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Beim Resonanzenergietransfer werden Fotonen von einem angeregten Donator über einen Wechselwirkungsabstand auf einen Akzeptor übertragen. Nach der quantenmechanischen Theorie von FÖRSTER kann dieser Abstand mit Hilfe des Überlappungsintegrals von Fluoreszenzspektrum des Donators und Absorp-tionsspektrum des Akzeptors berechnet werden.
Eine andere Möglichkeit der Bestimmung erhält man mit Hilfe von statistischen Modellen, die in einem Überblick zusammengestellt sind. Dabei kann der Abstand durch Auswertung der Löschkurve bestimmt werden.
In dieser Arbeit wird dazu eine weitere statistische Variante der Bestimmung des Wechselwirkungsradius hinzugefügt und an einem Beispiel ausführlich demonstriert.
Beim Resonanzenergietransfer werden Fotonen von einem angeregten Donator über einen Wechselwirkungsabstand auf einen Akzeptor übertragen. Nach der quantenmechanischen Theorie von FÖRSTER kann dieser Abstand mit Hilfe des Überlappungsintegrals von Fluoreszenzspektrum des Donators und Absorp-tionsspektrum des Akzeptors berechnet werden.
Eine andere Möglichkeit der Bestimmung erhält man mit Hilfe von statistischen Modellen, die in einem Überblick zusammengestellt sind. Dabei kann der Abstand durch Auswertung der Löschkurve bestimmt werden.
In dieser Arbeit wird dazu eine weitere statistische Variante der Bestimmung des Wechselwirkungsradius hinzugefügt und an einem Beispiel ausführlich demonstriert.
For the calculation of the work in an irreversible pressure-volume change, we propose approxima-tions, which in contrast to the usual representation in the literature reflect the work performed during expansion and compression symmetrically. The calculations are based on the Reversible-Share-Theorem: Is used the force to overcome for calculating the work, so it captures only the configurational reversible work share.
When azobenzene-modified photosensitive polymer films are irradiated with light interference patterns, topographic variations in the film develop that follow the electric field vector distribution resulting in the formation of surface relief grating (SRG). The exact correspondence of the electric field vector orientation in interference pattern in relation to the presence of local topographic minima or maxima of SRG is in general difficult to determine. In my thesis, we have established a systematic procedure to accomplish the correlation between different interference patterns and the topography of SRG. For this, we devise a new setup combining an atomic force microscope and a two-beam interferometer (IIAFM). With this set-up, it is possible to track the topography change in-situ, while at the same time changing polarization and phase of the impinging interference pattern. To validate our results, we have compared two photosensitive materials named in short as PAZO and trimer. This is the first time that an absolute correspondence between the local distribution of electric field vectors of interference pattern and the local topography of the relief grating could be established exhaustively. In addition, using our IIAFM we found that for a certain polarization combination of two orthogonally polarized interfering beams namely SP (↕, ↔) interference pattern, the topography forms SRG with only half the period of the interference patterns. Exploiting this phenomenon we are able to fabricate surface relief structures below diffraction limit with characteristic features measuring only 140 nm, by using far field optics with a wavelength of 491 nm. We have also probed for the stresses induced during the polymer mass transport by placing an ultra-thin gold film on top (5–30 nm). During irradiation, the metal film not only deforms along with the SRG formation, but ruptures in regular and complex manner. The morphology of the cracks differs strongly depending on the electric field distribution in the interference pattern even when the magnitude and the kinetic of the strain are kept constant. This implies a complex local distribution of the opto-mechanical stress along the topography grating. The neutron reflectivity measurements of the metal/polymer interface indicate the penetration of metal layer within the polymer resulting in the formation of bonding layer that confirms the transduction of light induced stresses in the polymer layer to a metal film.
LCST-type synthetic thermoresponsive polymers can reversibly respond to certain stimuli in aqueous media with a massive change of their physical state. When fluorophores, that are sensitive to such changes, are incorporated into the polymeric structure, the response can be translated into a fluorescence signal. Based on this idea, this thesis presents sensing schemes which transduce the stimuli-induced variations in the solubility of polymer chains with covalently-bound fluorophores into a well-detectable fluorescence output. Benefiting from the principles of different photophysical phenomena, i.e. of fluorescence resonance energy transfer and solvatochromism, such fluorescent copolymers enabled monitoring of stimuli such as the solution temperature and ionic strength, but also of association/disassociation mechanisms with other macromolecules or of biochemical binding events through remarkable changes in their fluorescence properties. For instance, an aqueous ratiometric dual sensor for temperature and salts was developed, relying on the delicate supramolecular assembly of a thermoresponsive copolymer with a thiophene-based conjugated polyelectrolyte. Alternatively, by taking advantage of the sensitivity of solvatochromic fluorophores, an increase in solution temperature or the presence of analytes was signaled as an enhancement of the fluorescence intensity. A simultaneous use of the sensitivity of chains towards the temperature and a specific antibody allowed monitoring of more complex phenomena such as competitive binding of analytes. The use of different thermoresponsive polymers, namely poly(N-isopropylacrylamide) and poly(meth)acrylates bearing oligo(ethylene glycol) side chains, revealed that the responsive polymers differed widely in their ability to perform a particular sensing function. In order to address questions regarding the impact of the chemical structure of the host polymer on the sensing performance, the macromolecular assembly behavior below and above the phase transition temperature was evaluated by a combination of fluorescence and light scattering methods. It was found that although the temperature-triggered changes in the macroscopic absorption characteristics were similar for these polymers, properties such as the degree of hydration or the extent of interchain aggregations differed substantially. Therefore, in addition to the demonstration of strategies for fluorescence-based sensing with thermoresponsive polymers, this work highlights the role of the chemical structure of the two popular thermoresponsive polymers on the fluorescence response. The results are fundamentally important for the rational choice of polymeric materials for a specific sensing strategy.
Wir schlagen einen allgemein anwendbaren Algorithmus vor, der unter Verwendung des Skalarprodukts von Kraft und Weg zum richtigen Vorzeichen in den Gleichungen für die Arbeit und die Potentielle Energie bei reversiblen Prozessen (Druck-Volumen-Änderung, Dehnung, Elektrostatische Wechselwirkung, Hub)führt. Wir zeigen, dass es dabei möglich ist, systemimmanente oder externe Kräfte zu benutzen. Wir zeigen, dass bei Verwendung von systemimmanenten Kräften das Skalarprodukt mit negativem Vorzeichen anzusetzen ist. Zudem ist es sehr wichtig, nötige Vorzeichenwechsel bei den einzelnen Schritten zu beachten. Wir betonen dies, weil gelegentlich übersehen wird, dass ein Vorzeichenwechsel nötig ist, wenn das Wegdifferential ds durch das Höhendifferential dh beziehungsweise durch das Abstandsdifferential dx oder dr ersetzt werden muss.
Within the course of this thesis, I have investigated the complex interplay between electron and lattice dynamics in nanostructures of perovskite oxides. Femtosecond hard X-ray pulses were utilized to probe the evolution of atomic rearrangement directly, which is driven by ultrafast optical excitation of electrons. The physics of complex materials with a large number of degrees of freedom can be interpreted once the exact fingerprint of ultrafast lattice dynamics in time-resolved X-ray diffraction experiments for a simple model system is well known. The motion of atoms in a crystal can be probed directly and in real-time by femtosecond pulses of hard X-ray radiation in a pump-probe scheme. In order to provide such ultrashort X-ray pulses, I have built up a laser-driven plasma X-ray source. The setup was extended by a stable goniometer, a two-dimensional X-ray detector and a cryogen-free cryostat. The data acquisition routines of the diffractometer for these ultrafast X-ray diffraction experiments were further improved in terms of signal-to-noise ratio and angular resolution. The implementation of a high-speed reciprocal-space mapping technique allowed for a two-dimensional structural analysis with femtosecond temporal resolution. I have studied the ultrafast lattice dynamics, namely the excitation and propagation of coherent phonons, in photoexcited thin films and superlattice structures of the metallic perovskite SrRuO3. Due to the quasi-instantaneous coupling of the lattice to the optically excited electrons in this material a spatially and temporally well-defined thermal stress profile is generated in SrRuO3. This enables understanding the effect of the resulting coherent lattice dynamics in time-resolved X-ray diffraction data in great detail, e.g. the appearance of a transient Bragg peak splitting in both thin films and superlattice structures of SrRuO3. In addition, a comprehensive simulation toolbox to calculate the ultrafast lattice dynamics and the resulting X-ray diffraction response in photoexcited one-dimensional crystalline structures was developed in this thesis work. With the powerful experimental and theoretical framework at hand, I have studied the excitation and propagation of coherent phonons in more complex material systems. In particular, I have revealed strongly localized charge carriers after above-bandgap femtosecond photoexcitation of the prototypical multiferroic BiFeO3, which are the origin of a quasi-instantaneous and spatially inhomogeneous stress that drives coherent phonons in a thin film of the multiferroic. In a structurally imperfect thin film of the ferroelectric Pb(Zr0.2Ti0.8)O3, the ultrafast reciprocal-space mapping technique was applied to follow a purely strain-induced change of mosaicity on a picosecond time scale. These results point to a strong coupling of in- and out-of-plane atomic motion exclusively mediated by structural defects.
Tätigkeitsbericht 1994-2000
(2004)
Das Interdisziplinäre Zentrum für Nichtlineare Dynamik an der Universität Potsdam verbindet theoretisch-methodische Untersuchungen in Mathematik und theoretischer Physik mit einer Vielzahl anderer Wissenschaften und zielt auf eine fruchtbare Wechselwirkung zwischen Theorie und Experiment. Unter Einbezug von Instituten und Großforschungseinrichtungen, die insbesondere im Potsdamer Raum angesiedelt sind, soll sich ein überregional bedeutender Schwerpunkt entwickeln, wie er an keiner anderen deutschen Universität in gleicher Weise interdisziplinär angelegt ist.
A detailed theoretical investigation of the reflection of an atomic de Broglie wave at an evanescent wave mirror is presented. The classical and the semiclassical descriptions of the reflection process are reviewed, and a full wave-mechanical approach based on the analytical soution of the corresponding Schrödinger equation is presented. The phase shift at reflection is calculated exactly and interpreted in terms of instantaneous reflection of the atom at an effective mirror. Besides the semiclassical regime of reflection describable by the WKB method, a pure quantum regime of reflection is identified in the limit where the incident de Broglie wavelength is large compared to the evanescent wave decay length.
A novel atomic beam splitter, using reflection of atoms off an evanescent light wave, is investigated theoretically. The intensity or frequency of the light is modulated in order to create sidebands on the reflected de Broglie wave. The weights and phases of the various sidevands are calculated using three different approaches: the Born approximation, a semiclassical path integral approach, and a numerical solution of the time-dependent Schrdinger equation. We show how this modulated mirror could be used to build practical atomic interferometers.
We present a semiclassical perturbation method for the description of atomic diffraction by a weakly modulated potential. It proceeds in a way similar to the treatment of light diffraction by a thin phase grating, and consists in calculating the atomic wavefunction by means of action integrals along the classical trajectories of the atoms in the absence of the modulated part of the potential. The capabilities and the validity condition of the method are illustrated on the well-known case of atomic diffraction by a Gaussian standing wave. We prove that in this situation the perturbation method is equivalent to the Raman-Nath approximation, and we point out that the usually-considered Raman-Nath validity condition can lead to inaccuracies in the evaluation of the phases of the diffraction amplitudes. The method is also applied to the case of an evanescent wave reflection grating, and an analytical expression for the diffraction pattern at any incidence angle is obtained for the first time. Finally, the application of the method to other situations is briefly discussed.
Das Strahlungsfeld in einem absorbierenden, periodischen Dielektrikum ist kanonisch quantisiert worden. Dabei wurde ein eindimensionales Modell mit punktförmigen Streuern betrachtet, deren Polarisierbarkeit den Kramers-Kronig Relationen gehorcht. Es wurde ein Quantisierungsverfahren nach Knöll, Scheel und Welsch [1] verwendet, das als eine Ergänzung zum mikroskopischen Huttner-Barnett Schema [2] aufgefaßt werden kann und in dem auf der Basis der phänomenologischen Maxwell Gleichungen eine bosonische Rauschpolarisation als die Quelle des Feldes auftritt. Das Problem reduziert sich dabei auf die Bestimmung der klassischenGreens Funktion. Die Kramers-Kronig Relationen der komplexen Polarisierbarkeit der Punktstreuer sichert die korrekte Verknüpfung zwischen Dispersion und Absorption. Der Punktstreuer ist dabei ein idealisiertes Modell, um periodische Hintergrundmedien, denen das Strahlungsfeld ausgesetzt ist, zu beschreiben. Er bedarf jedoch eines Kompromisses, um die entsprechenden Rauschquellen zu konstruieren. Es konnte gezeigt werden, daß der Punktstreuer dasselbe Streuverhalten wie eine dünne Potentialschwelle besitzt und damit die technischen Schwierigkeiten für den Fall eines absorptiven Punktstreuers überwunden werden können. An Hand dieses Beispiels konnte das Quantisierungsschema nach Knöll, Scheel und Welsch auf periodische und absorbierende Strukturen angewendet werden. Es ist bekannt, daß die Bestimmung der Modenstruktur für den Fall der Modenzerlegung des Strahlungsfeldes ein rein klassisches Problem darstellt. Mit Ausnahme des Vakuums ist eine zweckmäßige Modenzerlegung nur dann durchführbar, wenn mit einer reellen Polarisierbarkeit die Absorption vernachlässigt werden kann. Aus den Kramers-Kronig Relationen wird klar, daß solch eine Annahme nur in bestimmten Intervallen des Frequenzspektrums gerechtfertigt werden kann. Es wurde gezeigt, daß auch das quantisierte Strahlungsfeld in Anwesenheit der Punktstreuer in eben solchen Intervallen in Quasimoden entwickelt werden kann, wenn man neue Quasioperatoren als Erzeuger und Vernichter einführt. Die bosonischen Vertauschungsrelationen dieser Operatoren konnten bestätigt werden. Die allgemeine Vertauschungsrelation kanonisch konjugierter Variablen im Sinne der kanonischen Quantisierung kann für das elektrische Feld und das Vektorpotential beibehalten werden. In der Greens Funktion sind sämtliche Informationen über die dispersiven und absorptiven Eigenschaften des Dielektrikums sowie über die räumliche Struktur enthalten. Die wesentlichen Merkmale werden dabei durch den Reflexionskoeffizienten nach Boedecker und Henkel [3] bestimmt, der das Reflexionsverhalten an einem unendlich ausgedehnten Halbraum aus periodisch angeordneten Punktstreuern beschreibt. Mit Hilfe des Transfermatrixformalismus war es möglich einen allgemeinen Zugang zum Reflexionsverhalten zunächst endlicher Strukturen zu erhalten. Die Ausdehnung auf den Halbraum mit Hilfe der Klassifizierung in Untergruppen der Transfermatrizen nach ermöglichte es, den Reflexionskoeffizienten nach Boedecker und Henkel [3] auch geometrisch plausibel zu machen. Ein wesentlicher Aspekt von periodischen Systemen ist die Translationssymmetrie, die im Fall unendlich ausgedehnter, verlustfreier Systeme auf eine ideale Bandstruktur führt. Mit Hilfe der Untergruppenklassifizierung kann im verlustfreien Fall die Geometrie der Anordnung indirekt mit der Bandstruktur verknüpft werden. Es konnte nachgewiesen werden, daß auch der einzelne Punktstreuer immer in einer dieser Untergruppen zu finden ist. Dabei besitzt die Bandstruktur der unendlich periodischen Anordnung dieser Streuer immer eine von der Polarisierbarkeit abhängige Bandkante und eine von der Polarisierbarkeit unabhängige Bandkante. Die Bandstruktur, die mit den verlustbehafteten Feldern einhergeht, ist eine doppelt komplexe. Alternativ zu dieser nur schwer zu interpretierenden Bandstruktur wurden die Feldfluktuationen selektiv nach reellen Frequenzen und Wellenzahlen sondiert. Es zeigt sich, daß Absorption besonders in der Nähe der Bandkanten die Bänder verbreitert. Die Ergebnisse, die mit Hilfe der lokalen Zustandsdichtefunktion gewonnen wurden, konnten dabei bestätigt werden. [1] S. Scheel, L. Knöll and D. G. Welsch, Phys.Rev. A 58, 700 (1998). [2] B. Huttner and S. M. Barnett, Phys. Rev. A 46, 4306 (1992). [3] G. Boedecker and C. Henkel, OPTICS EXPRESS 11, 1590 (2003).
In Allefeld & Kurths [2004], we introduced an approach to multivariate phase synchronization analysis in the form of a Synchronization Cluster Analysis (SCA). A statistical model of a synchronization cluster was described, and an abbreviated instruction on how to apply this model to empirical data was given, while an implementation of the corresponding algorithm was (and is) available from the authors. In this letter, the complete details on how the data analysis algorithm is to be derived from the model are filled in.
In order to investigate the temporal characteristics of cognitive processing, we apply multivariate phase synchronization analysis to event-related potentials. The experimental design combines a semantic incongruity in a sentence context with a physical mismatch (color change). In the ERP average, these result in an N400 component and a P300-like positivity, respectively. The synchronization analysis shows an effect of global desynchronization in the theta band around 288ms after stimulus presentation for the semantic incongruity, while the physical mismatch elicits an increase of global synchronization in the alpha band around 204ms. Both of these effects clearly precede those in the ERP average. Moreover, the delay between synchronization effect and ERP component correlates with the complexity of the cognitive processes.
Phase synchronization analysis, including our recently introduced multivariate approach, is applied to event-related EEG data from an experiment on language processing, following a classic psycholinguistic paradigm. For the two types of experimental manipulation distinct effects in overall synchronization are found; for one of them they can also be localized. The synchronization effects occur earlier than those found by the conventional analysis method, indicating that the new approach provides additional information on the underlying neuronal process.
A method for the multivariate analysis of statistical phase synchronization phenomena in empirical data is presented. A first statistical approach is complemented by a stochastic dynamic model, to result in a data analysis algorithm which can in a specific sense be shown to be a generic multivariate statistical phase synchronization analysis. The method is applied to EEG data from a psychological experiment, obtaining results which indicate the relevance of this method in the context of cognitive science as well as in other fields.
We present different tests for phase synchronization which improve the procedures currently used in the literature. This is accomplished by using a two-samples test setup and by utilizing insights and methods from directional statistics and bootstrap theory. The tests differ in the generality of the situation in which they can be applied as well as in their complexity, including computational cost. A modification of the resampling technique of the bootstrap is introduced, making it possible to fully utilize data from time series.
During the last few years there was a tremendous growth of scientific activities in the fields related to both Physics and Control theory: nonlinear dynamics, micro- and nanotechnologies, self-organization and complexity, etc. New horizons were opened and new exciting applications emerged. Experts with different backgrounds starting to work together need more opportunities for information exchange to improve mutual understanding and cooperation. The Conference "Physics and Control 2007" is the third international conference focusing on the borderland between Physics and Control with emphasis on both theory and applications. With its 2007 address at Potsdam, Germany, the conference is located for the first time outside of Russia. The major goal of the Conference is to bring together researchers from different scientific communities and to gain some general and unified perspectives in the studies of controlled systems in physics, engineering, chemistry, biology and other natural sciences. We hope that the Conference helps experts in control theory to get acquainted with new interesting problems, and helps experts in physics and related fields to know more about ideas and tools from the modern control theory.
The nonlinear interaction of waves excited by the modified two-stream instability (Farley-Buneman instability) is considered. It is found that, during the linear stage of wave growth, the enhanced pressure of the high-frequency part of the waves locally generates a ponderomotive force. This force acts on the plasma particles and redistributes them. Thus an additional electrostatic polarization field occurs, which influences the low-frequency part of the waves. Then, the low-frequency waves also cause a redistribution of the high-frequency waves. In the paper, a self-consistent system of equations is obtained, which describes the nonlinear interaction of the waves. It is shown that the considered mechanism of wave interaction causes a nonlinear stabilization of the high-frequency waves’ growth and a formation of local density structures of the charged particles. The density modifications of the charged particles during the non-linear stage of wave growth and the possible interval of aspect angles of the high-frequency waves are estimated.
Contents: 1 Introduction 2 Formation and destruction of sporadic E-layers 3 Temporal variations of parameters of sporadic E-layers during earthquake preparation 3.1 Temporal variations of fbEs with time-scales of a few hours 3.2 Study of fbEs variations with characteristic time-scales of 0.5-3 hours 3.3 Variations of the parameters of sporadic E-layers with characteristic time-scales of 15-45 minutes 3.4 Sporadic E-layer variations with characteristic time-scales of 2-15 minutes 4 On the spatial scales of sporadic E-layer disturbances related to seismic activity 5 Complex experimental researches of the ionosphere, electromagnetic noise and the geomagnetic field 5.1 Ionospheric and electromagnetic phenomena of the Kayraccum earthquake in 1985 5.2 Comparison of anomalies with characteristic time-scales of 2-3 hours for ionospheric E- and F-layers, and temporal behaviour of electromagnetic noise emission intensity 5.3 Night airglow emissions in the E-region before earthquakes and sporadic E-layer variations 6 Physical models of lithosphere-ionosphere links 6.1 Lithosphere-ionosphere links due to AGW 6.2 Electromagnetic models for the lithosphere-ionosphere coupling 6.3 Sporadic E-layers as current generators 7 Discussion and conclusion
In single photon emission computed tomography (SPECT) one is interested in reconstructing the activity distribution f of some radiopharmaceutical. The data gathered suffer from attenuation due to the tissue density µ. Each imaged slice incorporates noisy sample values of the nonlinear attenuated Radon transform (formular at this place in the original abstract) Traditional theory for SPECT reconstruction treats µ as a known parameter. In practical applications, however, µ is not known, but either crudely estimated, determined in costly additional measurements or plainly neglected. We demonstrate that an approximation of both f and µ from SPECT data alone is feasible, leading to quantitatively more accurate SPECT images. The result is based on nonlinear Tikhonov regularization techniques for parameter estimation problems in differential equations combined with Gauss-Newton-CG minimization.
The aim of this paper is to describe an efficient strategy for descritizing ill-posed linear operator equations of the first kind: we consider Tikhonov-Phillips-regularization χ^δ α = (a * a + α I)^-1 A * y ^δ with a finite dimensional approximation A n instead of A. We propose a sparse matrix structure which still leads to optimal convergences rates but requires substantially less scalar products for computing A n compared with standard methods.
The determination of the atmospheric aerosol size distribution is an inverse illposed problem. The shape and the material composition of the air-carried particles are two substantial model parameters. Present evaluation algorithms only used an approximation with spherical homogeneous particles. In this paper we propose a new numerically efficient recursive algorithm for inhomogeneous multilayered coated and absorbing particles. Numerical results of real existing particles show that the influence of the two parameters on the model is very important and therefore cannot be ignored.
We have numerically studied the bifurcations and transition to chaos in a two-dimensional fluid for varying values of the Reynolds number. These investigations have been motivated by experiments in fluids, where an array of vortices was driven by an electromotive force. In these experiments, successive changes leading to a complex motion of the vortices, due to increased forcing, have been explored [Tabeling, Perrin, and Fauve, J. Fluid Mech. 213, 511 (1990)]. We model this experiment by means of two-dimensional Navier-Stokes equations with a special external forcing, driving a linear chain of eight counter-rotating vortices, imposing stress-free boundary conditions in the vertical direction and periodic boundary conditions in the horizontal direction. As the strength of the forcing or the Reynolds number is raised, the original stationary vortex array becomes unstable and a complex sequence of bifurcations is observed. Several steady states and periodic branches and a period doubling cascade appear on the route to chaos. For increasing values of the Reynolds number, shear flow develops, for which the spatial scale is large compared to the scale of the forcing. Furthermore, we have investigated the influence of the aspect ratio of the container as well as the effect of no-slip boundary conditions at the top and bottom, on the bifurcation scenario.
This paper deals with the electrical conductivity problem in geophysics. It is formulated as an elliptic boundary value problem of second order for a large class of bounded and unbounded domains. A special boundary condition, the so called "Complete Electrode Model", is used. Poincaré inequalities are formulated and proved in the context of weighted Sobolev spaces, leading to existence and uniqueness statements for the boundary value problem. In addition, a parameter-to-solution operator arising from the inverse conductivity problem in medicine (EIT) and geophysics is investigated mathematically and is shown to be smooth and analytic.
The stability of the quiescent ground state of an incompressible, viscous and electrically conducting fluid sheet, bounded by stress-free parallel planes and driven by an external electric field tangential to the boundaries, is studied numerically. The electrical conductivity varies as cosh–2(x1/a), where x1 is the cross-sheet coordinate and a is the half width of a current layer centered about the midplane of the sheet. For a <~ 0.4L, where L is the distance between the boundary planes, the ground state is unstable to disturbances whose wavelengths parallel to the sheet lie between lower and upper bounds depending on the value of a and on the Hartmann number. Asymmetry of the configuration with respect to the midplane of the sheet, modelled by the addition of an externally imposed constant magnetic field to a symmetric equilibrium field, acts as a stabilizing factor.
The bifurcations in a three-dimensional incompressible, electrically conducting fluid with an external forcing of the Roberts type have been studied numerically. The corresponding flow can serve as a model for the convection in the outer core of the Earth and is realized in an ongoing laboratory experiment aimed at demonstrating a dynamo effect. The symmetry group of the problem has been determined and special attention has been paid to symmetry breaking by the bifurcations. The nonmagnetic, steady Roberts flow loses stability to a steady magnetic state, which in turn is subject to secondary bifurcations. The secondary solution branches have been traced until they end up in chaotic states.
Two-dimensional bouyancy-driven convection in a horizontal fluid layer with stress-free boundary conditions at top and bottom and periodic boundary conditions in the horizontal direction is investigated by means of numerical simulation and bifurcation-analysis techniques. As the bouyancy forces increase, the primary stationary and symmetric convection rolls undergo successive Hopf bifurcations, bifurcations to traveling waves, and phase lockings. We pay attention to symmetry breaking and its connection with the generation of large-scale horizontal flows. Calculations of Lyapunov exponents indicate that at a Rayleigh number of 2.3×105 no temporal chaos is reached yet, but the system moves nonchaotically on a 4-torus in phase space.
We investigate the cognitive control in polyrhythmic hand movements as a model paradigm for bimanual coordination. Using a symbolic coding of the recorded time series, we demonstrate the existence of qualitative transitions induced by experimental manipulation of the tempo. A nonlinear model with delayed feedback control is proposed, which accounts for these dynamical transitions in terms of bifurcations resulting from variation of the external control parameter. Furthermore, it is shown that transitions can also be observed due to fluctuations in the timing control level. We conclude that the complexity of coordinated bimanual movements results from interactions between nonlinear control mechanisms with delayed feedback and stochastic timing components.
The stability of the quiescent ground state of an incompressible viscous fluid sheet bounded by two parallel planes, with an electrical conductivity varying across the sheet, and driven by an external electric field tangential to the boundaries is considered. It is demonstrated that irrespective of the conductivity profile, as magnetic and kinetic Reynolds numbers (based on the Alfvén velocity) are raised from small values, two-dimensional perturbations become unstable first.
Three-dimensional bouyancy-driven convection in a horizontal fluid layer with stress-free boundary conditions at the top and bottom and periodic boundary conditions in the horizontal directions is investigated by means of numerical simulation and bifurcation-analysis techniques. The aspect ratio is fixed to a value of 2√2 and the Prandtl number to a value of 6.8. Two-dimensional convection rolls are found to be stable up to a Rayleigh number of 17 950, where a Hopf bifurcation leads to traveling waves. These are stable up to a Rayleigh number of 30 000, where a secondary Hopf bifurcation generates modulated traveling waves. We pay particular attention to the symmetries of the solutions and symmetry breaking by the bifurcations.
The ill-posed problem of aerosol size distribution determination from a small number of backscatter and extinction measurements was solved successfully with a mollifier method which is advantageous since the ill-posed part is performed on exactly given quantities, the points r where n(r) is evaluated may be freely selected. A new twodimensional model for the troposphere is proposed.
We have studied the bifurcation structure of the incompressible two-dimensional Navier-Stokes equations with a special external forcing driving an array of 8×8 counterrotating vortices. The study has been motivated by recent experiments with thin layers of electrolytes showing, among other things, the formation of large-scale spatial patterns. As the strength of the forcing or the Reynolds number is raised the original stationary vortex array becomes unstable and a complex sequence of bifurcations is observed. The bifurcations lead to several periodic branches, torus and chaotic solutions, and other stationary solutions. Most remarkable is the appearance of solutions characterized by structures on spatial scales large compared to the scale of the forcing. We also characterize the different dynamic regimes by means of tracers injected into the fluid. Stretching rates and Hausdorff dimensions of convected line elements are calculated to quantify the mixing process. It turns out that for time-periodic velocity fields the mixing can be very effective.
The dynamics of noisy bistable systems is analyzed by means of Lyapunov exponents and measures of complexity. We consider both the classical Kramers problem with additive white noise and the case when the barrier fluctuates due to additional external colored noise. In case of additive noise we calculate the Lyapunov exponents and all measures of complexity analytically as functions of the noise intensity resp. the mean escape time. For the problem of fluctuating barrier the usual description of the dynamics with the mean escape time is not sufficient. The application of the concept of measures of complexity allows to describe the structures of motion in more detail. Most complexity measures sign the value of correlation time at which the phenomenon of resonant activation occurs with an extremum.
The usage of nonlinear Galerkin methods for the numerical solution of partial differential equations is demonstrated by treating an example. We desribe the implementation of a nonlinear Galerkin method based on an approximate inertial manifold for the 3D magnetohydrodynamic equations and compare its efficiency with the linear Galerkin approximation. Special bifurcation points, time-averaged values of energy and enstrophy as well as Kaplan-Yorke dimensions are calculated for both schemes in order to estimate the number of modes necessary to correctly describe the behavior of the exact solutions.
Anhand eines paradigmatischen Modellbeispiels werden die Konsequenzen der Koexistenz vieler Attraktoren auf die globale Dynamik schwach dissipativer Systeme studiert. Es wird gezeigt, dass diese Systeme eine sehr reichhaltige Dynamik besitzen und extrem sensitiv gegenüber Störungen in den Anfangsbedingungen sind. Diese Systeme zeichnen sich durch eine extrem hohe Flexibilität ihres Verhaltens aus.
The paper presents a method that determines, by standard numerical means, the type of mutual relations of fold and flip bifurcations (configured as a so-called communication area) of a map. Equation systems are developed for the computation of points where a transition between areas of different types occurs. Furthermore, it is shown that saddle area<->spring area transitions can exist which have not yet been considered in the literature. Analytical conditions of that transition are derived.
We have numerically studied the bifurcation properties of a sheet pinch with impenetrable stress-free boundaries. An incompressible, electrically conducting fluid with spatially and temporally uniform kinematic viscosity and magnetic diffusivity is confined between planes at x1=0 and 1. Periodic boundary conditions are assumed in the x2 and x3 directions and the magnetofluid is driven by an electric field in the x3 direction, prescribed on the boundary planes. There is a stationary basic state with the fluid at rest and a uniform current J=(0,0,J3). Surprisingly, this basic state proves to be stable and apparently to be the only time-asymptotic state, no matter how strong the applied electric field and irrespective of the other control parameters of the system, namely, the magnetic Prandtl number, the spatial periods L2 and L3 in the x2 and x3 directions, and the mean values B¯2 and B¯3 of the magnetic-field components in these directions.
We have studied the bifurcations in a three-dimensional incompressible magnetofluid with periodic boundary conditions and an external forcing of the Arnold-Beltrami-Childress (ABC) type. Bifurcation-analysis techniques have been applied to explore the qualitative behavior of solution branches. Due to the symmetry of the forcing, the equations are equivariant with respect to a group of transformations isomorphic to the octahedral group, and we have paid special attention to symmetry-breaking effects. As the Reynolds number is increased, the primary nonmagnetic steady state, the ABC flow, loses its stability to a periodic magnetic state, showing the appearance of a generic dynamo effect; the critical value of the Reynolds number for the instability of the ABC flow is decreased compared to the purely hydrodynamic case. The bifurcating magnetic branch in turn is subject to secondary, symmetry-breaking bifurcations. We have traced periodic and quasi- periodic branches until they end up in chaotic states. In particular detail we have analyzed the subgroup symmetries of the bifurcating periodic branches, which are closely related to the spatial structure of the magnetic field.
Contents: 1 Introduction 1.1 Tikhanov-Phillips Regularization of Ill-Posed Problems 1.2 A Compact Course to Wavelets 2 A Multilevel Iteration for Tikhonov-Phillips Regularization 2.1 Multilevel Splitting 2.2 The Multilevel Iteration 2.3 Multilevel Approach to Cone Beam Reconstuction 3 The use of approximating operators 3.1 Computing approximating families {Ah}
We have shown that the two-dimensional complex Ginzburg-Landau equation exhibits supertransient chaos in a certain parameter range. Using numerical methods this behavior is found near the transition line separating frozen spiral solutions from turbulence. Supertransient chaos seems to be a common phenomenon in extended spatiotemporal systems. These supertransients are characterized by an average transient lifetime which depends exponentially on the size of the system and are due to an underlying nonattracting chaotic set.
Using a special technique of data analysis, we have found out 34 grand minima of solar activity obtained from a 7,700 years long Δ14C record. The method used rests on a proper filtering of the Δ14C record and the extrapolation of verifiable results for the later history back in time. Additionally, we use a method of nonlinear dynamics, the recurrence rate, to back up the results. Our findings are not contradictory to the record of solar maxima resp. minima by Eddy [5], but constitute a considerable extension. Hence, it has become possible to look closer at the validity of models. This way, we have tested several models for solar activity, esp. the model of Barnes et al. [1]. There are hints for that the grand minima might solely be driven by the 209 year period found in the Δ14C record.
Contents: I. Algorithms 1. Theoretical Backround 2. Numerical Procedures 3. Graph Representation of the Solutions 4. Applications and Example II. Users' Manual 5. About the Program 6. The Course of a Qualitative Analysis 7. The Model Module 8. Input description 9. Output Description 10. Example 11. Graphics
The layer-by-layer assembly (LBL) of polyelectrolytes has been extensively studied for the preparation of ultrathin films due to the versatility of the build-up process. The control of the permeability of these layers is particularly important as there are potential drug delivery applications. Multilayered polyelectrolyte microcapsules are also of great interest due to their possible use as microcontainers. This work will present two methods that can be used as employable drug delivery systems, both of which can encapsulate an active molecule and tune the release properties of the active species. Poly-(N-isopropyl acrylamide), (PNIPAM) is known to be a thermo-sensitive polymer that has a Lower Critical Solution Temperature (LCST) around 32oC; above this temperature PNIPAM is insoluble in water and collapses. It is also known that with the addition of salt, the LCST decreases. This work shows Differential Scanning Calorimetry (DSC) and Confocal Laser Scanning Microscopy (CLSM) evidence that the LCST of the PNIPAM can be tuned with salt type and concentration. Microcapsules were used to encapsulate this thermo-sensitive polymer, resulting in a reversible and tunable stimuli- responsive system. The encapsulation of the PNIPAM inside of the capsule was proven with Raman spectroscopy, DSC (bulk LCST measurements), AFM (thickness change), SEM (morphology change) and CLSM (in situ LCST measurement inside of the capsules). The exploitation of the capsules as a microcontainer is advantageous not only because of the protection the capsules give to the active molecules, but also because it facilitates easier transport. The second system investigated demonstrates the ability to reduce the permeability of polyelectrolyte multilayer films by the addition of charged wax particles. The incorporation of this hydrophobic coating leads to a reduced water sensitivity particularly after heating, which melts the wax, forming a barrier layer. This conclusion was proven with Neutron Reflectivity by showing the decreased presence of D2O in planar polyelectrolyte films after annealing creating a barrier layer. The permeability of capsules could also be decreased by the addition of a wax layer. This was proved by the increase in recovery time measured by Florescence Recovery After Photobleaching, (FRAP) measurements. In general two advanced methods, potentially suitable for drug delivery systems, have been proposed. In both cases, if biocompatible elements are used to fabricate the capsule wall, these systems provide a stable method of encapsulating active molecules. Stable encapsulation coupled with the ability to tune the wall thickness gives the ability to control the release profile of the molecule of interest.