Referiert
Refine
Year of publication
Document Type
- Article (17582)
- Postprint (2119)
- Review (646)
- Other (536)
- Conference Proceeding (219)
- Preprint (116)
- Part of Periodical (103)
- Monograph/Edited Volume (87)
- Doctoral Thesis (74)
- Part of a Book (53)
Language
- English (19354)
- German (2027)
- Spanish (105)
- French (49)
- Multiple languages (21)
- Russian (12)
- Italian (9)
- Portuguese (7)
- Chinese (1)
Keywords
- climate change (115)
- Germany (86)
- diffusion (72)
- anomalous diffusion (58)
- stars: massive (56)
- machine learning (55)
- German (54)
- Arabidopsis thaliana (50)
- Climate change (49)
- Holocene (49)
Institute
- Institut für Biochemie und Biologie (3370)
- Institut für Physik und Astronomie (3221)
- Institut für Geowissenschaften (2700)
- Institut für Chemie (2092)
- Department Psychologie (1150)
- Institut für Ernährungswissenschaft (795)
- Department Linguistik (675)
- Institut für Mathematik (662)
- Department Sport- und Gesundheitswissenschaften (655)
- Institut für Umweltwissenschaften und Geographie (556)
We study thermally induced birefringence in crystalline Nd:YAG zigzag slab lasers and the associated depolarization losses. The optimum crystallographic orientation of the zigzag slab within the Nd:YAG boule and photoelastic effects in crystalline Nd:YAG slabs are briefly discussed. The depolarization is evaluated using the temperature and stress distributions, calculated using a finite element model, for realistically pumped and cooled slabs of finite dimensions. Jones matrices are then used to calculate the depolarization of the zigzag laser mode. We compare the predictions with measurements of depolarization, and suggest useful criteria for the design of the gain media for such lasers.
High cw power using an external cavity for spectral beam combining of diode laser-bar emission
(2006)
In extension to known concepts of wavelength-multiplexing diode laser arrays, a new external cavity is presented. The setup simultaneously improves the beam quality of each single emitter of a standard 25 emitter broad-area stripe laser bar and spectrally superimposes the 25 beams into one. By using this external resonator in an "off-axis" arrangement, beam qualities of M-slow(2) < 14 and M-fast(2) < 3 with optical powers in excess of 10 W in cw operation are obtained.
Diagnosis and repair of negative polarity constructions in the light of symbolic resonance analysis
(2006)
in a post hoc analysis, we investigate differences in event-related potentials of two studies (Drenhaus et al., 2004, to appear; Saddy et al., 2004) by using the symbolic resonance analysis (Beim Graben & Kurths, 2003). The studies under discussion, examined the failure to license a negative polarity item (NPI) in German: Saddy et al. (2004a) reported an N400 component when the NPI was not accurately licensed by negation; Drenhaus et al. (2004, to appear) considered additionally the influence of constituency of the licensor in NPI constructions. A biphasic N400-P600 response was found for the two induced violations (the lack of licensor and the inaccessibility of negation in a relative clause). The symbolic resonance analysis (SRA) revealed an effect in the P600 time window for the data in Saddy et al., which was not found by using the averaging technique. The SRA of the ERPs in Drenhaus et al., showed that the P600 components are distinguishable concerning the amplitude and latency. It was smaller and earlier in the condition where the licensor is inaccessible, compared to the condition without negation in the string. Our findings suggest that the failure in licensing NPIs is not exclusively related to semantic integration costs (N400). The elicited P600 components reflect differences in syntactic processing. Our results confirm and replicate the effects of the traditional voltage average analysis and show that the SRA is a useful tool to reveal and pull apart ERP differences which are not evident using the traditional voltage average analysis.
Variously substituted tolanes were employed to show that the push-pull effect is also active in C equivalent to C triple bonds by the successful correlation of the occupation quotient pi*/pi of the pi orbital in resonance with the substituted phenyl moieties of tolanes versus the bond length of the C equivalent to C triple bond. In addition, the influences of the ortho phenyl ring substituents on the C-13 chemical shifts of the triple bond carbon atoms, which were estimated by Rubin et al.(4) to be "inapplicable for describing triple bond polarization", were re-evaluated, leading to the conclusion that, while anisotropic effects of ortho substituents are negligible, the steric ortho-substituent effects do in fact dominate the deviations obtained. A detailed theoretical NBO/NCS study has been employed to illuminate the facts of this case
New amphiphilic diblock copolymers : surfactant properties and solubilization in their micelles
(2006)
Several series of amphiphilic diblock copolymers are investigated as macrosurfactants in comparison to reference low-molar-mass and polymeric surfactants. The various copolymers share poly(butyl acrylate) as a common hydrophobic block but are distinguished by six different hydrophilic blocks (one anionic, one cationic, and four nonionic hydrophilic blocks) with various compositions. Dynamic light scattering experiments indicate the presence of micelles over the whole concentration range from 10(-4) to 10 g(.)L(-1). Accordingly, the critical micellization concentrations are very low. Still, the surface tension of aqueous solutions of block copolymers decreases slowly but continuously with increasing concentration, without exhibiting a plateau. The longer the hydrophobic block, the shorter the hydrophilic block, and the less hydrophilic the monomer of the hydrophilic block is, the lower the surface tension is. However, the effects are small, and the copolymers reduce the surface tension much less than standard low-molar-mass surfactants. Also, the copolymers foam much less and even act as anti-foaming agents in classical foaming systems composed of standard surfactants. The copolymers stabilize O/W emulsions made of methyl palmitate as equally well as standard surfactants but are less efficient for O/W emulsions made of tributyrine. However, the copolymer micelles exhibit a high solubilization power for hydrophobic dyes, probably at their core-corona interface, in dependence on the initial geometry of the micelles and the composition of the block copolymers. Whereas micelles of copolymers with strongly hydrophilic blocks are stable upon solubilization, solubilization-induced micellar growth is observed for copolymers with moderately hydrophilic blocks
Finding non-Gaussian components of high-dimensional data is an important preprocessing step for efficient information processing. This article proposes a new linear method to identify the '' non-Gaussian subspace '' within a very general semi-parametric framework. Our proposed method, called NGCA (non-Gaussian component analysis), is based on a linear operator which, to any arbitrary nonlinear (smooth) function, associates a vector belonging to the low dimensional non-Gaussian target subspace, up to an estimation error. By applying this operator to a family of different nonlinear functions, one obtains a family of different vectors lying in a vicinity of the target space. As a final step, the target space itself is estimated by applying PCA to this family of vectors. We show that this procedure is consistent in the sense that the estimaton error tends to zero at a parametric rate, uniformly over the family, Numerical examples demonstrate the usefulness of our method
In the estimate of dispersion with the help of wavelet analysis considerable emphasis has been put on the extraction of the group velocity using the modulus of the wavelet transform. In this paper we give an asymptotic expression of the full propagator in wavelet space that comprises the phase velocity as well. This operator establishes a relationship between the observed signals at two different stations during wave propagation in a dispersive and attenuating medium. Numerical and experimental examples are presented to show that the method accurately models seismic wave dispersion and attenuation
We report measurements of radial and azimuthal anisotropy in the tipper mantle beneath southern and central Finland, which we obtained by array analysis of fundamental-mode Rayleigh and Love waves. Azimuthally averaged phase velocities were analysed in the period range 15 to 190 s for Rayleigh waves and 15 to 100 s for Love waves. The azimuthal variation of the Rayleigh wave phase velocities was obtained in the period range 20 to 100s. The limited depth resolution of fundamental-mode surface waves necessitated strong damping constraints in the inversion for anisotropic parameters. We investigated the effects of non-unicity on the final model by experimenting with varying model geometries. The radial anisotropy beneath Finland can be explained by a lithosphere at least 200km thick, predominantly (> 50% by volume) composed of olivine crystals having their a-axes randomly distributed in the horizontal plane. On the contrary, the measured lithospheric azimuthal anisotropy is small. This call be reconciled with body-wave observations made in the area that indicate a complex pattern of rapidly varying anisotropy. Below 200-250km depth, that is below the petrologic lithosphere as revealed by xenolith analyses conducted in the area, the magnitude of the azimuthal anisotropy increases and would be compatible with a mantle containing 15-20% by volume of olivine crystals whose a-axes are coherently aligned in the N-NE direction. The alignment of the a-axes is off the direction of present-day absolute plate motion in either the no-net-rotation or hot-spot reference frame, currently N55-N60. We interpret this mismatch as evidence for a complex convective flow pattern of the mantle beneath the shield, which, by inference, is decoupled from the overlying lithosphere.
The regioselectivities of methyl- and phenylhydrazine with acridin-9-yl isothiocyanate (thus yielding thiosemicarbazides with acridine substituted on the urea-type side) were examined. Methythydrazine regioselectivity was high with the alpha-nitrogen atom overwhelmingly more nucleophilic than the beta-nitrogen atom; phenylhydrazine regioselectivity was poor but varied with the solvent and only in the case of ethanol was nucleophilic predominance of the alpha-nitrogen atom pronounced. Of note, whilst both phenyl thiosemicarbazides were present in solution only as spiro forms, the methyl product was present as an equilibrium mixture of open-chain and spiro thiosemicarbazides. Reactions on the NH2 blocked analogue of methyl acridin-9-ylthiosemicarbazide (1-isopropylidene-2- methylthiosemicarbazide) were also examined. Interestingly, present in the starting material itself was a structural motif of novelty wherein a triazolethione represented the major species of an equilibrium between cyclic and open-chain forms
A free-ranging bushbuck (Tragelaphus scriptus) population was observed over a period of 3 years, thereby enabling a detailed description of the behavioural repertoire of this widespread but barely investigated solitary African antelope species. Agonistic and submissive behaviour patterns are described, among them several hitherto un- described behaviour patterns - such as "escorting", where territorial males guide intruders to the periphery of their territory - and "push-up position", an extreme form of submissive behaviour. Furthermore, we report on behaviour patterns of males and females during mating as well as on behaviour patterns of parents directed towards their offspring. Again, we describe a hitherto unknown behaviour: the protection of calves by adult males, which may be a socio-positive behaviour directed towards their offspring led by kin selection
What makes computer users spend their free time working with the computer? Are there different types of users and, if so, in what ways do they differ? N = 271 subjects took part in an online survey concerning the incentives for computer use in free time. Selected mailing lists were used to identify highly committed users (A4 3.9 hours of free time a day spent working with computers). The following incentive factors were found for these users: community/ affiliation; sense of competence; flexibility/utility; avoidance of boredom; rebellious tendency to illegality. Depending on their favorite use of the computer, three types of users were found: Purposeful users (58%), hackers (entering other networks without intention to cause damage) (22%), and crackers (entering other networks with intention to cause damage) (20%). There are significant differences in the incentive profiles of these types of users. Hacking and cracking, but not purposeful use, are correlated with flow experience and positive activation. These findings are not representative for all leisure time computer users. They refer to a sample of highly committed users who can be reached in special associations (e.g., relevant student networks, the Chaos Computer Club)
The crystal and molecular structures of sodium and barium complexes of dibenzo-24-crown-8 ether
(2006)
The sodium and barium isothiocyanate complexes of 6,7,9,10,12,13,20,21,23,24,26,27-dodecahydrodibenzo[b,n]- 1,4,7,10,13,16,19,22-octaoxacyclotetracosin (dibenzo-24-crown-8 ether = DB24C8) were synthesized and analyzed by X-ray diffraction. The sodium complex, [Na(DB24C8)(NCS)(H2O)] 1, crystallizes in the orthorhombic space group Fdd2 with 16 molecules in the unit cell. The coordination number of Na is 6 and the central ion is located in a distorted octahedric environment. Only four of the crown ether oxygen atoms are involved. The coordination polyhedron is completed by the isothiocanate anion and by a water molecule, which is stabilized by hydrogen bonds. The barium complex, [Ba(DB24C8)(NCS)(2)] 2, crystallizes in the trigonale space group P3(1)21 with 3 molecules in the unit cell. Crystallographic C-2 symmetry is observed for the complex. The coordination number of Ba is 10. Barium is coordinated with the eight oxygen atoms of the macrocyclic ligand and with two isothiocyanate anions. The absolute structure was estimated using the FLACK parameter
In the humid tropics, continuing high deforestation rates are seen alongside an increasing expansion of secondary forests. In order to understand and model the consequences of these dynamic land-use changes for regional water cycles, the response of soil hydraulic properties to forest disturbance and recovery has to be quantified.At a site in the Brazilian Amazonia, we annually monitored soil infiltrability and saturated hydraulic conductivity (K-s) at 12.5, 20 cm, and 50 cm soil depth after manual forest conversion to pasture (year zero to four after pasture establishment), and during secondary succession after pasture abandonment (year zero to seven after pasture abandonment). We evaluated the hydrological consequences of the detected changes by comparing the soil hydraulic properties with site-specific rainfall intensities and hydrometric observations. Within one year after grazing started, infiltrability and K-s at 12.5 and 20 cm depth decreased by up to one order of magnitude to levels which are typical for 20-year-old pasture. In the three subsequent monitoring years, infiltrability and K-s remained stable. Land use did not impact on subsoil permeability. Whereas infiltrability values are large enough to allow all rainwater to infiltrate even after the conversion, the sudden decline of near-surface K-s is of hydrological relevance as perched water tables and overland flow occur more often on pastures than in forests at our study site. After pasture abandonment and during secondary succession, seven years of recovery did not suffice to significantly increase infiltrability and K-s at 12.5 depth although a slight recovery is obvious. At 20 cm soil depth, we detected a positive linear increase within the seven-year time frame but annual means did not differ significantly. Although more than a doubling of infiltrability and K-s is still required to achieve pre-disturbance levels, which will presumably take more than a decade, the observed slight increases of K-s might already decrease the probability of perched water table generation and overland flow development well before complete recovery.
Penicillin amidase from Alacaligenes faecalis is an attractive biocatalyst for hydrolysis of penicillin G for production of 6-aminopenicillanic acid, which is used in the synthesis of semi-synthetic beta-lactam antibiotics. Recently a mutant of this enzyme with extended C-terminus of the A-chain comprising parts of the connecting linker peptide was constructed. Its turnover number for the hydrolysis of penicillin G was 140 s(-1), about twice of the value for the wild-type enzyme (80 s(-1)). At the same time the specificity constant was improved about three-fold. The wild- type and the mutant enzymes showed similar pH stability suggesting that the linker peptide fragment covalently attached to the A-chain does not alter the electrostatic interactions in the protein core. Although the global stability of A. faecalis wild-type enzyme and the T206GS213G variant does not differ, the presence of the linker fragment stabilizes the domains interface, as evidenced by the monophasic transition of the mutant enzyme from folded to unfolded state during urea-induced denaturation. The high stability and activity of the mutant enzyme provides a rationale to use it as a biocatalyst in the industrial processes, where the enzyme must be more robust to fluctuations in the operational conditions.
We present a detailed, realistic analysis of the implementation of a proposal for a quantum phase gate based on atomic vibrational states, specializing it to neutral rubidium atoms on atom chips. We show how to create a double-well potential with static currents on the atom chips, using for all relevant parameters values that are achieved with present technology. The potential barrier between the two wells can be modified by varying the currents in order to realize a quantum phase gate for qubit states encoded in the atomic external degree of freedom. The gate performance is analyzed through numerical simulations; the operation time is similar to 10 ms with a performance fidelity above 99.9%. For storage of the state between the operations the qubit state can be transferred efficiently via Raman transitions to two hyperfine states, where its decoherence is strongly inhibited. In addition we discuss the limits imposed by the proximity of the surface to the gate fidelity.
The acinar salivary glands of cockroaches receive a dual innervation from the subesophageal ganglion and the stomatogastric nervous system. Acinar cells are surrounded by a plexus of dopaminergic and serotonergic varicose fibers. In addition, seroton-ergic terminals lie deep in the extracellulor spaces between acinar cells. Excitation-secretion coupling in cockroach salivary glands is stimulated by both dopamine and serotonin. These monoamines cause increases in the intracellular concentrations of cAMP and Ca2+. Stimulation of the glands by serotonin results in the production of a protein-rich saliva, whereas stimulation by dopamine results in saliva that is protein-free. Thus, two elementary secretary processes, namely electrolyte/water secretion and protein secretion, are triggered by different aminergic transmitters. Because of its simplicity and experimental accessibility, cockroach salivary glands have been used extensively as a model system to study the cellular actions of biogenic amines and to examine the pharmacological properties of biogenic amine receptors. In this review, we summarize current knowledge concerning the aminergic control of cockroach salivary glands and discuss our efforts to characterize Periplaneta biogenic amine receptors molecularly
Different chemical and enzymatic methods were applied for the hydrolysis of main stems from Lupinus nootkatensis (harvest November 2002). The whole process (all steps) is based on the lignocellulose-feedstock biorefinery regime. The acid hydrolysis of L. was performed with concentrated hydrochloric acid; advantages in this process are exothermic hydrolysis and the possibility of acid recovery. Enzymatic hydrolysis achieved high yields of fermentable carbohydrates (regarding to input cellulose) with high selectivity. However, this way requires the generation of cellulose from L. by chemical pulping. Monosaccharide derivatives thus obtained were identified by their GC retention times and the corresponding MS fragmentation. Hexamethyldisilazane was used as derivatization reagent to prepare the trimethylsilyl derivatives of the carbohydrates and of the degradations products of cellulose from the different fractions. The glucose content was quantified by GC peak integration with respect to an internal standard.
In this Letter, we show that coherence and phase synchronization analysis are sensitive but not specific in detecting the correct class of underlying dynamics. We propose procedures to increase specificity and demonstrate the power of the approach by application to paradigmatic dynamic model systems. (c) 2006 Elsevier B.V. All rights reserved