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- film (5)
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- functionalization (5)
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- partial melting (5)
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- pathways (5)
- perceptual reorganization (5)
- periodization (5)
- permafrost degradation (5)
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- peroxides (5)
- phase separation (5)
- phenomenology (5)
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- plant functional trait (5)
- plant functional traits (5)
- plateau (5)
- plyometric exercise (5)
- politeness (5)
- political education (5)
- poly(lactic acid) (5)
- polyethylene (5)
- polymer chemistry (5)
- polymer degradation (5)
- polymorphism (5)
- population genomics (5)
- populations (5)
- pornography (5)
- porous carbon (5)
- positive selection (5)
- postural sway (5)
- poverty (5)
- predictability (5)
- preferences (5)
- preferential flow (5)
- pressure (5)
- presupposition (5)
- private households (5)
- probabilistic (5)
- probiotics (5)
- problem solving (5)
- process mining (5)
- professional knowledge (5)
- professionalization (5)
- protection (5)
- protein modification (5)
- protein-protein interactions (5)
- psychometric properties (5)
- pupillometry (5)
- purification (5)
- qualitative analysis (5)
- quantification (5)
- quantitative Analyse (5)
- quantitative analysis (5)
- quantum field theory (5)
- radiocarbon (5)
- random diffusivity (5)
- random-walks (5)
- range shifts (5)
- rare earth elements (5)
- reading comprehension (5)
- real-time rendering (5)
- reconstruction (5)
- reflexives (5)
- regional development (5)
- rejection sensitivity (5)
- relational aggression (5)
- relativistic jets (5)
- repetition (5)
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- resonance energy transfer (5)
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- rheology (5)
- rhythmic grouping (5)
- rice (5)
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- risk management (5)
- rotifers (5)
- running (5)
- rural (5)
- salicylic acid (5)
- salt stress (5)
- scaling (5)
- scenario (5)
- scenarios (5)
- school shooting (5)
- sedaDNA (5)
- sedimentary ancient DNA (5)
- seed bank (5)
- seismic noise (5)
- selectivity (5)
- self-employment (5)
- self-evaluation (5)
- semi-arid (5)
- sensitivity analysis (5)
- sentence production (5)
- sentiment analysis (5)
- service-oriented systems engineering (5)
- sex (5)
- shape-memory polymers (5)
- shotgun sequencing (5)
- silica (5)
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- smart contracts (5)
- social (5)
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- spatial autocorrelation (5)
- spatial cognition (5)
- spatial-distribution (5)
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- species distribution models (5)
- spectra (5)
- speech motor control (5)
- sphingosine-1-phosphate (5)
- sport-specific performance (5)
- sports (5)
- standards (5)
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- strategic growth adjustments (5)
- strategy (5)
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- students (5)
- stunting (5)
- sucrose (5)
- sulfate reduction (5)
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- surface processes (5)
- surface relief grating (5)
- surfaces (5)
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- top-down control (5)
- tourism (5)
- trajectories (5)
- transcriptome (5)
- trend analysis (5)
- tunneling (5)
- type 2 diabetes mellitus (5)
- tyramine (5)
- ultraviolet: ISM (5)
- uncertainties (5)
- uncertainty quantification (5)
- upconversion (5)
- urban (5)
- validation study (5)
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- walking (5)
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- xanthine dehydrogenase (5)
- öffentlicher Sektor (5)
- ökologische Modellierung (5)
- 1814-1831 (4)
- 2nd-language (4)
- 3D-Visualisierung (4)
- 4 (4)
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- Friedrich Wilhelm III. (4)
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- ISM: molecules (4)
- IT-Infrastruktur (4)
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- Xanthomonas (4)
- absorption (4)
- academic self-concept (4)
- accretion, accretion disks (4)
- achilles tendinopathy (4)
- actin (4)
- action language (4)
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- adaptive force (4)
- additive particles (4)
- adherence (4)
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- adjectives (4)
- advanced dynamic flow (4)
- aerosol (4)
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- agent-based model (4)
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- aldehyde oxidase (4)
- allelopathy (4)
- alternatives (4)
- amerikanische Reisetagebücher (4)
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- anisotropy (4)
- antifouling (4)
- antilocality (4)
- aphids (4)
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- arabidopsis (4)
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- argumentation (4)
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- circular dichroism (4)
- citizenship (4)
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- clone (4)
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- coating (4)
- cod-liver (4)
- coefficient (4)
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- coevolution (4)
- cognitive enhancement (4)
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- collagen (4)
- colonization (4)
- combat sports (4)
- common vole (4)
- community structure (4)
- compliance (4)
- computer-based training (4)
- conceptualization (4)
- concrete (4)
- conduct problems (4)
- conductivity (4)
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- consequences (4)
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- conversion (4)
- copper(II) (4)
- core (4)
- corpus linguistics (4)
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- covariance (4)
- creep (4)
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- cross-cultural comparison (4)
- cross-curriculum (4)
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- crust (4)
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- cyberbullying victimization (4)
- cylindrospermopsin (4)
- cystic fibrosis (4)
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- data mining (4)
- data preparation (4)
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- decarbonization (4)
- deformation (4)
- degenerative disc disease (4)
- democratic theory (4)
- demography (4)
- deposition (4)
- diachrony (4)
- diagnostic competence (4)
- diagnostics (4)
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- Trauma (3)
- Tree (3)
- Tree allometry (3)
- Treibhausgase (3)
- Trifluoromethanesulfonamide (3)
- Tripel-Graph-Grammatik (3)
- Trochaic Law (3)
- Trunk muscle strength (3)
- Tupaia (3)
- Two forms of isometric muscle action (3)
- Type 2 diabetes (3)
- Türkei (3)
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- UK (3)
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- YouTube (3)
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- [4+2] cycloaddition (3)
- ab initio (3)
- ab initio calculations (3)
- aboveground biomass (3)
- absolute (3)
- academic failure (3)
- acceptability judgments (3)
- accessibility (3)
- accuracy (3)
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- actin cytoskeleton (3)
- action recognition (3)
- active layer (3)
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- activity preference (3)
- acute coronary syndrome (3)
- adaptive management (3)
- additive Fertigung (3)
- adiposity (3)
- adolescent athletes (3)
- adolescent immigrants (3)
- adulthood (3)
- aerosols (3)
- affective priming (3)
- aggressive behavior (3)
- aggressive cognitions (3)
- aggressive peers (3)
- aging brain (3)
- agreement (3)
- agreement attraction (3)
- aid effectiveness (3)
- air-water interface (3)
- albuminuria (3)
- allocation policies (3)
- amitriptyline (3)
- amperometry (3)
- analytics (3)
- anaphor resolution (3)
- anatoxin (3)
- ancient sedimentary DNA (3)
- animal behaviour (3)
- anorexia nervosa (3)
- antecedent complexity (3)
- anthracene (3)
- anthropogenic environment (3)
- anthropometric measures (3)
- anti-doping (3)
- anti-fouling materials (3)
- antisemitism (3)
- aphasia treatment (3)
- app (3)
- apple (3)
- application (3)
- approach (3)
- aquaporin (3)
- arable land (3)
- area (3)
- argument mining (3)
- argumentation structure (3)
- artifical intelligence (3)
- artificial muscles (3)
- artificial neural networks (3)
- aspect (3)
- aspect ratio (3)
- assemblies (3)
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- asteroseismology (3)
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- asylum (3)
- asymmetry (3)
- asymptotic expansion (3)
- atherosclerosis (3)
- atmospheric deposition (3)
- atmospheric effects (3)
- atomic force microscopy (AFM) (3)
- attentional control (3)
- attentional demand (3)
- attenuation tomography (3)
- attraction (3)
- auditory perception (3)
- authentication (3)
- autism (3)
- automatic processing (3)
- autophagy (3)
- auxiliary control (3)
- auxotrophy (3)
- bacterial O-antigen (3)
- bacterial production (3)
- balance training (3)
- bandgap (3)
- basal accretion (3)
- basic psychological need frustration (3)
- bat fatalities (3)
- batch processing (3)
- bats (3)
- beliefs (3)
- benchmark (3)
- benefits (3)
- benzodiazepines (3)
- berufliche Wiedereingliederung (3)
- bifurcation (3)
- bilinguals (3)
- bioactive peptides (3)
- bioavailability (3)
- biochemistry (3)
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- biodiversity conservation (3)
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- biorefinery (3)
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- bird migration (3)
- bismuth (3)
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- body image (3)
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- bone (3)
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- bone remodeling (3)
- border (3)
- bottom-up (3)
- boundary element method (3)
- boundary layer (3)
- brain potentials (3)
- branching (3)
- brassinosteroid (3)
- business model (3)
- business process modeling (3)
- caffeine (3)
- calcite (3)
- cancer cachexia (3)
- capacity (3)
- capacity building (3)
- capillary recruitment (3)
- capital market (3)
- carbohydrate interaction (3)
- carbon budget (3)
- carbon dots (3)
- carbon pricing (3)
- carbon-cycle (3)
- carbonate (3)
- cardiomyopathy (3)
- caregiver (3)
- carotenoid (3)
- cartel (3)
- cartographic design (3)
- catalase (3)
- cell (3)
- cell motility (3)
- cell polarity (3)
- cellular bioenergetics (3)
- center embedding (3)
- centralization (3)
- centriole (3)
- channel (3)
- charcoal (3)
- charge storage (3)
- chemostat experiments (3)
- child care (3)
- child growth (3)
- chimera state (3)
- chimera states (3)
- chlorophyll (3)
- chronic back pain (3)
- chronic diseases (3)
- ciliates (3)
- cilium (3)
- cis-regulatory evolution (3)
- citizen participation (3)
- civil service (3)
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- civil war (3)
- classical solution (3)
- classical swine fever (3)
- cleft (3)
- climate change impact (3)
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- climate dynamics (3)
- climate mitigation (3)
- climate networks (3)
- climate neutrality (3)
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- coatings (3)
- cockroach (3)
- cocoa processing (3)
- cocoa proteins (3)
- code (3)
- code generation (3)
- coercive strategies (3)
- coffee processing (3)
- cognitive behavioral therapy (3)
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- cognitive decline (3)
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- cognitive module (3)
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- coherency (3)
- coiled coil (3)
- cold (3)
- collective dynamics (3)
- collective guilt (3)
- collective team identification (3)
- collusion (3)
- colon cancer (3)
- color (3)
- colorectal cancer (3)
- combat sport (3)
- comets: individual: 67P/Churyumov-Gerasimenko (3)
- community assembly (3)
- comorbidities (3)
- companies (3)
- comparative studies (3)
- compensatory dynamics (3)
- competence development (3)
- competencies (3)
- competitive growth (3)
- complementarity (3)
- compounds (3)
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- computer science education (3)
- concentration (3)
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- conduction (3)
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- configuration (3)
- conflict resolution (3)
- conformation (3)
- congeneric species (3)
- conscripts (3)
- constraint (3)
- constraint-based modeling (3)
- consumer behavior (3)
- consumer education (3)
- consumption (3)
- consumptive resistance (3)
- contact (3)
- content analysis (3)
- contestation (3)
- continental lithosphere (3)
- continuous time random walk (3)
- controlled radical polymerization (3)
- convolutional neural network (3)
- coping styles (3)
- copolymerization (3)
- coreference (3)
- coronal mass ejections (CMEs) (3)
- coronary bypass grafting (3)
- coronary heart disease (3)
- corpus analysis (3)
- correlated noise (3)
- correlations (3)
- cosmic-ray neutron sensing (3)
- cost-benefit analysis (3)
- counting process (3)
- coupled oscillators (3)
- coupled rotators (3)
- coupling (3)
- critical avalanche dynamics (3)
- critical phenomena (3)
- cross-domain priming (3)
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- crowding (3)
- cryolithology (3)
- cryptic species (3)
- crystalline (3)
- cue validity (3)
- curriculum framework (3)
- curvature (3)
- cyberhate (3)
- cybervictimization (3)
- cyclic AMP (3)
- cycloaddition (3)
- cylindrical geometry (3)
- cytosolic tRNA thiolation (3)
- damage estimation (3)
- damage modeling (3)
- dark matter theory (3)
- dark triad (3)
- data fusion (3)
- data matching (3)
- data science (3)
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- decentralisation (3)
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- decision tree (3)
- decompositon (3)
- deduplication (3)
- deep convection (3)
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- defense against predation (3)
- definition (3)
- deforestation (3)
- degraded DNA (3)
- dehydration (3)
- delta-D values (3)
- dendroclimatology (3)
- denitrification (3)
- density functional theory (3)
- denudation (3)
- depressive disorder (3)
- design parameters (3)
- deutsch-jüdische Geschichte (3)
- developing countries (3)
- developmental dyslexia (3)
- diagnosis (3)
- dialectics (3)
- diamond anvil cell (3)
- dictator game (3)
- dielectric relaxation spectroscopy (3)
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- differential gene expression (3)
- diffraction (3)
- diffusing diffusivity (3)
- digital elevation model (3)
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- effect (3)
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- elastomers (3)
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- electrophysiological evidence (3)
- elemental composition (3)
- elevated plus-maze (3)
- elite athlete (3)
- elliptic complexes (3)
- embedded systems (3)
- emergency management (3)
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- emotion regulation (3)
- emotional valence (3)
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- encoding (3)
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- endozoochory (3)
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- ensemble prediction (3)
- enterprise systems (3)
- environmental pollution (3)
- enzyme immobilization (3)
- enzymology (3)
- ephrin (3)
- episodic memory (3)
- epistemic modality (3)
- equalizing and stabilizing mechanisms (3)
- equation (3)
- equi-singular connections (3)
- equifinality (3)
- erythropoiesis (3)
- escherichia-coli (3)
- establishment (3)
- evaporation (3)
- event (3)
- eventology (3)
- evolution equation (3)
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- extracellular matrix (3)
- extraction and characterization methods (3)
- extremes (3)
- extremophiles (3)
- eye-voice span (3)
- fMRT (3)
- face morphing (3)
- facial feedback (3)
- factor analysis (3)
- factor structure (3)
- faking (3)
- family (3)
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- fault reactivation (3)
- fault tolerance (3)
- fermentation-related enzymes (3)
- fiber etching (3)
- fibers (3)
- fibrosis (3)
- figurative language (3)
- filter (3)
- financial time series (3)
- finite element modeling (3)
- fire (3)
- first-hitting time (3)
- fiscal equalization (3)
- fitness consequences (3)
- fixation durations (3)
- fixation locations (3)
- flavonoid (3)
- flavonoids (3)
- flood hazard (3)
- flood hazards (3)
- flood loss (3)
- floodplain sedimentation (3)
- floodplains (3)
- flow cytometry (3)
- flowering (3)
- fluctuation-dissipation theorem (3)
- fluid-rock interaction (3)
- fluorescence lifetime (3)
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- foam (3)
- focus particles (3)
- food security (3)
- forecast (3)
- forest (3)
- forest structure (3)
- forestREplot (3)
- formal languages (3)
- formale Verifikation (3)
- formate dehydrogenase (3)
- formation damage (3)
- fracture (3)
- framework (3)
- frameworks (3)
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- friendship (3)
- fsQCA (3)
- functional (3)
- functional capacity (3)
- functional dependencies (3)
- functional dependency (3)
- fungal diversity (3)
- gait analysis (3)
- galaxies: fundamental parameters (3)
- galaxy structure (3)
- gallbladder cancer (3)
- garnet (3)
- gas adsorption (3)
- gels (3)
- gender equality (3)
- gender inequality (3)
- gene duplication (3)
- gene family (3)
- gene regulatory network (3)
- general (3)
- generalizability (3)
- generalization (3)
- genetic programming (3)
- genome assembly (3)
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- glaciers (3)
- glass (3)
- global environmental change (3)
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- global surface warming (3)
- globular clusters: individual: NGC 6397 (3)
- glucan (3)
- glucocorticoid receptor (3)
- glycaemic control (3)
- glycogen (3)
- goal frames (3)
- goblet cells (3)
- good governance (3)
- grade-skipping (3)
- gradient boosting (3)
- gradient flow (3)
- grain-size distribution (3)
- grammatical illusion (3)
- granite (3)
- granitoids (3)
- graph constraints (3)
- graphite (3)
- graphomotor control (3)
- grassland (3)
- grasslands (3)
- green (3)
- green growth (3)
- gross primary production (3)
- ground reaction forces (3)
- ground-penetrating radar (3)
- grounded cognition (3)
- grouping (3)
- growth rate (3)
- guideline (3)
- guilt (3)
- habitat loss (3)
- habitus (3)
- hand (3)
- health behavior (3)
- health promotion (3)
- healthy eating (3)
- heat stress memory (3)
- heath potentials (3)
- heavy rainfall (3)
- hemispheric asymmetry (3)
- hermeneutics (3)
- heterogene Katalyse (3)
- heterogene Photokatalyse (3)
- heterogeneous photocatalysis (3)
- heterostyly (3)
- heterotrophic bacteria (3)
- hierarchical clustering (3)
- high temperature (3)
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- high-resolution record (3)
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- hillslopes (3)
- hip (3)
- historiography (3)
- holography (3)
- hospital (3)
- hospitalization (3)
- hospitals (3)
- hostile attribution bias (3)
- housing (3)
- hoverflies (3)
- human computer interaction (3)
- human-computer interaction (3)
- humanism (3)
- hybrid model (3)
- hybridoma (3)
- hydraulic fracturing (3)
- hydrogen bonds (3)
- hydrogenation (3)
- hydrogeology (3)
- hydrological processes (3)
- hypersound (3)
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- hypothesis (3)
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- ice sheet (3)
- image (3)
- image-based representation (3)
- imidazolium (3)
- immigrants (3)
- impact assessment (3)
- impedance spectroscopy (3)
- implementation (3)
- implicit association test (IAT) (3)
- implicit learning (3)
- implizit (3)
- in silico (3)
- inbreeding depression (3)
- incision (3)
- income distribution (3)
- incremental graph pattern matching (3)
- indianische Kunst (3)
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- infant (3)
- inferences (3)
- infiltration (3)
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- informatics (3)
- information integration (3)
- infrared: diffuse background (3)
- injection (3)
- inner magnetosphere (3)
- inorganic chemistry (3)
- input frequency (3)
- intensification (3)
- intercultural competence (3)
- interface engineering (3)
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- interferometry (3)
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- interleukin-8 (3)
- intermediate disturbance hypothesis (3)
- intermolecular interactions (3)
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- intervention locality (3)
- intervention study (3)
- interview study (3)
- intonation units (3)
- intracellular-transport (3)
- intraclass correlation (3)
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- intrinsically disordered proteins (3)
- intuition (3)
- invasion (3)
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- ionogel (3)
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- islands (3)
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- iterative regularization (3)
- job satisfaction (3)
- job search (3)
- junge Erwachsene (3)
- just transition (3)
- kana (3)
- kanji (3)
- keratinocytes (3)
- kernel density estimation (3)
- kernel methods (3)
- kettle hole (3)
- kinetic instabilities (3)
- knowledge sharing (3)
- kognitive Modellierung (3)
- kollektives Gedächtnis (3)
- kommunale Demokratie (3)
- kommunale Entscheidungsprozesse (3)
- komplexes Netzwerk (3)
- körperliche Fitness (3)
- l-cysteine desulfurase (3)
- lactate (3)
- lactate threshold (3)
- land cover change (3)
- land-use (3)
- landscape diversity (3)
- landscape homogenization (3)
- langevin equation (3)
- language attitudes (3)
- language courses (3)
- languages (3)
- large-scale (3)
- large-scale assessment (3)
- large-scale structure of Universe (3)
- last glacial period (3)
- late Holocene (3)
- latitude (3)
- latitudinal gradient (3)
- leaf (3)
- leaf development (3)
- leaf senescence (3)
- leaking (3)
- learning factories (3)
- learning factory (3)
- learning styles (3)
- lebenslanges Lernen (3)
- lesson evaluation (3)
- lexical development (3)
- lexical tones (3)
- liberalism (3)
- life course (3)
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- limits (3)
- line: profiles (3)
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- literatures of the world (3)
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- livestock (3)
- load (3)
- local (3)
- local governance (3)
- locus of control (3)
- logarithmic source condition (3)
- lokale Anpassung (3)
- long-distance dispersal (3)
- losses (3)
- lower thermosphere (3)
- lupin (3)
- lysosomal storage disorders (3)
- lysosome (3)
- mAb disposition (3)
- magnetic reconnection (3)
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- magnitude estimation (3)
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- major depression (3)
- majority rule (3)
- manufacturing (3)
- marine terrace (3)
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- masculinity (3)
- mass index (3)
- mass media (3)
- mass wasting (3)
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- matching (3)
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- mathematical precursor (3)
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- media education (3)
- medicine (3)
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- method (3)
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- microemulsion (3)
- microgel (3)
- micropolitics (3)
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- microwave irradiation (3)
- migrants (3)
- military culture (3)
- military history (3)
- miniemulsion (3)
- minimax convergence rates (3)
- mining lakes (3)
- minorities (3)
- missing-VP effect (3)
- mitochondrial dysfunction (3)
- mitogenome (3)
- mitogenomes (3)
- mittlere Kindheit (3)
- modal verbs (3)
- modality compatibility (3)
- model coupling (3)
- model transformation (3)
- model-driven engineering (3)
- modellgetriebene Entwicklung (3)
- moderne jüdische Geschichte (3)
- modularity (3)
- molecular doping (3)
- molybdoenzyme (3)
- monoclonal antibody (3)
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- monomer (3)
- monomers (3)
- morality (3)
- morpho-orthography (3)
- morphological decomposition (3)
- morphological priming (3)
- morphological structure (3)
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- neutron (3)
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- niche width (3)
- nichtlineare Optik (3)
- noisy systems (3)
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- octopamine (3)
- offspring (3)
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- online (3)
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- origin (3)
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- oxygen isotopes (3)
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- palaeolimnology (3)
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- paper (3)
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- parallel processing (3)
- parameterization (3)
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- particles (3)
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- phase (3)
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- poly(A) polymerase (3)
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- reaction mechanisms (3)
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- real-time (3)
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- stars: (3)
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- ) (2)
- 1 (2)
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Achromatium oxaliferum is a large sulfur bacterium easily recognized by large intracellular calcium carbonate bodies. Although these bodies often fill major parts of the cells' volume, their role and specific intracellular location are unclear. In this study, we used various microscopy and staining techniques to identify the cell compartment harboring the calcium carbonate bodies. We observed that Achromatium cells often lost their calcium carbonate bodies, either naturally or induced by treatments with diluted acids, ethanol, sodium bicarbonate and UV radiation which did not visibly affect the overall shape and motility of the cells (except for UV radiation). The water-soluble fluorescent dye fluorescein easily diffused into empty cavities remaining after calcium carbonate loss. Membranes (stained with Nile Red) formed a network stretching throughout the cell and surrounding empty or filled calcium carbonate cavities. The cytoplasm (stained with FITC and SYBR Green for nucleic acids) appeared highly condensed and showed spots of dissolved Ca2+ (stained with Fura-2). From our observations, we conclude that the calcium carbonate bodies are located in the periplasm, in extra-cytoplasmic pockets of the cytoplasmic membrane and are thus kept separate from the cell's cytoplasm. This periplasmic localization of the carbonate bodies might explain their dynamic formation and release upon environmental changes.
Achromatium oxaliferum is a large sulfur bacterium easily recognized by large intracellular calcium carbonate bodies. Although these bodies often fill major parts of the cells' volume, their role and specific intracellular location are unclear. In this study, we used various microscopy and staining techniques to identify the cell compartment harboring the calcium carbonate bodies. We observed that Achromatium cells often lost their calcium carbonate bodies, either naturally or induced by treatments with diluted acids, ethanol, sodium bicarbonate and UV radiation which did not visibly affect the overall shape and motility of the cells (except for UV radiation). The water-soluble fluorescent dye fluorescein easily diffused into empty cavities remaining after calcium carbonate loss. Membranes (stained with Nile Red) formed a network stretching throughout the cell and surrounding empty or filled calcium carbonate cavities. The cytoplasm (stained with FITC and SYBR Green for nucleic acids) appeared highly condensed and showed spots of dissolved Ca2+ (stained with Fura-2). From our observations, we conclude that the calcium carbonate bodies are located in the periplasm, in extra-cytoplasmic pockets of the cytoplasmic membrane and are thus kept separate from the cell's cytoplasm. This periplasmic localization of the carbonate bodies might explain their dynamic formation and release upon environmental changes.
Lake sediments are increasingly explored as reliable paleoflood archives. In addition to established flood proxies including detrital layer thickness, chemical composition, and grain size, we explore stable oxygen and carbon isotope data as paleoflood proxies for lakes in catchments with carbonate bedrock geology. In a case study from Lake Mondsee (Austria), we integrate high-resolution sediment trapping at a proximal and a distal location and stable isotope analyses of varved lake sediments to investigate flood-triggered detrital sediment flux. First, we demonstrate a relation between runoff, detrital sediment flux, and isotope values in the sediment trap record covering the period 2011-2013 CE including 22 events with daily (hourly) peak runoff ranging from 10 (24) m(3) s(-1) to 79 (110) m(3) s(-1). The three- to ten-fold lower flood-triggered detrital sediment deposition in the distal trap is well reflected by attenuated peaks in the stable isotope values of trapped sediments. Next, we show that all nine flood-triggered detrital layers deposited in a sediment record from 1988 to 2013 have elevated isotope values compared with endogenic calcite. In addition, even two runoff events that did not cause the deposition of visible detrital layers are distinguished by higher isotope values. Empirical thresholds in the isotope data allow estimation of magnitudes of the majority of floods, although in some cases flood magnitudes are overestimated because local effects can result in too-high isotope values. Hence we present a proof of concept for stable isotopes as reliable tool for reconstructing flood frequency and, although with some limitations, even for flood magnitudes.
Diet analysis of bats killed at wind turbines suggests large-scale losses of trophic interactions
(2022)
Agricultural practice has led to landscape simplification and biodiversity decline, yet recently, energy-producing infrastructures, such as wind turbines, have been added to these simplified agroecosystems, turning them into multi-functional energy-agroecosystems. Here, we studied the trophic interactions of bats killed at wind turbines using a DNA metabarcoding approach to shed light on how turbine-related bat fatalities may possibly affect local habitats. Specifically, we identified insect DNA in the stomachs of common noctule bats (Nyctalus noctula) killed by wind turbines in Germany to infer in which habitats these bats hunted. Common noctule bats consumed a wide variety of insects from different habitats, ranging from aquatic to terrestrial ecosystems (e.g., wetlands, farmland, forests, and grasslands). Agricultural and silvicultural pest insects made up about 20% of insect species consumed by the studied bats. Our study suggests that the potential damage of wind energy production goes beyond the loss of bats and the decline of bat populations. Bat fatalities at wind turbines may lead to the loss of trophic interactions and ecosystem services provided by bats, which may add to the functional simplification and impaired crop production, respectively, in multi-functional ecosystems.
The sediment profile from Lake Goscia(z) over dot in central Poland comprises a continuous, seasonally resolved and exceptionally well-preserved archive of the Younger Dryas (YD) climate variation. This provides a unique opportunity for detailed investigation of lake system responses during periods of rapid climate cooling (YD onset) and warming (YD termination). The new varve record of Lake Goscia(z) over dot presented here spans 1662 years from the late Allerod (AL) to the early Preboreal (PB). Microscopic varve counting provides an independent chronology with a YD duration of 1149+14/-22 years, which confirms previous results of 1140 +/- 40 years. We link stable oxygen isotopes and chironomid-based air temperature reconstructions with the response of various geochemical and varve microfacies proxies especially focusing on the onset and termination of the YD. Cooling at the YD onset lasted similar to 180 years, which is about a century longer than the terminal warming that was completed in similar to 70 years. During the AL/YD transition, environmental proxy data lagged the onset of cooling by similar to 90 years and revealed an increase of lake productivity and internal lake re-suspension as well as slightly higher detrital sediment input. In contrast, rapid warming and environmental changes during the YD/PB transition occurred simultaneously. However, initial changes such as declining diatom deposition and detrital input occurred already a few centuries before the rapid warming at the YD/PB transition. These environmental changes likely reflect a gradual increase in summer air temperatures already during the YD. Our data indicate complex and differing environmental responses to the major climate changes related to the YD, which involve different proxy sensitivities and threshold processes.
Large rock slope failures play a pivotal role in long-term landscape evolution and are a major concern in land use planning and hazard aspects. While the failure phase and the time immediately prior to failure are increasingly well studied, the nature of the preparation phase remains enigmatic. This knowledge gap is due, to a large degree, to difficulties associated with instrumenting high mountain terrain and the local nature of classic monitoring methods, which does not allow integral observation of large rock volumes. Here, we analyse data from a small network of up to seven seismic sensors installed during July-October 2018 (with 43 days of data loss) at the summit of the Hochvogel, a 2592 m high Alpine peak. We develop proxy time series indicative of cyclic and progressive changes of the summit. Modal analysis, horizontal-to-vertical spectral ratio data and end-member modelling analysis reveal diurnal cycles of increasing and decreasing coupling stiffness of a 260,000 m(3) large, instable rock volume, due to thermal forcing. Relative seismic wave velocity changes also indicate diurnal accumulation and release of stress within the rock mass. At longer time scales, there is a systematic superimposed pattern of stress increased over multiple days and episodic stress release within a few days, expressed in an increased emission of short seismic pulses indicative of rock cracking. Our data provide essential first order information on the development of large-scale slope instabilities towards catastrophic failure. (c) 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd
The Big Naryn Complex (BNC) in the East Djetim-Too Range of the Kyrgyz Middle Tianshan block is a tectonized, at least 2 km thick sequence of predominantly felsic to intermediate volcanic rocks intruded by porphyric rhyolite sills. It overlies a basement of metamorphic rocks and is overlain by late Neoproterozoic Djetim-Too Formation sediments; these also occur as tectonic intercalations in the BNC. The up to ca. 1100 m thick Lower Member is composed of predominantly rhyolites-to-dacites and minor basalts, while the at least 900 m thick pyroclastic Upper Member is dominated by rhyolitic-to-dacitic ignimbrites. Porphyric rhyolite sills are concentrated at the top of the Lower Member. A Lower Member rhyolite and a sill sample have LA-ICP-MS U-Pb zircon crystallization ages of 726.1 +/- 2.2 Ma and 720.3 +/- 6.5 Ma, respectively, showing that most of the magmatism occurred within a short time span in the late Tonian-early Cryogenian. Inherited zircons in the sill sample have Neoarchean (2.63, 2.64 Ga), Paleo- (2.33-1.81 Ga), Meso- (1.55 Ga), and Neoproterozoic (ca. 815 Ma) ages, and were derived from a heterogeneous Kuilyu Complex basement. A 1751 +/- 7 Ma Ar-40/Ar-39 age for amphibole from metagabbro is the age of cooling subsequent to Paleoproterozoic metamorphism of the Kuilyu Complex. The large amount of pyroclastic rocks, and their major and trace element compositions, the presence of Neoarchean to Neoproterozoic inherited zircons and a depositional basement of metamorphic rocks point to formation of the BNC in a continental magmatic arc setting.
The catalytic activity of metal nanoparticles (NPs) supported on porous supports can be controlled by various factors, such as NPs size, shape, or dispersivity, as well as their interaction with the support or the properties of the support material itself. However, these intrinsic properties are not solely responsible for the catalytic behavior of the overall reaction system, as the local environment and surface coverage of the catalyst with reactants, products, intermediates and other invloved species often play a crucial role in catalytic processes as well. Their contribution can be particularly critical in liquid-phase reactions with gaseous reactants that often suffer from low solubiltiy. One example is (D)-glucose oxidation with molecular oxygen over gold nanoparticles supported on porous carbons. The possibility to promote oxygen delivery in such aqueous phase oxidation reactions via the immobilization of heterogenous catalysts onto the interface of perfluorocarbon emulsion droplets is reported here. Gold-on-carbon catalyst particles can stabilize perfluorocarbon droplets in the aqueous phase and the local concentration of the oxidant in the surroundings of the gold nanoparticles accelerates the rate-limiting step of the reaction. Consequently, the reaction rate of a system with the optimal volume fraction of fluorocarbon is higher than a reference emulsion system without fluorocarbon, and the effect is observed even without additional oxygen supply.
Openness indicators for the evaluation of digital platforms between the launch and maturity phase
(2024)
In recent years, the evaluation of digital platforms has become an important focus in the field of information systems science. The identification of influential indicators that drive changes in digital platforms, specifically those related to openness, is still an unresolved issue. This paper addresses the challenge of identifying measurable indicators and characterizing the transition from launch to maturity in digital platforms. It proposes a systematic analytical approach to identify relevant openness indicators for evaluation purposes. The main contributions of this study are the following (1) the development of a comprehensive procedure for analyzing indicators, (2) the categorization of indicators as evaluation metrics within a multidimensional grid-box model, (3) the selection and evaluation of relevant indicators, (4) the identification and assessment of digital platform architectures during the launch-to-maturity transition, and (5) the evaluation of the applicability of the conceptualization and design process for digital platform evaluation.
Global change is shifting the timing of biological events, leading to temporal mismatches between biological events and resource availability. These temporal mismatches can threaten species' populations. Importantly, temporal mismatches not only exert strong pressures on the population dynamics of the focal species, but can also lead to substantial changes in pairwise species interactions such as host-pathogen systems. We adapted an established individual-based model of host-pathogen dynamics. The model describes a viral agent in a social host, while accounting for the host's explicit movement decisions. We aimed to investigate how temporal mismatches between seasonal resource availability and host life-history events affect host-pathogen coexistence, that is, disease persistence. Seasonal resource fluctuations only increased coexistence probability when in synchrony with the hosts' biological events. However, a temporal mismatch reduced host-pathogen coexistence, but only marginally. In tandem with an increasing temporal mismatch, our model showed a shift in the spatial distribution of infected hosts. It shifted from an even distribution under synchronous conditions toward the formation of disease hotspots, when host life history and resource availability mismatched completely. The spatial restriction of infected hosts to small hotspots in the landscape initially suggested a lower coexistence probability due to the critical loss of susceptible host individuals within those hotspots. However, the surrounding landscape facilitated demographic rescue through habitat-dependent movement. Our work demonstrates that the negative effects of temporal mismatches between host resource availability and host life history on host-pathogen coexistence can be reduced through the formation of temporary disease hotspots and host movement decisions, with implications for disease management under disturbances and global change.
Peer assessment in MOOCs
(2021)
We report on a systematic review of the landscape of peer assessment in massive open online courses (MOOCs) with papers from 2014 to 2020 in 20 leading education technology publication venues across four databases containing education technology-related papers, addressing three research issues: the evolution of peer assessment in MOOCs during the period 2014 to 2020, the methods used in MOOCs to assess peers, and the challenges of and future directions in MOOC peer assessment. We provide summary statistics and a review of methods across the corpus and highlight three directions for improving the use of peer assessment in MOOCs: the need for focusing on scaling learning through peer evaluations, the need for scaling and optimizing team submissions in team peer assessments, and the need for embedding a social process for peer assessment.
In the data analysis of oscillatory systems, methods based on phase reconstruction are widely used to characterize phase-locking properties and inferring the phase dynamics. The main component in these studies is an extraction of the phase from a time series of an oscillating scalar observable. We discuss a practical procedure of phase reconstruction by virtue of a recently proposed method termed iterated Hilbert transform embeddings. We exemplify the potential benefits and limitations of the approach by applying it to a generic observable of a forced Stuart-Landau oscillator. Although in many cases, unavoidable amplitude modulation of the observed signal does not allow for perfect phase reconstruction, in cases of strong stability of oscillations and a high frequency of the forcing, iterated Hilbert transform embeddings significantly improve the quality of the reconstructed phase. We also demonstrate that for significant amplitude modulation, iterated embeddings do not provide any improvement.
In many species, dispersal is decisive for survival in a changing climate. Simulation models for population dynamics under climate change thus need to account for this factor. Moreover, large numbers of species inhabiting agricultural landscapes are subject to disturbances induced by human land use. We included dispersal in the HiLEG model that we previously developed to study the interaction between climate change and agricultural land use in single populations. Here, the model was parameterized for the large marsh grasshopper (LMG) in cultivated grasslands of North Germany to analyze (1) the species development and dispersal success depending on the severity of climate change in subregions, (2) the additional effect of grassland cover on dispersal success, and (3) the role of dispersal in compensating for detrimental grassland mowing. Our model simulated population dynamics in 60-year periods (2020-2079) on a fine temporal (daily) and high spatial (250 x 250 m(2)) scale in 107 subregions, altogether encompassing a range of different grassland cover, climate change projections, and mowing schedules. We show that climate change alone would allow the LMG to thrive and expand, while grassland cover played a minor role. Some mowing schedules that were harmful to the LMG nevertheless allowed the species to moderately expand its range. Especially under minor climate change, in many subregions dispersal allowed for mowing early in the year, which is economically beneficial for farmers. More severe climate change could facilitate LMG expansion to uninhabited regions but would require suitable mowing schedules along the path. These insights can be transferred to other species, given that the LMG is considered a representative of grassland communities. For more specific predictions on the dynamics of other species affected by climate change and land use, the publicly available HiLEG model can be easily adapted to the characteristics of their life cycle.
As the focus on digital transformation and its unexplored opportunities is prospering, consulting firms have also turned their attention to it. Despite this increased attention, digital transformation project failure rate remains high, thereby reaffirming the “IT productivity paradox” or “AI productivity paradox. The purpose of this paper is to holistically scrutinize the current approach of digital transformation consulting. A deductive qualitative study draws upon the Human Technology Performance model to elucidate papers on digital transformation published by four major management consulting firms in 2014-2019. Whereas the focus on customer-centricity and some measures of corporate performance is prominent in the consulting approaches, the study results have revealed several “blind spots” that are still either neglected or poorly covered. Three main blind spots are particularly prominent from the analysis. First of all, consulting firms often apply a “one size fits all” approach, thereby neglecting contextual factors, such as age, size, or industry. Secondly, they neglect process level in the return on investment of IT. Thirdly, the suitability of IS development methods remains poorly considered. Hence, the paper argues that, while consulting firms purport to support digital transformation exigences and efforts, they, in fact, adhere to traditional approaches to business consulting.
Die Digitalisierung des deutschen Mittelstandes schreitet weiterhin schleppend voran. So verfügt zwar ein wachsender Teil dieser Unternehmen über vereinzelte Informations- und Kommunikationssysteme, die zielführende Vernetzung und Integration dieser Systeme stellt jedoch weiterhin eine große Aufgabe dar [1]. Besonders vor dem Hintergrund wachsender Bedürfnisse für Informationen und Transparenz sehen sich Unternehmen zunehmend mit der analyseorientierten Nutzbarmachung der Unternehmensdaten konfrontiert [2].
The Walker Circulation (WC) is an east-west trending band of atmospheric circulation cells along the equator and the predominant controller of heat and moisture transport in the tropics. Its variability is closely linked to the sea-surface temperature (SST) changes across the Pacific, the Indian and the Atlantic Oceans and can have pronounced effects on the humidity regimes of the adjacent continents. In recent years, the evolution of the WC during the Plioand Pleistocene epochs has been intensely studied in the context of the effectiveness of the tropics in modulating global climate change (e.g., the intensification of Northern Hemisphere glaciation). However, the onset of the modern WC pattern as well as its global impact during the Plioand Pleistocene is controversially assessed in the literature. For its onset, previous studies have suggested dates ranging between 2.4 and 0.8 million years ago (Myr), while its argued impact ranges from crucially influencing the increase of Northern Hemisphere ice sheet growth by channelling heat and moisture from the tropics into the high latitudes to having no effect on global ice volume changes. In order to achieve a comprehensive understanding of the spatiotemporal evolution of the WC during this time frame, we statistically analysed 30 globally distributed SST records covering the low and high latitudes between 3.5 and 1.5 Myr, encompassing the Late Pliocene to Early Pleistocene. We utilized a statistical change-point regression model to determine significant change points in the SST evolution of the (sub)-tropics and high latitudes that potentially relate to changes in the WC. We find that the WC experienced a multifaceted evolution between the Late Pliocene and the Early Pleistocene with significant transitional steps at-2.7 and-2.1 Ma. Our results suggest after the Late Pliocene, a pre-modern WC set in, which was characterized by a progressively strengthened Pacific Walker Cell alongside a weakened Indian Ocean Walker Cell. This change was potentially triggered by the constriction of the Indonesian seaway, an important transmitter between the Pacific and Indian Ocean. The ensuing mode of the WC intensified until-2.1 Myr, when SST values around the global scale signalled a progressive strengthening of the Indian Walker Cell in phase with the progressive strengthening of the Pacific and Atlantic Cells. Our findings indicate that a shift from a pre-modern to a modern-like WC potentially only occurred during the mid-Pleistocene.
The increasing demand for software engineers cannot completely be fulfilled by university education and conventional training approaches due to limited capacities. Accordingly, an alternative approach is necessary where potential software engineers are being educated in software engineering skills using new methods. We suggest micro tasks combined with theoretical lessons to overcome existing skill deficits and acquire fast trainable capabilities. This paper addresses the gap between demand and supply of software engineers by introducing an actionoriented and scenario-based didactical approach, which enables non-computer scientists to code. Therein, the learning content is provided in small tasks and embedded in learning factory scenarios. Therefore, different requirements for software engineers from the market side and from an academic viewpoint are analyzed and synthesized into an integrated, yet condensed skills catalogue. This enables the development of training and education units that focus on the most important skills demanded on the market. To achieve this objective, individual learning scenarios are developed. Of course, proper basic skills in coding cannot be learned over night but software programming is also no sorcery.
Einleitung
(2021)
Der Einsatz digitaler Personalzeiterfassungssysteme bietet Unternehmen zahlreiche Vorteile, z. B. effizientere Lohn- und Gehaltsabrechnungen, mehr Transparenz und Übersicht über die Arbeitszeiten der Mitarbeiter sowie flexiblere Erfassungsmöglichkeiten. In der Testreihe werden neun Lösungen auf Funktionen, Benutzerfreundlichkeit, Kosten, Zuverlässigkeit, Kompatibilität, Implementierung und Barrierefreiheit getestet. Erfahren Sie, welche Lösungen am besten abschneiden und ob eine davon für Ihr Unternehmen geeignet ist.
Der nutzbringenden Einsatz einer Datenbrille besteht nicht nur aus der Brille selbst. Die potenzielle ressourcenschonende Assistenz bei der Abarbeitung von komplexen Workflows bedarf eine ausreichende Integration in die Anwendungssystemlandschaft. Implikation sind demnach zwei Hauptelemente: die Brille selbst und die Integrationssoftware. Beide Komponenten sind in geeigneter Form auszulegen und auf die intendierten Anwendungsfälle zu konfigurieren. Dieser Beitrag fasst die Erfahrungen aus zahlreichen Projekten zusammen und liefert einen Überblick über die Herausforderungen bei AR-Einführungen.
Der nutzbringende Einsatz einer Datenbrille besteht nicht nur aus der Brille selbst. Die potenzielle ressourcenschonende Assistenz bei der Abarbeitung von komplexen Workflows bedarf einer ausreichenden Integration in die Anwendungssystemlandschaft. Dafür sind Brille und Integrationssoftware in geeigneter Form auszulegen und auf die intendierten Anwendungsfälle zu konfigurieren.
Im Zentrum Industrie 4.0 Potsdam (ZIP 4.0) kann diese Frage individuell und ohne großen Aufwand beantwortet werden. Mehr noch, mit Hilfe der hybriden Simulationsumgebung ist die Interaktion mit dem AR-Gerät durch den Akteur innerhalb von Fertigungsprozessen möglich. So kann nicht nur der Nutzen demonstriert, sondern auch durch den tatsächlichen Einsatz innerhalb der realitätsnahen Prozessabbildung die Akzeptanz für die spätere Nutzung geschaffen werden.
ControlCenter 4.0
(2021)
In der Theorie bieten dezentrale Steuerungsansätze im Produktionskontext einige Vorteile gegenüber monolithischen Zentralsystemen, die sämtliche Funktionen in einer oder wenigen Instanzen vereinen. Allerdings bedarf die praktischen Umsetzung der Anpassung des allgemeinen Konzepts der Dezentralität an die individuellen und spezifischen Anwendungsfälle insbesondere hinsichtlich ihres sinnvollen Umfangs. Ein Anwendungsfall ist die Montage von variantenreichen Produkten. Der vorliegende Beitrag zeigt, wie mittels der geeigneten Kombination von zentralen und dezentralen Ansätzen eine bessere Planbarkeit und Steigerung des Durchsatzes erreicht werden kann. Mit einer flexiblen Taktsteuerung der Arbeitsstationen und geeigneter Assistenz am Montagearbeitsplatz kann die bisherige werkstatt-orientierte Organisation zu einer serienähnlichen Fertigung transformiert werden. Dies geschieht unter Einsatz einer mehrschichtigen Infrastruktur, die den Industrie 4.0-Paradigmen der dezentralen Informationsverarbeitung durch autonome vernetzte Systeme folgt.
Um in der digitalisierten Wirtschaft mitzuspielen, müssen Unternehmen, Markt und insbesondere Kunden detailliert verstanden werden. Neben den „Big Playern“ aus dem Silicon Valley sieht der deutsche Mittelstand, der zu großen Teilen noch auf gewachsenen IT-Infrastrukturen und Prozessen agiert, oft alt aus. Um in den nächsten Jahren nicht gänzlich abgehängt zu werden, ist ein Umbruch notwendig. Sowohl Leistungserstellungsprozesse als auch Leistungsangebot müssen transparent und datenbasiert ausgerichtet werden. Nur so können Geschäftsvorfälle, das Marktgeschehen sowie Handeln der Akteure integrativ bewertet und fundierte Entscheidungen getroffen werden. In diesem Beitrag wird das Konzept der Data-Driven Organization vorgestellt und aufgezeigt, wie Unternehmen den eigenen Analyticsreifegrad ermitteln und in einem iterativen Transformationsprozess steigern können.
Für die Transformation der industriellen Fertigung stellt die Integration der Realwelt und die parallele Abbildung in der Digitalwelt eine wichtige Anforderung dar. Hier greift das Konzept des digitalen Zwillings zur digitalen Repräsentation physischer Objekte. Zur Verbesserung der Mensch-Maschinen-Interaktion zwischen Fabrikpersonal, Anlagen sowie Werkstücken und Steigerung der Transparenz am Shopfloor, kann ein solcher digitaler Zwilling relevante Daten liefern. In diesem Beitrag wird ein Konzept zur Visualisierung des digitalen Zwillings mittels Augmented Reality vorgestellt und evaluiert.
For the last 20 years, enterprise architecture management (EAM) was primarily an instrument for harmonizing and consolidating IT landscapes and is lived as a transformation and governance discipline. It, however, is rather related to IT strategy than aligned to the actual corporate strategy and the work of the enterprise architect is characterized by tasks like prescribing, monitoring, documenting, and controlling. As digital transformation continues apace, companies are facing new challenges that lead to a volatile, uncertain, complex, and ambiguous (VUCA) world. To face these challenges, vision, understanding, clarity and agility allow to anticipative and implement necessary changes. This, of course, has implications for the role of the enterprise architect. S/he needs to start actively supporting innovation and taking more of an advisory role instead of just being driven by the current state of the enterprise architecture. This paper investigates the role of the enterprise architect in the VUCA world. Based on current literature and expert interviews, a survey was conducted among consultants who work as (or with) enterprise architects. Survey results include the evaluation of statements on current tasks of enterprise architects, their influence on projects and companies as well as future requirements on the roles of the enterprise architect. The results from the survey were synthesized with the findings from literature to derive the roles, tasks and skills of enterprise architect in the VUCA world.
Cell-free protein synthesis (CFPS) represents a versatile key technology for the production of toxic proteins. As a cell lysate, rather than viable cells, is used, the toxic effects on the host organism can be circumvented. The open nature of cell-free systems allows for the addition of supplements affecting protein concentration and folding. Here, we present the cell-free synthesis and functional characterization of two AB(5) toxins, namely the cholera toxin (Ctx) and the heat-labile enterotoxin (LT), using two eukaryotic cell-free systems based on Chinese hamster ovary (CHO) and Spodoptera frugiperda (Sf21) cells. Through an iterative optimization procedure, the synthesis of the individual AB(5) toxins was established, and the formation of multimeric structures could be shown by autoradiography. A functional analysis was performed using cell-based assays, thereby demonstrating that the LT complex induced the characteristic cell elongation of target cells after 24 h. The LT complex induced cell death at higher concentrations, starting at an initial concentration of 5 nM. The initial toxic effects of the Ctx multimer could already be detected at 4 nM. The detection and characterization of such AB(5) toxins is of utmost importance, and the monitoring of intracellular trafficking facilitates the further identification of the mechanism of action of these toxins. We showed that the B-subunit of LT (LTB) could be fluorescently labeled using an LTB-Strep fusion protein, which is a proof-of-concept for future Trojan horse applications. Further, we performed a mutational analysis of the CtxA subunit as its template was modified, and an amber stop codon was inserted into CtxA's active site. Subsequently, a non-canonical amino acid was site-specifically incorporated using bio-orthogonal systems. Finally, a fluorescently labeled CtxA protein was produced using copper-catalyzed click reactions as well as a Staudinger ligation. As expected, the modified Ctx multimer no longer induced toxic effects. In our study, we showed that CFPS could be used to study the active centers of toxins by inserting mutations. Additionally, this methodology can be applied for the design of Trojan horses and targeted toxins, as well as enabling the intracellular trafficking of toxins as a prerequisite for the analysis of the toxin's mechanism of action.
Advances in characteristics improvement of polymeric membranes/separators for zinc-air batteries
(2022)
Zinc-air batteries (ZABs) are gaining popularity for a wide range of applications due to their high energy density, excellent safety, and environmental friendliness. A membrane/separator is a critical component of ZABs, with substantial implications for battery performance and stability, particularly in the case of a battery in solid state format, which has captured increased attention in recent years. In this review, recent advances as well as insight into the architecture of polymeric membrane/separators for ZABs including porous polymer separators (PPSs), gel polymer electrolytes (GPEs), solid polymer electrolytes (SPEs) and anion exchange membranes (AEMs) are discussed. The paper puts forward strategies to enhance stability, ionic conductivity, ionic selectivity, electrolyte storage capacity and mechanical properties for each type of polymeric membrane. In addition, the remaining major obstacles as well as the most potential avenues for future research are examined in detail.
Vegetation with an adequate supply of water might contribute to cooling the land surface around it through the latent heat flux of transpiration. This study investigates the potential estimation of evaporative cooling at plot scale, using soybean as example. Some of the plants' physiological parameters were monitored and sampled at weekly intervals. A physics-based model was then applied to estimate the irrigation-induced cooling effect within and above the canopy during the middle and late season of the soybean growth period. We then examined the results of the temperature changes at a temporal resolution of ten minutes between every two irrigation rounds. During the middle and late season of growth, the cooling effects caused by evapotranspiration within and above the canopy were, on average, 4.4 K and 2.9 K, respectively. We used quality indicators such as R-squared (R-2) and mean absolute error (MAE) to evaluate the performance of the model simulation. The performance of the model in this study was better above the canopy (R-2 = 0.98, MAE = 0.3 K) than below (R-2 = 0.87, MAE = 0.9 K) due to the predefined thermodynamic condition used to estimate evaporative cooling. Moreover, the study revealed that canopy cooling contributes to mitigating heat stress conditions during the middle and late seasons of crop growth.
The African weakly electric fishes (Mormyridae) exhibit a remarkable adaptive radiation possibly due to their species-specific electric organ discharges (EODs). It is produced by a muscle-derived electric organ that is located in the caudal peduncle. Divergence in EODs acts as a pre-zygotic isolation mechanism to drive species radiations. However, the mechanism behind the EOD diversification are only partially understood.
The aim of this study is to explore the genetic basis of EOD diversification from the gene expression level across Campylomormyrus species/hybrids and ontogeny. I firstly produced a high quality genome of the species C. compressirostris as a valuable resource to understand the electric fish evolution.
The next study compared the gene expression pattern between electric organs and skeletal muscles in Campylomormyrus species/hybrids with different types of EOD duration. I identified several candidate genes with an electric organ-specific expression, e.g. KCNA7a, KLF5, KCNJ2, SCN4aa, NDRG3, MEF2. The overall genes expression pattern exhibited a significant association with EOD duration in all analyzed species/hybrids. The expression of several candidate genes, e.g. KCNJ2, KLF5, KCNK6 and KCNQ5, possibly contribute to the regulation of EOD duration in Campylomormyrus due to their increasing or decreasing expression. Several potassium channel genes showed differential expression during ontogeny in species and hybrid with EOD alteration, e.g. KCNJ2.
I next explored allele specific expression of intragenus hybrids by crossing the duration EOD species C. compressirostris with the medium duration EOD species C. tshokwe and the elongated duration EOD species C. rhynchophorus. The hybrids exhibited global expression dominance of the C. compressirostris allele in the adult skeletal muscle and electric organ, as well as in the juvenile electric organ. Only the gene KCNJ2 showed dominant expression of the allele from C. rhynchophorus, and this was increasingly dominant during ontogeny. It hence supported our hypothesis that KCNJ2 is a key gene of regulating EOD duration. Our results help us to understand, from a genetic perspective, how gene expression effect the EOD diversification in the African weakly electric fish.
Protected cultivation in greenhouses or polytunnels offers the potential for sustainable production of high-yield, high-quality vegetables. This is related to the ability to produce more on less land and to use resources responsibly and efficiently. Crop yield has long been considered the most important factor. However, as plant-based diets have been proposed for a sustainable food system, the targeted enrichment of health-promoting plant secondary metabolites should be addressed. These metabolites include carotenoids and flavonoids, which are associated with several health benefits, such as cardiovascular health and cancer protection.
Cover materials generally have an influence on the climatic conditions, which in turn can affect the levels of secondary metabolites in vegetables grown underneath. Plastic materials are cost-effective and their properties can be modified by incorporating additives, making them the first choice. However, these additives can migrate and leach from the material, resulting in reduced service life, increased waste and possible environmental release. Antifogging additives are used in agricultural films to prevent the formation of droplets on the film surface, thereby increasing light transmission and preventing microbiological contamination.
This thesis focuses on LDPE/EVA covers and incorporated antifogging additives for sustainable protected cultivation, following two different approaches. The first addressed the direct effects of leached antifogging additives using simulation studies on lettuce leaves (Lactuca sativa var capitata L). The second determined the effect of antifog polytunnel covers on lettuce quality. Lettuce is usually grown under protective cover and can provide high nutritional value due to its carotenoid and flavonoid content, depending on the cultivar.
To study the influence of simulated leached antifogging additives on lettuce leaves, a GC-MS method was first developed to analyze these additives based on their fatty acid moieties. Three structurally different antifogging additives (reference material) were characterized outside of a polymer matrix for the first time. All of them contained more than the main fatty acid specified by the manufacturer. Furthermore, they were found to adhere to the leaf surface and could not be removed by water or partially by hexane.
The incorporation of these additives into polytunnel covers affects carotenoid levels in lettuce, but not flavonoids, caffeic acid derivatives and chlorophylls. Specifically, carotenoids were higher in lettuce grown under polytunnels without antifog than with antifog. This has been linked to their effect on the light regime and was suggested to be related to carotenoid function in photosynthesis.
In terms of protected cultivation, the use of LDPE/EVA polytunnels affected light and temperature, and both are closely related. The carotenoid and flavonoid contents of lettuce grown under polytunnels was reversed, with higher carotenoid and lower flavonoid levels. At the individual level, the flavonoids detected in lettuce did not differ however, lettuce carotenoids adapted specifically depending on the time of cultivation. Flavonoid reduction was shown to be transcriptionally regulated (CHS) in response to UV light (UVR8). In contrast, carotenoids are thought to be regulated post-transcriptionally, as indicated by the lack of correlation between carotenoid levels and transcripts of the first enzyme in carotenoid biosynthesis (PSY) and a carotenoid degrading enzyme (CCD4), as well as the increased carotenoid metabolic flux. Understanding the regulatory mechanisms and metabolite adaptation strategies could further advance the strategic development and selection of cover materials.
Relativistic pair beams produced in the cosmic voids by TeV gamma rays from blazars are expected to produce a detectable GeV-scale cascade emission missing in the observations. The suppression of this secondary cascade implies either the deflection of the pair beam by intergalactic magnetic fields (IGMFs) or an energy loss of the beam due to the electrostatic beam-plasma instability. IGMF of femto-Gauss strength is sufficient to significantly deflect the pair beams reducing the flux of secondary cascade below the observational limits. A similar flux reduction may result in the absence of the IGMF from the beam energy loss by the instability before the inverse Compton cooling. This dissertation consists of two studies about the instability role in the evolution of blazar-induced beams.
Firstly, we investigated the effect of sub-fG level IGMF on the beam energy loss by the instability. Considering IGMF with correlation lengths smaller than a few kpc, we found that such fields increase the transverse momentum of the pair beam particles, dramatically reducing the linear growth rate of the electrostatic instability and hence the energy-loss rate of the pair beam. Our results show that the IGMF eliminates beam plasma instability as an effective energy-loss agent at a field strength three orders of magnitude below that needed to suppress the secondary cascade emission by magnetic deflection. For intermediate-strength IGMF, we do not know a viable process to explain the observed absence of GeV-scale cascade emission and hence can be excluded.
Secondly, we probed how the beam-plasma instability feeds back on the beam, using a realistic two-dimensional beam distribution. We found that the instability broadens the beam opening angles significantly without any significant energy loss, thus confirming a recent feedback study on a simplified one-dimensional beam distribution. However, narrowing diffusion feedback of the beam particles with Lorentz factors less than 1e6 might become relevant even though initially it is negligible. Finally, when considering the continuous creation of TeV pairs, we found that the beam distribution and the wave spectrum reach a new quasi-steady state, in which the scattering of beam particles persists and the beam opening angle may increase by a factor of hundreds. This new intrinsic scattering of the cascade can result in time delays of around ten years, thus potentially mimicking the IGMF deflection. Understanding the implications on the GeV cascade emission requires accounting for inverse Compton cooling and simulating the beam-plasma system at different points in the IGM.
The present dissertation investigates changes in lingual coarticulation across childhood in German-speaking children from three to nine years of age and adults. Coarticulation refers to the mismatch between the abstract phonological units and their seemingly commingled realization in continuous speech. Being a process at the intersection of phonology and phonetics, addressing its changes across childhood allows for insights in speech motor as well as phonological developments. Because specific predictions for changes in coarticulation across childhood can be derived from existing speech production models, investigating children’s coarticulatory patterns can help us model human speech production.
While coarticulatory changes may shed light on some of the central questions of speech production development, previous studies on the topic were sparse and presented a puzzling picture of conflicting findings. One of the reasons for this lack is the difficulty in articulatory data acquisition in a young population. Within the research program this dissertation is embedded in, we accepted this challenge and successfully set up the hitherto largest corpus of articulatory data from children using ultrasound tongue imaging. In contrast to earlier studies, a high number of participants in tight age cohorts across a wide age range and a thoroughly controlled set of pseudowords allowed for statistically powerful investigations of a process known as variable and complicated to track.
The specific focus of my studies is on lingual vocalic coarticulation as measured in the horizontal position of the highest point of the tongue dorsum. Based on three studies on a) anticipatory coarticulation towards the left, b) carryover coarticulation towards the right side of the utterance, and c) anticipatory coarticulatory extent in repeated versus read aloud speech, I deduct the following main theses:
1. Maturing speech motor control is responsible for some developmental changes in coarticulation.
2. Coarticulation can be modeled as the coproduction of articulatory gestures.
3. The developmental change in coarticulation results from a decrease of vocalic activation width.
In the aftermath of the Shoah and the ostensible triumph of nationalism, it became common in historiography to relegate Jews to the position of the “eternal other” in a series of binaries: Christian/Jewish, Gentile/Jewish, European/Jewish, non-Jewish/Jewish, and so forth. For the longest time, these binaries remained characteristic of Jewish historiography, including in the Central European context. Assuming instead, as the more recent approaches in Habsburg studies do, that pluriculturalism was the basis of common experience in formerly Habsburg Central Europe, and accepting that no single “majority culture” existed, but rather hegemonies were imposed in certain contexts, then the often used binaries are misleading and conceal the complex and sometimes even paradoxical conditions that shaped Jewish life in the region before the Shoah.
The very complexity of Habsburg Central Europe both in synchronic and diachronic perspective precludes any singular historical narrative of “Habsburg Jewry,” and it is not the intention of this volume to offer an overview of “Habsburg Jewish history.” The selected articles in this volume illustrate instead how important it is to reevaluate categories, deconstruct historical narratives, and reconceptualize implemented approaches in specific geographic, temporal, and cultural contexts in order to gain a better understanding of the complex and pluricultural history of the Habsburg Empire and the region as a whole.
Role of diversification rates and evolutionary history as a driver of plant naturalization success
(2020)
Human introductions of species beyond their natural ranges and their subsequent establishment are defining features of global environmental change. However, naturalized plants are not uniformly distributed across phylogenetic lineages, with some families contributing disproportionately more to the global alien species pool than others. Additionally, lineages differ in diversification rates, and high diversification rates have been associated with characteristics that increase species naturalization success. Here, we investigate the role of diversification rates in explaining the naturalization success of angiosperm plant families.
We use five global data sets that include native and alien plant species distribution, horticultural use of plants, and a time-calibrated angiosperm phylogeny. Using phylogenetic generalized linear mixed models, we analysed the effect of diversification rate, different geographical range measures, and horticultural use on the naturalization success of plant families.
We show that a family's naturalization success is positively associated with its evolutionary history, native range size, and economic use. Investigating interactive effects of these predictors shows that native range size and geographic distribution additionally affect naturalization success. High diversification rates and large ranges increase naturalization success, especially of temperate families.
We suggest this may result from lower ecological specialization in temperate families with large ranges, compared with tropical families with smaller ranges.
Manganese (Mn) and zinc (Zn) are not only essential trace elements, but also potential exogenous risk factors for various diseases. Since the disturbed homeostasis of single metals can result in detrimental health effects, concerns have emerged regarding the consequences of excessive exposures to multiple metals, either via nutritional supplementation or parenteral nutrition. This study focuses on Mn-Zn-interactions in the nematode Caenorhabditis elegans (C. elegans) model, taking into account aspects related to aging and age-dependent neurodegeneration.
Mycotoxins and pesticides regularly co-occur in agricultural products worldwide. Thus, humans can be exposed to both toxic contaminants and pesticides simultaneously, and multi-methods assessing the occurrence of various food contaminants and residues in a single method are necessary. A two-dimensional high performance liquid chromatography tandem mass spectrometry method for the analysis of 40 (modified) mycotoxins, two plant growth regulators, two tropane alkaloids, and 334 pesticides in cereals was developed. After an acetonitrile/water/formic acid (79:20:1, v/v/v) multi-analyte extraction procedure, extracts were injected into the two-dimensional setup, and an online clean-up was performed. The method was validated according to Commission Decision (EC) no. 657/2002 and document N° SANTE/12682/2019. Good linearity (R2 > 0.96), recovery data between 70-120%, repeatability and reproducibility values < 20%, and expanded measurement uncertainties < 50% were obtained for a wide range of analytes, including very polar substances like deoxynivalenol-3-glucoside and methamidophos. However, results for fumonisins, zearalenone-14,16-disulfate, acid-labile pesticides, and carbamates were unsatisfying. Limits of quantification meeting maximum (residue) limits were achieved for most analytes. Matrix effects varied highly (−85 to +1574%) and were mainly observed for analytes eluting in the first dimension and early-eluting analytes in the second dimension. The application of the method demonstrated the co-occurrence of different types of cereals with 28 toxins and pesticides. Overall, 86% of the samples showed positive findings with at least one mycotoxin, plant growth regulator, or pesticide.
Èto-clefts are Russian focus constructions with the demonstrative pronoun èto ‘this’ at the beginning: “Èto Mark vyigral gonku” (“It was Mark who won the race”). They are often being compared with English it-clefts, German es-clefts, as well as the corresponding focus-background structures in other languages.
In terms of semantics, èto-clefts have two important properties which are cross-linguistically typical for clefts: existence presupposition (“Someone won the race”) and exhaustivity (“Nobody except Mark won the race”). However, the exhaustivity effects are not as strong as exhaustivity effects in structures with the exclusive only and require more research.
At the same time, the question if the syntactic structure of èto-clefts matches the biclausal structure of English and German clefts, remains open. There are arguments in favor of biclausality, as well as monoclausality. Besides, there is no consistency regarding the status of èto itself.
Finally, the information structure of èto-clefts has remained underexplored in the existing literature.
This research investigates the information-structural, syntactic, and semantic properties of Russian clefts, both theoretically (supported by examples from Russian text corpora and judgments from native speakers) and experimentally. It is determined which desired changes in the information structure motivate native speakers to choose an èto-cleft and not the canonical structure or other focus realization tools. Novel syntactic tests are conducted to find evidence for bi-/monoclausality of èto-clefts, as well as for base-generation or movement of the cleft pivot. It is hypothesized that èto has a certain important function in clefts, and its status is investigated. Finally, new experiments on the nature of exhaustivity in èto-clefts are conducted. They allow for direct cross-linguistic comparison, using an incremental-information paradigm with truth-value judgments.
In terms of information structure, this research makes a new proposal that presents èto-clefts as structures with an inherent focus-background bipartitioning. Even though èto-clefts are used in typical focus contexts, evidence was found that èto-clefts (as well as Russian thetic clefts) allow for both new information focus and contrastive focus. Èto-clefts are pragmatically acceptable when a singleton answer to the implied question is expected (e.g. “It was Mark who won the race” but not “It was Mark who came to the party”). Importantly, èto in Russian clefts is neither dummy, nor redundant, but is a topic expression; conveys familiarity which triggers existence presupposition; refers to an instantiated event, or a known/perceivable situation; finally, èto plays an important role in the spoken language as a tool for speech coherency and a focus marker.
In terms of syntax, this research makes a new monoclausal proposal and shows evidence that the cleft pivot undergoes movement to the left peripheral position. Èto is proposed to be TopP.
Finally, in terms of semantics, a novel cross-linguistic evaluation of Russian clefts is made. Experiments show that the exhaustivity inference in èto-clefts is not robust. Participants used different strategies in resolving exhaustivity, falling into 2 groups: one group considered èto-clefts exhaustive, while another group considered them non-exhaustive. Hence, there is evidence for the pragmatic nature of exhaustivity in èto-clefts. The experimental results for èto-clefts are similar to the experimental results for clefts in German, French and Akan. It is concluded that speakers use different tools available in their languages to produce structures with similar interpretive properties.
The use of organic materials with reversible redox activity holds enormous potential for next-generation Li-ion energy storage devices. Yet, most candidates are not truly sustainable, i.e., not derived from renewable feedstock or made in benign reactions. Here an attempt is reported to resolve this issue by synthesizing an organic cathode material from tannic acid and microporous carbon derived from biomass. All constituents, including the redox-active material and conductive carbon additive, are made from renewable resources. Using a simple, sustainable fabrication method, a hybrid material is formed. The low cost and ecofriendly material shows outstanding performance with a capacity of 108 mAh g(-1) at 0.1 A g(-1) and low capacity fading, retaining approximately 80% of the maximum capacity after 90 cycles. With approximately 3.4 V versus Li+/Li, the cells also feature one of the highest reversible redox potentials reported for biomolecular cathodes. Finally, the quinone-catecholate redox mechanism responsible for the high capacity of tannic acid is confirmed by electrochemical characterization of a model compound similar to tannic acid but without catecholic groups.
Background:
Epidemiological evidence indicates that diets rich in plant foods are associated with a lower risk of ischaemic heart disease (IHD), but there is sparse information on fruit and vegetable subtypes and sources of dietary fibre. This study examined the associations of major plant foods, their subtypes and dietary fibre with risk of IHD in the European Prospective Investigation into Cancer and Nutrition (EPIC).
Methods:
We conducted a prospective analysis of 490 311 men and women without a history of myocardial infarction or stroke at recruitment (12.6 years of follow-up, n cases = 8504), in 10 European countries. Dietary intake was assessed using validated questionnaires, calibrated with 24-h recalls. Multivariable Cox regressions were used to estimate hazard ratios (HR) of IHD.
Results:
There was a lower risk of IHD with a higher intake of fruit and vegetables combined [HR per 200 g/day higher intake 0.94, 95% confidence interval (CI): 0.90-0.99, P-trend = 0.009], and with total fruits (per 100 g/day 0.97, 0.95-1.00, P-trend = 0.021). There was no evidence for a reduced risk for fruit subtypes, except for bananas. Risk was lower with higher intakes of nuts and seeds (per 10 g/day 0.90, 0.82-0.98, Ptrend = 0.020), total fibre (per 10 g/day 0.91, 0.85-0.98, P-trend = 0.015), fruit and vegetable fibre (per 4 g/day 0.95, 0.91-0.99, P-trend = 0.022) and fruit fibre (per 2 g/day 0.97, 0.95-1.00, P-trend = 0.045). No associations were observed between vegetables, vegetables subtypes, legumes, cereals and IHD risk.
Conclusions:
In this large prospective study, we found some small inverse associations between plant foods and IHD risk, with fruit and vegetables combined being the most strongly inversely associated with risk. Whether these small associations are causal remains unclear.
The Salt Range in Pakistan exposes Precambrian to Pleistocene strata outcropping along the Salt Range Thrust (SRT). To better understand the in-situ Cambrian and Pliocene tectonic evolution of the Pakistan Subhimalaya, we have conducted low-temperature thermochronological analysis using apatite (U-Th-Sm)/He and fission track dating. We combine cooling ages from different samples located along the thrust front of the SRT into a thermal model that shows two major cooling events associated with rifting and regional erosion in the Late Palaeozoic and SRT activity since the Pliocene. Our results suggest that the SRT maintained a long-term average shortening rate of similar to 5-6 mm/yr and a high exhumation rate above the SRT ramp since similar to 4 Ma.
Global biodiversity is under high and rising anthropogenic pressure. Yet, how the taxonomic, phylogenetic, and functional facets of biodiversity are affected by different threats over time is unclear. This is particularly true for the two main drivers of the current biodiversity crisis: habitat destruction and overexploitation. We provide the first long-term assessment of multifaceted biodiversity changes caused by these threats for any tropical region. Focussing on larger mammals in South America's 1.1 million km(2) Gran Chaco region, we assessed changes in multiple biodiversity facets between 1985 and 2015, determined which threats drive those changes, and identified remaining key areas for all biodiversity facets. Using habitat and threat maps, we found, first, that between 1985 and 2015 taxonomic (TD), phylogenetic (PD) and functional (FD) diversity all declined drastically across over half of the area assessed. FD declined about 50% faster than TD and PD, and these declines were mainly driven by species loss, rather than species turnover. Second, habitat destruction, hunting, and both threats together contributed similar to 57%, similar to 37%, and similar to 6% to overall facet declines, respectively. However, hunting pressure increased where TD and PD declined most strongly, whereas habitat destruction disproportionally contributed to FD declines. Third, just 23% of the Chaco would have to be protected to safeguard the top 17% of all three facets. Our findings uncover a widespread impoverishment of mammal species richness, evolutionary history, and ecological functions across broad areas of the Chaco due to increasing habitat destruction and hunting. Moreover, our results pinpoint key areas that should be preserved and managed to maintain all facets of mammalian diversity across the Chaco. More generally, our work highlights how long-term changes in biodiversity facets can be assessed and attributed to specific threats, to better understand human impacts on biodiversity and to guide conservation planning to mitigate them.
Development of a CRISPR/Cas gene editing technique for the coccolithophore Chrysotila carterae
(2024)
The simulation of broad-band (0.1 to 10 + Hz) ground-shaking over deep and spatially extended sedimentary basins at regional scales is challenging. We evaluate the ground-shaking of a potential M 6.5 earthquake in the southern Lower Rhine Embayment, one of the most important areas of earthquake recurrence north of the Alps, close to the city of Cologne in Germany. In a first step, information from geological investigations, seismic experiments and boreholes is combined for deriving a harmonized 3D velocity and attenuation model of the sedimentary layers. Three alternative approaches are then applied and compared to evaluate the impact of the sedimentary cover on ground-motion amplification. The first approach builds on existing response spectra ground-motion models whose amplification factors empirically take into account the influence of the sedimentary layers through a standard parameterization. In the second approach, site-specific 1D amplification functions are computed from the 3D basin model. Using a random vibration theory approach, we adjust the empirical response spectra predicted for soft rock conditions by local site amplification factors: amplifications and associated ground-motions are predicted both in the Fourier and in the response spectra domain. In the third approach, hybrid physics-based ground-motion simulations are used to predict time histories for soft rock conditions which are subsequently modified using the 1D site-specific amplification functions computed in method 2. For large distances and at short periods, the differences between the three approaches become less notable due to the significant attenuation of the sedimentary layers. At intermediate and long periods, generic empirical ground-motion models provide lower levels of amplification from sedimentary soils compared to methods taking into account site-specific 1D amplification functions. In the near-source region, hybrid physics-based ground-motions models illustrate the potentially large variability of ground-motion due to finite source effects.
Borehole leakage is a common and complex issue. Understanding the fluid flow characteristics of a cemented area inside a borehole is crucial to monitor and quantify the wellbore integrity as well as to find solutions to minimise existing leakages. In order to improve our understanding of the flow behaviour of cemented boreholes, we investigated experimental data of a large-scale borehole leakage tests by means of numerical modelling using three different conceptual models. The experiment was performed with an autoclave system consisting of two vessels bridged by a cement-filled casing. After a partial bleed-off at the well-head, a sustained casing pressure was observed due to fluid flow through the cementsteel composite. The aim of our simulations is to investigate and quantify the permeability of the cement-steel composite. From our model results, we conclude that the flow occurred along a preferential flow path at the cement-steel interface. Thus, the inner part of the cement core was impermeable during the duration of the experiment. The preferential flow path can be described as a highly permeable and highly porous area with an aperture of about 5 mu m and a permeability of 3 . 10(-12) m(2) (3 Darcy). It follows that the fluid flow characteristics of a cemented area inside a borehole cannot be described using one permeability value for the entire cement-steel composite. Furthermore, it can be concluded that the quality of the cement and the filling process regarding the cement-steel interface is crucial to minimize possible well leakages.
Electrical actuation of coated and composite fibers based on poly[ethylene-co-(vinyl acetate)]
(2020)
Robots are typically controlled by electrical signals. Resistive heating is an option to electrically trigger actuation in thermosensitive polymer systems. In this study electrically triggerable poly[ethylene-co-(vinyl acetate)] (PEVA)-based fiber actuators are realized as composite fibers as well as polymer fibers with conductive coatings. In the coated fibers, the core consists of crosslinked PEVA (cPEVA), while the conductive coating shell is achieved via a dip coating procedure with a coating thickness between 10 and 140 mu m. The conductivity of coated fibers sigma = 300-550 S m(-1) is much higher than that of the composite fibers sigma = 5.5 S m(-1). A voltage (U) of 110 V is required to heat 30 cm of coated fiber to a targeted temperature of approximate to 65 degrees C for switching in less than a minute. Cyclic electrical actuation investigations reveal epsilon '(rev) = 5 +/- 1% reversible change in length for coated fibers. The fabrication of such electro-conductive polymeric actuators is suitable for upscaling so that their application potential as artificial muscles can be explored in future studies.
Droughts in São Paulo
(2023)
Literature has suggested that droughts and societies are mutually shaped and, therefore, both require a better understanding of their coevolution on risk reduction and water adaptation. Although the Sao Paulo Metropolitan Region drew attention because of the 2013-2015 drought, this was not the first event. This paper revisits this event and the 1985-1986 drought to compare the evolution of drought risk management aspects. Documents and hydrological records are analyzed to evaluate the hazard intensity, preparedness, exposure, vulnerability, responses, and mitigation aspects of both events. Although the hazard intensity and exposure of the latter event were larger than the former one, the policy implementation delay and the dependency of service areas in a single reservoir exposed the region to higher vulnerability. In addition to the structural and non-structural tools implemented just after the events, this work raises the possibility of rainwater reuse for reducing the stress in reservoirs.