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In this work we present spectra of all gamma-ray burst (GRB) afterglows that have been promptly observed with the X-shooter spectrograph until 31/03/2017. In total, we have obtained spectroscopic observations of 103 individual GRBs observed within 48 hours of the GRB trigger. Redshifts have been measured for 97 per cent of these, covering a redshift range from 0.059 to 7.84. Based on a set of observational selection criteria that minimise biases with regards to intrinsic properties of the GRBs, the follow-up effort has been focused on producing a homogeneously selected sample of 93 afterglow spectra for GRBs discovered by the Swift satellite. We here provide a public release of all the reduced spectra, including continuum estimates and telluric absorption corrections. For completeness, we also provide reductions for the 18 late-time observations of the underlying host galaxies. We provide an assessment of the degree of completeness with respect to the parent GRB population, in terms of the X-ray properties of the bursts in the sample and find that the sample presented here is representative of the full Swift sample. We have constrained the fraction of dark bursts to be <28 per cent and confirm previous results that higher optical darkness is correlated with increased X-ray absorption. For the 42 bursts for which it is possible, we have provided a measurement of the neutral hydrogen column density, increasing the total number of published HI column density measurements by similar to 33 per cent. This dataset provides a unique resource to study the ISM across cosmic time, from the local progenitor surroundings to the intervening Universe.
We investigate the NV absorption signal along the line of sight of background quasars, in order to test the robustness of the use of this ion as the criterion to select intrinsic (i.e. physically related to the quasar host galaxy) narrow absorption lines (NALs). We build composite spectra from a sample of similar to 1000 CIV absorbers, covering the redshift range 2.55 < z < 4.73, identified in 100 individual sight lines from the XQ-100 Legacy Survey. We detect a statistically significant NV absorption signal only within 5000 km s(-1) of the systemic redshift, z(em). This absorption trough is similar to 15 sigma when only CIV systems with N(CIV) > 10(14) cm(-2) are included in the composite spectrum. This result confirms that NV offers an excellent statistical tool to identify intrinsic systems. We exploit stacks of 11 different ions to show that the gas in proximity to a quasar exhibits a considerably different ionization state with respect to gas in the transverse direction and intervening gas at large velocity separations from the continuum source. Indeed, we find a dearth of cool gas, as traced by low-ionization species and in particular by MgII, in the proximity of the quasar. We compare our findings with the predictions given by a range of CLOUDY ionization models and find that they can be naturally explained by ionization effects of the quasar.