: | National de la Recherche Scientifique (CNRS); Ministere des Affaires Etrangeres et Europeennes; Agence Nationale de la Recherche (ANR) [ANR-12-BS07-0004-METALHEL-01]; Campus France; Deutsche Forschungsgemeinschaft (DFG); COST action PhoSciNet for short-term scientific mission (STSM) grants; Alexander von Humboldt Foundation |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
Peer review: | Referiert |