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Ab Mitte der 1820er Jahre erfuhr die Mikroskop- Technik eine stürmische Entwicklung. Dadurch, dass es gelang, nach und nach die optischen Fehler zu korrigieren, verbesserte sich die Auflösung bis zum Ende des Jahrhunderts um den Faktor 10 von 3 μm auf 0,3 μm. Um 1820 begann Christian Gottfried Ehrenberg mit mikroskopischen Untersuchungen. Er nutzte zunächst ein einfaches Nürnberger Mikroskop. 1832 erwarb er ein Mikroskop aus der Berliner Werkstatt von Pistor & Schiek, das er dann zeitlebens nutzte. Ein Vergleich der Leistungsfähigkeit seines Instruments mit der für seine Untersuchungen notwendigen Auflösung zeigt, dass es für seine Untersuchungen vollkommen genügte. Für seine Untersuchungsobjekte entwickelte er Präparationstechniken und Aufbewahrungsmethoden für die Dauerpräparate. Da er auch die mikroskopischen Abbildungen bis hin zu den Vorlagen für die Kupfertafeln selbst anfertigte, behielt er den gesamten Prozess von der Präparation bis zum Druck der Ergebnisse stets in der Hand.
Als langjähriges und aktives Mitglied der Gesellschaft Naturforschender Freunde zu Berlin bestimmte Ehrenberg ihre Aktivitäten und ihr Ansehen maßgeblich mit. Seine Beiträge zu den Sitzungen und Schriften und seine Rolle als Bewohner des gesellschaftseigenen Hauses förderten in der GNF sowohl Fortschritt als auch Beständigkeit. Das Ziel der Naturgeschichte des 18. Jahrhunderts, also die Entdeckung, Beschreibung und Bewahrung möglichst aller Organismen- und Gesteinsarten, wurde in der GNF bis in die zweite Hälfte des 19. Jahrhunderts tradiert. Ehrenbergs wissenschaftliche Leistungen, insbesondere seine zahlreichen Entdeckungen mit Hilfe des Mikroskops, stehen ganz in dieser Tradition.
We use ultrafast x-ray diffraction to investigate the effect of expansive phononic and contractive magnetic stress driving the picosecond strain response of a metallic perovskite SrRuO3 thin film upon femtosecond laser excitation. We exemplify how the anisotropic bulk equilibrium thermal expansion can be used to predict the response of the thin film to ultrafast deposition of energy. It is key to consider that the laterally homogeneous laser excitation changes the strain response compared to the near-equilibrium thermal expansion because the balanced in-plane stresses suppress the Poisson stress on the picosecond timescale. We find a very large negative Grüneisen constant describing the large contractive stress imposed by a small amount of energy in the spin system. The temperature and fluence dependence of the strain response for a double-pulse excitation scheme demonstrates the saturation of the magnetic stress in the high-fluence regime.
A tale of shifting relations
(2021)
Understanding the dynamics between the East Asian summer (EASM) and winter monsoon (EAWM) is needed to predict their variability under future global warming scenarios. Here, we investigate the relationship between EASM and EAWM as well as the mechanisms driving their variability during the last 10,000 years by stacking marine and terrestrial (non-speleothem) proxy records from the East Asian realm. This provides a regional and proxy independent signal for both monsoonal systems. The respective signal was subsequently analysed using a linear regression model. We find that the phase relationship between EASM and EAWM is not time-constant and significantly depends on orbital configuration changes. In addition, changes in the Atlantic Meridional Overturning circulation, Arctic sea-ice coverage, El Niño-Southern Oscillation and Sun Spot numbers contributed to millennial scale changes in the EASM and EAWM during the Holocene. We also argue that the bulk signal of monsoonal activity captured by the stacked non-speleothem proxy records supports the previously argued bias of speleothem climatic archives to moisture source changes and/or seasonality.
This book presents an overview of European migration policy and the various institutional arrangements within and between various actors, such as local councils, local media, local economies, and local civil society initiatives. Both the role of local authorities in this policy field and their cooperation with civil society initiatives or networks are under-explored topics for research. In response, this book provides a range of detailed case studies focusing on the six main groups of national and administrative traditions in Europe: Germanic, Scandinavian, Napoleonic, Southeastern European, Central-Eastern European and Anglo-Saxon.
In this introductory chapter, the editors describe the main theoretical basis of analysis of this book and the methodological approach. The core of this book consists of 14 country-specific chapters, which allow a European comparison and show the increasing variance in migration policy approaches within and between European countries. The degree of local autonomy, the level of centralisation and the traditional forms of migration policy are factors that especially influence the possibilities for local authorities to formulate their own integration policies.
The chapter begins with a brief historical overview of Germany’s transition in the twentieth and twenty-first century from a transit and emigration country to one of immigration. The next part of this chapter looks at the challenges and problems facing German immigration policy within a multi-level federal system. Finally, the chapter gives an analysis of some of the trends in German migration policy since the refugee crisis in 2015, such as changes in the party system and in the concepts underlying migration policies to better manage, control and limit immigration to Germany.
This chapter focuses on the relationship between public opinion on migration and its media coverage. Different explanatory models, including individual characteristics, cultural factors and the impact of media and politics, have been proposed to explain public attitudes towards migrants. Understanding the local context is important, as the shares of migrants living in each region and city vary considerably. Providing correct statistical information, stressing the diversity of current migration patterns in Europe and taking part in media and public discussions are ways in which to impact public attitudes at the local level.
As expected, the traditions of national-state migration policies continue to play a very important role, path-dependence in this policy field remains high. The distribution of competences in migration policy and the integration of migrants in the nation states continues to be very different. When implementing integration strategies at grassroots level, the respective policies should be tailored to the profile of both the local migrant community and the native population. Besides better migration management in local administration and the interaction of top-down and bottom-up efforts to integrate migrants is of importance.
Introduction
(2021)
Paths Are Made by Walking
(2021)
Philosophie der Personalität
(2021)
Die Philosophie der Person tritt mit dem Anspruch an, unser Selbstverständnis als Individuen artikulieren zu wollen. Wird die gängige Lesart von Personen als rationalen, selbstbewussten Individuen diesem Anspruch wirklich gerecht? In Auseinandersetzung mit unterschiedlichen Ansätzen der Gegenwart arbeitet Moritz von Kalckreuth neben der rationalen auch die leibliche, emotionale und soziokulturelle Dimension von Personalität heraus und fragt nach der Möglichkeit, sie alle in einem „Syntheseversuch“ zusammenzuführen. Im Anschluss an Helmuth Plessners Philosophische Anthropologie, Nicolai Hartmanns Neue Ontologie und Max Schelers Phänomenologie lassen sich verschiedene Lesarten von Geist gewinnen, die sich für eine solche Verknüpfung der einzelnen Dimensionen von Personalität besonders eignen.
Gothic Cinema
(2021)
Als erste deutschsprachige Einführung in das Gothic Cinema stellt dieser Band ein im deutschsprachigen Raum bisher kaum etabliertes und wenig erforschtes Filmgenre vor. Er begreift Gothic Cinema als eine Form inoffizieller Historiographie, die einen Blick nicht nur auf die Geschichte des Films und seiner Technik, sondern auch auf Moralvorstellungen, Geschlechterverhältnisse, kollektive Ängste oder ästhetische Strömungen zulässt. Auf eine Abgrenzung und Bestimmung des Begriffs und der zentralen Elemente des Gothic folgt ein umfassender historischer Überblick von 1896 bis zur heutigen Zeit. Der Schwerpunkt im dritten Teil liegt auf Analysen einzelner Gothic-Filme und Fernsehserien nach 2015. Die untersuchten Beispiele sind einerseits repräsentativ im Hinblick auf typische Elemente, Motive oder Topoi und weisen andererseits Besonderheiten und Brüche auf, die sich für eine kultur- und medienwissenschaftliche Untersuchung als fruchtbar erweisen.
Chinas neuer langer Marsch
(2021)
In sports and movement sciences isometric muscle function is usually measured by pushing against a stable resistance. However, subjectively one can hold or push isometrically. Several investigations suggest a distinction of those forms. The aim of this study was to investigate whether these two forms of isometric muscle action can be distinguished by objective parameters in an interpersonal setting. 20 subjects were grouped in 10 same sex pairs, in which one partner should perform the pushing isometric muscle action (PIMA) and the other partner executed the holding isometric muscle action (HIMA). The partners had contact at the distal forearms via an interface, which included a strain gauge and an acceleration sensor. The mechanical oscillations of the triceps brachii (MMGtri) muscle, its tendon (MTGtri) and the abdominal muscle (MMGobl) were recorded by a piezoelectric-sensor-based measurement system. Each partner performed three 15s (80% MVIC) and two fatiguing trials (90% MVIC) during PIMA and HIMA, respectively. Parameters to compare PIMA and HIMA were the mean frequency, the normalized mean amplitude, the amplitude variation, the power in the frequency range of 8 to 15 Hz, a special power-frequency ratio and the number of task failures during HIMA or PIMA (partner who quit the task). A “HIMA failure” occurred in 85% of trials (p < 0.001). No significant differences between PIMA and HIMA were found for the mean frequency and normalized amplitude. The MMGobl showed significantly higher values of amplitude variation (15s: p = 0.013; fatiguing: p = 0.007) and of power-frequency-ratio (15s: p = 0.040; fatiguing: p = 0.002) during HIMA and a higher power in the range of 8 to 15 Hz during PIMA (15s: p = 0.001; fatiguing: p = 0.011). MMGtri and MTGtri showed no significant differences. Based on the findings it is suggested that a holding and a pushing isometric muscle action can be distinguished objectively, whereby a more complex neural control is assumed for HIMA.
Afghanistan-Krieg
(2021)
Retinol-binding protein 4 (RBP4) is the major transport protein for retinol in blood. Recent evidence from genetic mouse models shows that circulating RBP4 derives exclusively from hepatocytes. Because RBP4 is elevated in obesity and associates with the development of glucose intolerance and insulin resistance, we tested whether a liver-specific overexpression of RBP4 in mice impairs glucose homeostasis. We used adeno-associated viruses (AAV) that contain a highly liver-specific promoter to drive expression of murine RBP4 in livers of adult mice. The resulting increase in serum RBP4 levels in these mice was comparable with elevated levels that were reported in obesity. Surprisingly, we found that increasing circulating RBP4 had no effect on glucose homeostasis. Also during a high-fat diet challenge, elevated levels of RBP4 in the circulation failed to aggravate the worsening of systemic parameters of glucose and energy homeostasis. These findings show that liver-secreted RBP4 does not impair glucose homeostasis. We conclude that a modest increase of its circulating levels in mice, as observed in the obese, insulin-resistant state, is unlikely to be a causative factor for impaired glucose homeostasis.
Leveraging large-deviation statistics to decipher the stochastic properties of measured trajectories
(2021)
Extensive time-series encoding the position of particles such as viruses, vesicles, or individualproteins are routinely garnered insingle-particle tracking experiments or supercomputing studies.They contain vital clues on how viruses spread or drugs may be delivered in biological cells.Similar time-series are being recorded of stock values in financial markets and of climate data.Such time-series are most typically evaluated in terms of time-averaged mean-squareddisplacements (TAMSDs), which remain random variables for finite measurement times. Theirstatistical properties are different for differentphysical stochastic processes, thus allowing us toextract valuable information on the stochastic process itself. To exploit the full potential of thestatistical information encoded in measured time-series we here propose an easy-to-implementand computationally inexpensive new methodology, based on deviations of the TAMSD from itsensemble average counterpart. Specifically, we use the upper bound of these deviations forBrownian motion (BM) to check the applicability of this approach to simulated and real data sets.By comparing the probability of deviations fordifferent data sets, we demonstrate how thetheoretical bound for BM reveals additional information about observed stochastic processes. Weapply the large-deviation method to data sets of tracer beads tracked in aqueous solution, tracerbeads measured in mucin hydrogels, and of geographic surface temperature anomalies. Ouranalysis shows how the large-deviation properties can be efficiently used as a simple yet effectiveroutine test to reject the BM hypothesis and unveil relevant information on statistical propertiessuch as ergodicity breaking and short-time correlations.
George Santayana
(2021)
Water-deficits can cause lethal damage to organisms, which is rooted in cellular dehydration. Many plant species, but also other organisms have developed mechanisms to tolerate such stresses, such as the expression of LEA proteins. Many studies report on physiological protective functions of LEA proteins but lack information about their precise mechanisms on a molecular level. Most LEA proteins are intrinsically disordered in dilute solution but may adopt a distinct secondary structure upon changes in solvent conditions. Understanding the molecular mechanism of how LEA proteins contribute to the counteraction of cellular damage during water-deficits may in the long-term pave the way for breeding crops that are resistant to the effects of global warming. The objective of the work at hand is to improve the biophysical understanding of the sequencestructure-function relationship of LEA proteins as membrane stabilizers, based on the LEA_4 family of the model plant A. thaliana. This is pursued by using a combination of spectroscopic and scattering techniques, supported by bioinformatics and computational analyses. Eight out of the 18 LEA_4 proteins are experimentally assessed revealing that a coil-helix transition in response to water-deficit is a common feature, as predicted for the entire family. In addition, they all stabilize simple membrane models during a freeze/ thaw cycle. Three-dimensional structure prediction of representative members suggests that their completely folded states are represented by a sequential arrangement of alpha-helical segments connected by unstructured linkers, which is experimentally verified for the LEA_4 protein COR15A. The unstructured linker region of COR15A represents a conserved motif among its closest homologs and is, therefore, of particular interest. Facilitating a set of seven designed and investigated COR15A mutants uncovers a complex interplay of transient interactions between the amphipathic alpha-helical segments, mediated by the linker, which fine-tunes folding transitions and structural ensembles upon reduced water-availability. Finally, alpha-helicity is also induced in COR15A upon temperature decrease, which is enhanced in the presence of osmolytes. In addition, high solution osmolarity induced secondary structure is followed by oligomerization of COR15A. Interestingly, the functionality of COR15A, in terms of liposome stabilization, strongly correlates with its alpha-helix ratio in the folded state. The present work significantly improves the understanding of the sequence-structure-function relationship for LEA_4 proteins and offers novel findings on folding mechanisms and oligomerization of COR15A.
Die Geschichte der Mikrobiologie als Laborwissenschaft des späten 19. Jahrhunderts hat für Ehrenberg keinen Platz. Unmodern, ja fehlerhaft scheinen die Befunde dieses „Humboldt en miniature“, der die Belebtheit von Wasser oder Luft mikroskopisch untersuchte, der Proben aus aller Welt sammelte und so zahlreiche „Infusorien“ genannte Mikroben sowie deren Effekte etwa bei Blutwundern beschrieb, deren Beteiligung an Infektionskrankheiten aber verneinte. Zugleich scheint sein ökologischer Blick auf den Mikrokosmos die Gegenwart auf überraschende Weise anzusprechen – einerseits weil Mikroben omnipräsentes Faszinosum wie Bedrohung bleiben, andererseits weil viele der Prämissen von Pasteur und Koch im Zeitalter der Genomik überholt erscheinen. Ausgehend von der zwiespältigen Position Ehrenbergs fragt dieser Artikel, warum er möglicherweise gerade deswegen spannender ist, als ihn die Historiographie bislang hat erscheinen lassen.
Im Jahr 1820 traten zwei Universitätsabsolventen, Christian Gottfried Ehrenberg und Wilhelm Hemprich, eine Forschungsreise nach Nordafrika an, die eine der ersten vom preußischen Staat maßgeblich getragenen Reiseunternehmungen darstellt. Wesentliches Ziel der Reise war das Sammeln von naturkundlichen Exemplaren für die junge Berliner Museumslandschaft. Der Beitrag ordnet die afrikanische Forschungsreise in die wissenschaftliche Laufbahn Ehrenbergs ein, der als einziger Reisender überlebte, sowie in die Geschichte der Berliner Wissenschaftslandschaft im frühen 19. Jahrhundert. Dabei konzentriert sich der Beitrag auf die Medien – insbesondere Sammlungsverzeichnisse und Sammlungsobjekte – die die Reisenden im Feld einsetzen mussten, um ihre Identität als gelehrte Naturforscher gegenüber ihren Förderern zu inszenieren und damit ihre Position in der preußischen Wissenschaft strategisch zu sichern.
The Russian-Siberian journey, carried out with Alexander von Humboldt and Gustav Rose in 1829 coincided with a decisive phase in Christian Gottfried Ehrenberg’s scientific career. His field diary and the drawings he made on the trip document his intensified focus on the study of microorganisms. The numerous observations on plant and animal geography show how Ehrenberg tested a combination of micro- and macro-perspectives that would shape his research on infusoria in the following decades: In addition to the task of classification at the microscope, Ehrenberg carried out worldwide comparative research on the distribution of microorganisms.
Die Erforschung und Beschreibung mikroskopischer Organismen durch Christian Gottfried Ehrenberg ist durch seine publizierten Texte und Kupfertafeln in den „Infusionsthierchen“, der „Mikrogeologie“ sowie aus Abhandlungen der Akademie der Wissenschaften überliefert. Zentrale Bedeutung haben seine Zeichenblätter, anfangs alleinige Dokumentation, später komplementiert durch tausende mikroskopischer Dauerpräparate rezenter und fossiler Kieselschalen sowie getrockneter Einzeller. Alle Originalmaterialien Ehrenbergs stehen für die aktuelle Forschung in der Ehrenbergsammlung zur Verfügung. Seine detailgenauen Zeichnungen dienten der Erstbeschreibung einer Vielzahl neuer Arten aus allen Weltteilen. Biogeografische und ökologische Fragestellungen, Beschreibungen von Lebenszyklen sowie außerordentliche Phänomene wie die Färbung von Gewässern und Erden wurden mithilfe zeichnerischer Analysen bearbeitet.
Geleitwort
(2021)
Essays on Macroeconomics
(2021)
This dissertation consists of four self-contained papers. Each paper deals with a specific macroeconomic question. The first paper assesses the distributional implications of environmental policies from a general equilibrium macroeconomic perspective. I develop a New-Keynesian model with several types of uncertainties and frictions that incorporates liquidity constrained households. The model is calibrated to match the German economy and the numerical results show that climate policy instruments can be associated with regressive welfare effects. Furthermore, the analysis shows that these effects can be mitigated through an appropriate revenue recycling scheme. The second paper deals with short-run inequality dynamics within a real business cycle model. An empirical evaluation shows that the cyclical components of income inequality, the capital share and real GDP are correlated. We develop tractable representation of common inequality indicators in the general equilibrium model and show that the observed pattern is driven by innovations in the capital share. A Bayesian estimation of the model for the United States with data for the period 1948 to 2017 indicates that the model provides a reasonable fit for the data and successfully replicates the observed pattern of cyclical correlations. The third paper empirically examines the effects of banking regulation on the risk-relationship between sovereigns and banks. Based on a comprehensive data set of the European banking sector, we find that the implementation of the novel European banking regulation framework significantly contributed to a weakening of the risk-link between sovereigns and banks.The fourth paper empirically examines the role of institutional experience for institutional development in transition economies. To capture institutional experience, we develop a novel index, based on historical country records. The results of cross-sectional and panel estimations suggest that institutional experience helps to explain the divergent economic and institutional development in transition economies after the dissolution of the Soviet Union.
Heinrich Menu von Minutoli unternahm 1820 eine Reise nach Nordafrika zur Erforschung ägyptischer und griechischer Altertümer. Die Preußische Akademie der Wissenschaften bestimmte die jungen Naturforscher Christian Gottfried Ehrenberg und Wilhelm Hemprich als weitere Teilnehmer.
Während Minutoli bereits ein Jahr nach Beginn der Expedition 1821 nach Europa zurückkehrte, setzten Ehrenberg und Hemprich ihre Forschungen fort. Von Alexandria aus unternahmen sie, zum Teil getrennt, Exkursionen in die libysche Wüste, auf die Sinaihalbinsel, zum Roten Meer, in das Libanongebirge sowie bis in den Sudan und nach Eritrea, wo Hemprich 1825 dem Malariafieber erlag.
Wie von der Akademie der Wissenschaften beauftragt, sammelten Ehrenberg und Hemprich insgesamt 34 000 Tiere, 46 000 Pflanzen und 300 Mineralien. Diese trafen im Laufe der Jahre, verpackt in insgesamt 114 Kisten, in Berlin ein. Die Akademie stellte Mittel für die Auswertung der Sammlungen zur Verfügung. Ehrenbergs Reisebericht blieb aber ebenso Fragment wie das großangelegte Tafelwerk Symbolae physicae.
„Eine der größten Freuden meines Lebens würde sein, einmal 5 – 6 Monathe mit Ihnen, an Ihrer Seite, unter Ihrer Belehrung reisen zu können. Süßwassermuscheln, Fische, Bergpflanzen Rußlands sind wenig bekannt.“ Mit diesen Worten lud Alexander von Humboldt seinen Akademiekollegen Ehrenberg zur Teilnahme an der russisch-sibirischen Reise ein, die der preußische Kammerherr auf Einladung des Kaisers Nikolaj I. unternahm. Knapp drei Jahre nach der Rückkehr von der arabisch-afrikanischen Forschungsreise brach Ehrenberg also erneut auf: Am 12. April 1829 traten Humboldt, Ehrenberg und der Mineraloge Gustav Rose ihre Reise in Berlin an. Diese führte sie in knapp neun Monaten und über 19 000 Kilometer in den Ural und durch Westsibirien bis zur russisch-chinesischen Grenzstation Baty. Während Humboldt und Rose die Hüttenbezirke im Ural und Altai inspizierten, legte Ehrenberg botanische und zoologische Sammlungen an.
Nach den beiden großen Forschungsreisen konzentrierte Ehrenberg seine Arbeit in Berlin auf die systematische Beschreibung von Kleinstlebewesen, die sogenannten Infusorien. 1838 erschien eines seiner Hauptwerke, Die Infusionsthierchen als vollkommene Organismen. Ein Blick in das tiefere organische Leben der Natur. Ehrenberg untersuchte tausende Proben aus aller Welt und wies Infusorien auf dem Grund der Weltmeere, in atmosphärischem Staub und in Hochgebirgen nach. Ausgehend von diesen Befunden beschäftigte er sich mit dem Anteil einzelliger kieselschaliger Mikroorganismen an der Bildung von Erden und geologischen Formationen. 1854 legte er die Mikrogeologie vor: In 41 Bildtafeln gab er weltweite „geographische Uebersichten über das kleine jetzige erdbildende Leben“. Christian Gottfried Ehrenberg gilt als Mitbegründer der Boden-Mikrobiologie und Mikropaläontologie sowie als Pionier der Kieselalgenforschung und Protozoologie.
Wissenschaftliches Arbeiten
(2021)
Die formalen und theoretischen Grundlagen wissenschaftlichen Arbeitens spielen in der akademischen Weiterbildung und darüber hinaus auch im Geschäftsalltag eine - zumeist unterschätzte - Rolle: Gerade im Managementkontext müssen aus selbst erhobenen oder recherchierten Informationen gutachterliche Stellungnahmen erarbeitet und dabei die Grundsätze ordnungsgemäßer wissenschaftlicher Arbeit beachtet werden. Die Erstellung solcher Texte erfordert neben der Fähigkeit zur Formulierung bzw. Abgrenzung einer forschungsleitenden Frage und zur gezielten Informationsrecherche auch spezifische Fähigkeiten im Schreibprozess und beim Belegen von Quellen. Diese Kompetenzen sollen im Rahmen eines "Refresher"-Kurses, der als Grundlage für dieses Werk dient, so vermittelt werden, dass sowohl Studierende als auch Fach- und Führungskräfte aus der Praxis schnell informiert werden.
The trace elements zinc and manganese are essential for human health, especially due to their enzymatic and protein stabilizing functions. If these elements are ingested in amounts exceeding the requirements, regulatory processes for maintaining their physiological concentrations (homeostasis) can be disturbed. Those homeostatic dysregulations can cause severe health effects including the emergence of neurodegenerative disorders such as Parkinson’s disease (PD). The concentrations of essential trace elements also change during the aging process. However, the relations of cause and consequence between increased manganese and zinc uptake and its influence on the aging process and the emergence of the aging-associated PD are still rarely understood. This doctoral thesis therefore aimed to investigate the influence of a nutritive zinc and/or manganese oversupply on the metal homeostasis during the aging process. For that, the model organism Caenorhabditis elegans (C. elegans) was applied. This nematode suits well as an aging and PD model due to properties such as its short life cycle and its completely sequenced, genetically amenable genome. Different protocols for the propagation of zinc- and/or manganese-supplemented young, middle-aged and aged C. elegans were established. Therefore, wildtypes, as well as genetically modified worm strains modeling inheritable forms of parkinsonism were applied. To identify homeostatic and neurological alterations, the nematodes were investigated with different methods including the analysis of total metal contents via inductively-coupled plasma tandem mass spectrometry, a specific probe-based method for quantifying labile zinc, survival assays, gene expression analysis as well as fluorescence microscopy for the identification and quantification of dopaminergic neurodegeneration.. During aging, the levels of iron, as well as zinc and manganese increased.. Furthermore, the simultaneous oversupply with zinc and manganese increased the total zinc and manganese contents to a higher extend than the single metal supplementation. In this relation the C. elegans metallothionein 1 (MTL-1) was identified as an important regulator of metal homeostasis. The total zinc content and the concentration of labile zinc were age-dependently, but differently regulated. This elucidates the importance of distinguishing these parameters as two independent biomarkers for the zinc status. Not the metal oversupply, but aging increased the levels of dopaminergic neurodegeneration. Additionally, nearly all these results yielded differences in the aging-dependent regulation of trace element homeostasis between wildtypes and PD models. This confirms that an increased zinc and manganese intake can influence the aging process as well as parkinsonism by altering homeostasis although the underlying mechanisms need to be clarified in further studies.
Breslau has been almost entirely forgotten in the Anglophone sphere as a place of Enlightenment. Moreover, in the context of the Jewish Enlightenment, Breslau has never been discussed as a place of intercultural exchange between German-speaking Jewish, Protestant and Catholic intellectuals. The story of Moses Hirschel offers us an excellent case-study to investigate the complex reciprocal relationship between Jewish and non-Jewish enlighteners in a prosperous and influential Central European city on the cusp of the 18th century.
Coordinated subjects often show variable number agreement with the finite verb, but linguistic approaches to this phenomenon have rarely been informed by systematically collected data. We report the results from three experiments investigating German speakers' agreement preferences with complex subjects joined by the correlative conjunctions sowohl horizontal ellipsis als auch ('both horizontal ellipsis and'), weder horizontal ellipsis noch ('neither horizontal ellipsis nor') or entweder horizontal ellipsis oder ('either horizontal ellipsis or'). We examine to what extent conjunction type and a conjunct's relative proximity to the verb affect the acceptability and processibility of singular vs. plural agreement. Experiment 1 was an untimed acceptability rating task, Experiment 2 a timed sentence completion task, and Experiment 3 was a self-paced reading task. Taken together, our results show that number agreement with correlative coordination in German is primarily determined by a default constraint triggering plural agreement, which interacts with linear order and semantic factors. Semantic differences between conjunctions only affected speakers' agreement preferences in the absence of processing pressure but not their initial agreement computation. The combined results from our offline and online experimental measures of German speakers' agreement preferences suggest that the constraints under investigation do not only differ in their relative weighting but also in their relative timing during agreement computation.
Un dandy de zapatos gastados
(2021)
El comienzo podrían ser dos imágenes de Vallejo en París. La primera la extraigo de la más reciente biografía del escritor peruano, César Vallejo: A Literary Biography, obra del hispanista británico Stephen Hart. Refiere Hart que en sus primeros años en París la situación de Vallejo era tan precaria que cuando viajaba en tren evitaba descender del vagón hasta que no se hubiera detenido del todo para no desgastar su único par de zapatos. En cierta ocasión, yendo con unos amigos y topándose con una acera encharcada por la ruptura de una boca de riego, Vallejo prefirió dar media vuelta y despedirse de sus amigos antes que arriesgarse a arruinar sus zapatos atravesando el charco (108). Quisiera contrastar esta imagen, que sintetiza la penuria económica que marcó la vida de Vallejo en París y en general los quince años que pasó en Europa desde que abandonó el Perú en 1923 hasta su muerte en 1938, con la imagen que propone una fotografía (véase Fig. 1).
Es una fotografía muy conocida: tomada en 1929 por Juan Domingo Córdoba en el curso de un paseo veraniego por Versalles, se ha convertido en una suerte de imagen emblemática, reproducida en numerosas reediciones de la obra de Vallejo. De hecho, lo que a mí siempre me llamó la atención en esta imagen es la pose. La pose, y la elegancia del atuendo. Consideremos por un momento lo atildado del traje, el coqueto pañuelo que asoma del bolsillo superior de la chaqueta, el anillo con un ágata negra engastada en el dedo corazón, el sombrero de fieltro dejado al desgaire en la pierna, el señorial bastón—o la corbata anudada en pajarita con que aparece en otra fotografía contemporánea (véase Fig. 2). Si hubiera que definir en una palabra la elegancia de esa pose, yo diría que es la pose de un dandy. Un dandy de zapatos gastados.
En los múltiples transtierros de Vallejo, y en particular en los quince años que vivió en París, coexisten así pues la precariedad económica del emigrante y el cosmopolitismo del viajero culto.
A convenient method for the synthesis of gamma-spirolactams in only three steps is described. Birch reduction of inexpensive and commercially available aromatic carboxylic acids in the presence of chloroacetonitrile affords nitriles in moderate to good yields. Suitable precursors are methyl-substituted benzoic acids, naphthoic, and anthroic acid. Subsequent catalytic hydrogenation proceeds smoothly with PtO2 or Raney Ni as catalysts and lactams are isolated in excellent yields and stereoselectivities. Thus, up to 3 new stereogenic centers can be constructed as sole diastereomers from achiral benzoic acids. Furthermore, it is possible to control the degree of saturation at different pressures, affording products with 0, 1, or 2 double bonds. Overall, more than 15 new gamma-spirolactams have been synthesized in analytically pure form.
Influence of functional groups on the ene reaction of singlet oxygen with 1,4-cyclohexadienes
(2021)
The photooxygenation of 1,4-cyclohexadienes has been studied with a special focus on regio- and stereoselectivities. In all examples, only the methyl-substituted double bond undergoes an ene reaction with singlet oxygen, to afford hydroperoxides in moderate to good yields. We explain the high regioselectivities by a "large-group effect" of the adjacent quaternary stereocenter. Nitriles decrease the reactivity of singlet oxygen, presumably by quenching, but can stabilize proposed per-epoxide intermediates by polar interactions resulting in different stereoselectivities. Spiro lactams and lactones show an interesting effect on regio- and stereoselectivities of the ene reactions. Thus, singlet oxygen attacks the double bond preferentially anti to the carbonyl group, affording only one regioisomeric hydroperoxide. If the reaction occurs from the opposite face, the other regioisomer is exclusively formed by severe electrostatic repulsion in a perepoxide intermediate. We explain this unusual behavior by the fixed geometry of spiro compounds and call it a "spiro effect" in singlet oxygen ene reactions.
In the absence of a stranded auxiliary or modal, VP-topicalization in most Germanic languages gives rise to the presence of a dummy verb meaning 'do'. Cross-linguistically, this is a rather uncommon strategy as comparable VP-fronting constructions in other languages, e.g. Hebrew, Polish, and Portuguese, among many others, exhibit verb doubling. A comparison of several recent approaches to verb doubling in VP-fronting reveals that it is the consequence of VP-evacuating head movement of the verb to some higher functional head, which saves the (low copy of the) verb from undergoing copy deletion as part of the low VP copy in the VP-topicalization dependency. Given that almost all Germanic languages have such V-salvaging head movement, namely V-to-C movement, but do not show verb doubling, this paper suggests that V-raising is exceptionally impossible in VP-topicalization clauses and addresses the question of why it is blocked. After discussing and rejecting some conceivable explanations for the lack of verb doubling, I propose that the blocking effect arises from a bleeding interaction between V-to-C movement and VP-to-SpecCP movement. As both operations are triggered by the same head, i.e. C, the VP is always encountered first by a downward search algorithm. Movement of VP then freezes it and its lower copies for subextraction precluding subsequent V-raising. Crucially, this implies that there is no V-to-T raising in most Germanic languages. V2 languages with V-to-T raising, e.g. Yiddish, are correctly predicted to not exhibit the blocking effect.
Background
Despite the prevalence of obsessive-compulsive disorder (OCD), its precise identification remains challenging. With the Zohar-Fineberg Obsessive-Compulsive Screen (ZF-OCS; 5 or 6 items), a brief instrument is widely available mainly in English. As there is a lack of empirical studies on the ZF-OCS, the aim of the present study was to translate the items into German and investigate the instrument in a nonclinical sample.
Methods
In two consecutive online surveys, n = 304 and n = 51 students participated. Besides the ZF-OCS, they answered established measures on OCD, depression, health anxiety, general anxiety and health-related well-being.
Results
Whereas internal consistency was low (α = .53–.72; ω = .55–.69), retest reliability (rt1,t2 = .89) at two weeks was high. As expected, we found high correlations with other OCD instruments (r > .61; convergent validity), and significantly weaker correlations with measures of depression (r = .39), health anxiety (r = .29), and health-related well-being (r = −.28, divergent validity). Nonetheless, the correlations with general anxiety were somewhere in between (r = .52).
Conclusions
Due to heterogeneous OCD subtypes, the ZF-OCS asks diverse questions which probably resulted in the present internal consistency. Nevertheless, the results on retest reliability and validity were promising. As for other OCD instruments, divergent validity regarding general anxiety seems problematic to establish. Even so, the ZF-OCS seems valuable for screening purposes, as it is short and easy to administer, and may facilitate initiating subsequent clinical assessment. Further studies should determine the instrument’s diagnostic accuracy.
‘La poesía no da para tanto’
(2021)
Este artículo se enfoca en la singular combinación de poesía, ficción y autobiografía que pone en juego la obra reciente de Lorenzo García Vega. A través de una lectura de dicha obra, y en particular de la ‘mala novela’, Devastación del Hotel San Luis (2007), se propone un replanteamiento teórico del concepto de autoficción que se apoya en el análisis lingüístico de los modos de enunciación de Benveniste y en una revisión de la teoría de los géneros literarios de Käte Hamburger. Mi lectura sitúa la cuestión de la autoficción en el conflictivo diálogo de este autor con el grupo Orígenes, y explora el cruce de modos narrativos y líricos de autofiguración en el singular proyecto de García Vega: reescribir la narrativa autobiográfica proustiana a la vez que la poética neobarroca lezamiana.
Recent research provides evidence that aggressive sexual fantasies predict aggressive sexual behavior in the general population. However, sexual fantasies including fantasies about the infliction of pain and humiliation, should be frequent and often consensually acted upon among individuals with sadomasochistic likings. The question arises whether sexual fantasies with aggressive content still predict presumably non-consensual aggressive sexual behavior in individuals with sadomasochistic likings, given that BDSM encounters are generally considered consensual. To investigate this question, we conducted a questionnaire survey of sexual fantasies, as sessing the frequency of seventy sexual fantasies involving non-aggressive, masochistic, and aggressive acts. Our sample (N = 182) contained 99 respondents who self-identified as sadist, masochist, or switcher; 44 reported no such identification. For respondents reporting BDSM identification, we replicated a factor structure for sexual fantasies similar to that previously found in the general population, including three factors reflecting fantasies about increasingly severe aggressive sexual acts. Fantasies about injuring a partner and/or using weapons and fantasies about sexual coercion predicted presumably non-consensual sexual behavior independently of other risk factors for aggressive sexual behavior and irrespective of BDSM identification. Hence, severely aggressive sexual fantasies may predispose to presumably non-consensual sexual behavior in both individuals with and without BDSM identification.
This paper intends to explore the interaction between aspect and lexical means, in this case temporal adverbials, in the bounding of representations of situations. First, the theoretical basis is outlined, followed by the results of a corpus analysis of coccurrences with adverbs that limit situations. The term situation encompasses all representable processes, states, events, or actions. Finally, some theoretical conclusions are drawn concerning the cognitive category of bounding, using the example of aspectuality. The imperfective verb forms maintain their aspectuality in delimiting connections with adverbs, resulting in a complex, multi-dimensional aspectuality. In nongrammaticalized forms, such as lexical markers, the speaker is free to make a temporal localization or an aspectual perspective. Lexical expressions can make temporal and aspect markings even more precisely and clearly than tenses. They can also limit or extend situations and thus express aspect. Aspectuality thus presents itself as a compositional category, in which external bounding and the internal representation of a course of action or development can interact.