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Le possiblili vite di un artista : Andrea De Carlo e la varietá delle sue alteritá immaginate
(2010)
Physikalisches Wissen und ästhetische Darstellung in Sur les nuages (1888) von Guy de Maupassant
(2010)
Einleitung
(2010)
We investigate the large-scale oceanic features determining the future ice shelf-ocean interaction by analyzing global warming experiments in a coarse resolution climate model with a comprehensive ocean component. Heat and freshwater fluxes from basal ice shelf melting (ISM) are parameterized following Beckmann and Goosse [Ocean Model 5(2):157-170, 2003]. Melting sensitivities to the oceanic temperature outside of the ice shelf cavities are varied from linear to quadratic (Holland et al. in J Clim 21, 2008). In 1% per year CO2-increase experiments the total freshwater flux from ISM triples to 0.09 Sv in the linear case and more than quadruples to 0.15 Sv in the quadratic case after 140 years at which 4 x 280 ppm = 1,120 ppm was reached. Due to the long response time of subsurface temperature anomalies, ISM thereafter increases drastically, if CO2 concentrations are kept constant at 1,120 ppm. Varying strength of the Antarctic circumpolar current (ACC) is crucial for ISM increase, because southward advection of heat dominates the warming along the Antarctic coast. On centennial timescales the ACC accelerates due to deep ocean warming north of the current, caused by mixing of heat along isopycnals in the Southern Ocean (SO) outcropping regions. In contrast to previous studies we find an initial weakening of the ACC during the first 150 years of warming. This purely baroclinic effect is due to a freshening in the SO which is consistent with present observations. Comparison with simulations with diagnosed ISM but without its influence on the ocean circulation reveal a number of ISM-related feedbacks, of which a negative ISM-feedback, due to the ISM-related local oceanic cooling, is the dominant one.
The 8.2 ka event : abrupt transition of the subpolar gyre toward a modern North Atlantic circulation
(2010)
Climate model simulations of the 8.2 ka event show an abrupt strengthening of the Atlantic subpolar gyre that allows us to connect two major but apparently contradictory climate events of the early Holocene: the freshwater outburst from proglacial lakes and the onset of Labrador Sea water formation. The 8.2 ka event is the largest climatic signal of our present interglacial with a widespread cooling in the North Atlantic region about 8200 years before present. It coincides with a meltwater outburst from North American proglacial lakes that is believed to have weakened the Atlantic meridional overturning circulation and northward heat transport, followed by a recovery of the deep ocean circulation and rising temperatures after a few centuries. Marine proxy data, however, date the onset of deep water formation in Labrador Sea to the same time. The subsequent strengthening of the slope current system created a regional signal recorded as an abrupt and persistent surface temperature decrease. Although similarities in timing are compelling, a mechanism to reconcile these apparently contradictory events was missing. Our simulations show that an abrupt and persistent strengthening of the Atlantic subpolar gyre provides a plausible explanation. The intense freshwater pulse triggered a transition of the gyre circulation into a different mode of operation, stabilized by internal feedbacks and persistent after the cessation of the perturbation. As a direct consequence, deep water formation around its center intensifies. This corresponds to the modern flow regime and stabilizes the meridional overturning circulation, possibly contributing to the Holocene's climatic stability.
We have studied I lie thermal behavior of amphiphilic, symmetric triblock copolymers having short, deuterated polystyrene (PS) end blocks and a large poly(N-isopropylacrylarnicle) (PNIPAM) middle block exhibiting a lower critical solution temperature (LCST) in aqueous solution. A wide range of concentrations (0.1-300 mg/mL) is investigated using it number of analytical methods such as fluorescence correlation spectroscopy (FCS), turbidimetry, dynamic light scattering (DLS), small-angle neutron scattering (SANS), and neutron spin-echo spectroscopy (NSE). The critical micelle concentration is determined using FCS to be 1 mu M or less. The collapse of the micelles at the LCST is investigated using turbidimetry and DLS and shows a weak dependence on the degree of polymerization of the PNIPAM block. SANS with contrast matching allows its to reveal the core-shell Structure of the micelles as well as their correlation as a function of temperature. The segmental dynamics of the PNIPAM shell are studied as a function of temperature and arc found to be faster in the collapsed state than in the swollen state. The mode detected has a linear dispersion in q(2) and is found to be faster in the collapsed state as compared to the swollen state. We attribute this result to the averaging over mobile and immobilized segments.
Several series of symmetrical triblock copolymers were synthesized by the reversible addition fragmentation chain transfer method. They consist of a long block of poly(N-isopropylacrylamide) as hydrophilic, thermoresponsive middle block, which is end-capped by two small strongly hydrophobic blocks made from five different vinyl polymers. The association of the amphiphilic polymers was studied in dilute and concentrated aqueous solution. The polymer micelles found at low concentrations form hydrogels at high concentrations, typically above 30-35 wt.%. Hydrogel formation and the thermosensitive rheological behavior were studied exemplarily for copolymers with hydrophobic blocks of polystyrene, poly(2-ethylhexyl acrylate), and poly(n-octadecyl acrylate). All systems exhibited a cloud point around 30 A degrees C. Heating beyond the cloud point initially favors hydrogel formation but continued heating results in macroscopic phase separation. The rheological behavior suggests that the copolymers associate into flower-like micelles, with only a small share of polymers that bridge the micelles and act as physical cross-linkers, even at high concentrations.
Isaac Euchel
(2010)
Isaac Euchel (1756-1804) war lange Zeit einer der zu Unrecht vergessenen jüdischen Aufklärer. Das hat sich erst seit wenigen Jahren geändert: Seine bedeutende Rolle innerhalb der Haskala, der jüdischen Aufklärungsbewegung, wurde in der Forschung erkannt, seine wichtigen Schriften in hebräischer und jiddischer Sprache wiederentdeckt, übersetzt und ediert.
Euchel war ein vielseitiger Aufklärer: Er war Verleger und Kaufmann, Autor, Herausgeber und Übersetzer, schrieb in Deutsch, Hebräisch und Jiddisch; er war zugleich in der jüdischen und in der christlichen Gesellschaft zu Hause, war Student Kants und Biograph Mendelssohns. In Königsberg und Berlin wurde er zum Organisator und Vernetzer der über halb Europa verstreuten Anhänger der Haskala, die nach seiner Vorstellung durch die Erneuerung der hebräischen Sprache eine aufgeklärte und moderne jüdische Kultur hervorbringen sollte.
Anlässlich seines 250. Geburtstags trafen sich Historiker, Hebraisten, Jiddisten, Judaisten und Literaturwissenschaftler aus Deutschland, Österreich, Israel und den USA in Potsdam, um auf einer internationalen Tagung unter dem Titel »Vom Nutzen der Aufklärung oder: Woß tut me damit« sein Leben und Werk zu ehren und umfassend zu diskutieren. Der vorliegende Tagungsband bündelt die Früchte dieser Diskussionen und bietet einen Überblick über den Stand der Forschung.
Jesu Wahrnehmung im Judentum war vielgestaltig. Rabbiner Walter Homolka zeichnet eine Geschichte von Abgrenzung und Auseinandersetzung. Im 19. Jahrhundert fuehrte die "Heimholung Jesu" ins Judentum zu einer heute selbstbewussten Position. War Jesus aus juedischer Sicht Pharisaeer und Schriftgelehrter? Vielleicht. War er bedeutend? Ohne Zweifel. War er der Messias oder gar Gottes eigener Sohn? Nach juedischem Verstaendnis nein. Homolkas Buch laedt dazu ein, die zentrale Gestalt des Christentums aus der Perspektive des juedischen Glaubens zu betrachten. Besonders interessant sind die von Homolka aufgezeigten vielfaeltigen Versuche juedischer Wissenschaftler, die Lehre Jesu als "integralen Bestandteil der juedischen Tradition und Geschichte zu begreifen"; Versuche, die auch das christliche Jesus-Bild bereichern koennen - auch wenn juedisches und christliches Jesus-Bild letztlich doch auf entscheidende Weise different bleiben. (ORF Buchtipp)
Risk attitudes influence the complete life cycle of entrepreneurs. Whereas recent research underpins the theoretical proposition of a positive correlation between risk attitudes and the decision to become self-employed, the effects on survival are not as straightforward. Psychological research posits an inverse U-shaped relationship between risk attitudes and entrepreneurial survival. On the basis of experimentally validated data of the German Socio-Economic Panel (SOEP), we examine the extent to which risk attitudes influence survival rates in self-employment in Germany. The empirical results confirm that persons whose risk attitudes are in the medium range survive significantly longer as entrepreneurs than do persons with particularly low or high risk attitudes.
The development of rise Cenozoic East African Rift System (EARS) profoundly re-shaped the landscape and significantly increased the amplitude of short-term environmental response to climate variation. In particular, the development of amplifier lakes in rift basins after three million years ago significantly contributed to this exceptional sensitivity of East Africa to climate change compared to elsewhere on the African continent. Amplifier lakes are characterized by tectonically-formed graben morphologies in combination with an extreme contrast between high precipitation in the elevated parts of the catchment and high evaporation in the lake area. Such amplifier lakes respond rapidly to moderate, precessional-forced climate shifts, and as they do so apply dramatic environmental pressure to the biosphere. Rift basins, when either extremely dry or lake-filled, form important barriers for migration, mixing and competition of different populations of animals and hominins. Amplifier lakes link long-term, high-amplitude tectonic processes and short-term environmental fluctuations. East Africa may have become the place where early humans evolved as a consequence of this strong link between different time scales. (C) 2010 Elsevier Ltd. All rights reserved.
Cenozoic uplift of the East African Plateau has been associated with fundamental climatic and environmental changes in East Africa and adjacent regions. While this influence is widely accepted, the timing and the magnitude of plateau uplift have remained unclear. This uncertainty stems from the lack of datable, geomorphically meaningful reference horizons that could record surface uplift. Here, we document the existence of significant relief along the East African Plateau prior to rifting, as inferred from modeling the emplacement history of one of the longest terrestrial lava flows, the similar to 300-km-long Yatta phonolite flow in Kenya. This 13.5 Ma lava flow originated on the present-day eastern Kenya Rift flank, and utilized a riverbed that once routed runoff from the eastern rim of the plateau. Combining an empirical viscosity model with subsequent cooling and using the Yatta lava flow geometry and underlying paleotopography (slope angle), we found that the prerift slope was at least 0.2 degrees, suggesting that the lava flow originated at a minimum elevation of 1400 m. Hence, high paleotopography in the Kenya Rift region must have existed by at least 13.5 Ma. We infer from this that middle Miocene uplift occurred, which coincides with the two-step expansion of grasslands, as well as important radiation and speciation events in tropical Africa.
Explaining the presence of normal faults in overall compressive settings is a challenging problem in understanding the tectonics of active mountain belts. The Himalayan-Tibetan orogenic system is an excellent setting to approach this problem because it preserves one of the most dramatic records of long-term, contemporaneous shortening and extension. Over the past decades, several studies have described extensional features, not only in the Tibetan Plateau, but also in the Himalaya. For a long time, the favored model explained the function of the Southern Tibetan detachment system, a major fault zone in the Himalaya, as a decoupling horizon between the regime of crustal shortening forming the Himalayan wedge to the south and the extensional regime of the Tibetan Plateau to the north. However, in recent years, increasing evidence has shown that N-S-trending normal faults in the Central Himalaya crosscut not only the Southern Tibetan detachment system, but also the Main Central thrust. Here, we present new structural data and geologic evidence collected within the NW Indian Himalaya and combine them with previously published seismicity data sets in order to document pervasive E-W extension accommodated along N-S-trending faults extending as far south as the footwall of the Main Central thrust. We conducted a kinematic analysis of fault striations on brittle faults, documented and mapped fault scarps in Quaternary sedimentary deposits using satellite imagery, and made field observations in the Greater Sutlej region (Spiti, Lahul, Kinnaur) and the Garhwal Himalaya. Studies of extensional features within the regionally NW- SE-trending NW Indian Himalaya provide the advantage that arc-parallel and E-W extension can be separated, in contrast to the Central Himalaya. Therefore, our observations of E-W extension in the Indian NW Himalaya are well suited to test the applicability of current tectonic models for the whole Himalaya. We favor the interpretation of E-W extension in the NW Indian Himalaya as a propagation of extension driven by collapse of the Tibetan Plateau.
Context. Helicity is a fundamental property of magnetic fields, conserved in ideal MHD. In flux rope geometry, it consists of twist and writhe helicity. Despite the common occurrence of helical structures in the solar atmosphere, little is known about how their shape relates to the writhe, which fraction of helicity is contained in writhe, and how much helicity is exchanged between twist and writhe when they erupt. Aims. Here we perform a quantitative investigation of these questions relevant for coronal flux ropes. Methods. The decomposition of the writhe of a curve into local and nonlocal components greatly facilitates its computation. We use it to study the relation between writhe and projected S shape of helical curves and to measure writhe and twist in numerical simulations of flux rope instabilities. The results are discussed with regard to filament eruptions and coronal mass ejections (CMEs). Results. (1) We demonstrate that the relation between writhe and projected S shape is not unique in principle, but that the ambiguity does not affect low- lying structures, thus supporting the established empirical rule which associates stable forward (reverse) S shaped structures low in the corona with positive (negative) helicity. (2) Kink-unstable erupting flux ropes are found to transform a far smaller fraction of their twist helicity into writhe helicity than often assumed. (3) Confined flux rope eruptions tend to show stronger writhe at low heights than ejective eruptions (CMEs). This argues against suggestions that the writhing facilitates the rise of the rope through the overlying field. (4) Erupting filaments which are S shaped already before the eruption and keep the sign of their axis writhe (which is expected if field of one chirality dominates the source volume of the eruption), must reverse their S shape in the course of the rise. Implications for the occurrence of the helical kink instability in such events are discussed. (5) The writhe of rising loops can easily be estimated from the angle of rotation about the direction of ascent, once the apex height exceeds the footpoint separation significantly. Conclusions. Writhe can straightforwardly be computed for numerical data and can often be estimated from observations. It is useful in interpreting S shaped coronal structures and in constraining models of eruptions.
Testing magnetofrictional extrapolation with the Titov-Demoulin model of solar active regions
(2010)
We examine the nonlinear magnetofrictional extrapolation scheme using the solar active region model by Titov and Demoulin as test field. This model consists of an arched, line-tied current channel held in force-free equilibrium by the potential field of a bipolar flux distribution in the bottom boundary. A modified version with a parabolic current density profile is employed here. We find that the equilibrium is reconstructed with very high accuracy in a representative range of parameter space, using only the vector field in the bottom boundary as input. Structural features formed in the interface between the flux rope and the surrounding arcade - "hyperbolic flux tube" and "bald patch separatrix surface" - are reliably reproduced, as are the flux rope twist and the energy and helicity of the configuration. This demonstrates that force-free fields containing these basic structural elements of solar active regions can be obtained by extrapolation. The influence of the chosen initial condition on the accuracy of reconstruction is also addressed, confirming that the initial field that best matches the external potential field of the model quite naturally leads to the best reconstruction. Extrapolating the magnetogram of a Titov-Demoulin equilibrium in the unstable range of parameter space yields a sequence of two opposing evolutionary phases, which clearly indicate the unstable nature of the configuration: a partial buildup of the flux rope with rising free energy is followed by destruction of the rope, losing most of the free energy.
Exploring the origin and fate of the Magellanic stream with ultraviolet and optical absorption
(2010)
We present an analysis of ionization and metal enrichment in the Magellanic Stream (MS), the nearest gaseous tidal stream, using Hubble Space Telescope/STIS and FUSE ultraviolet spectroscopy of two background active galactic nuclei. The targets are NGC 7469, lying directly behind the MS with log N(H I)(MS) = 18.63 +/- 0.03(stat) +/- 0.08(syst), and Mrk 335, lying 24 degrees.7 away with log N(H I)(MS) = 16.67 +/- 0.05. For NGC 7469, we include optical spectroscopy from VLT/UVES. In both sight lines, the MS is detected in low-ion (O I, C II, C III, Si II, Si III, Al II, Ca II) and high-ion (O VI, C IV, Si IV) absorption. Toward NGC 7469, we measure an MS oxygen abundance [O/H](MS) = [O I/ H I]= -1.00 +/- 0.05(stat) +/- 0.08(syst), supporting the view that the Stream originates in the Small Magellanic Cloud rather than the Large Magellanic Cloud. We use CLOUDY to model the low-ion phase of the Stream as a photoionized plasma using the observed Si III/Si II and C III/C II ratios. Toward Mrk 335, this yields an ionization parameter between log U= -3.45 and -3.15, a gas density log (n(H)/cm(-3)) between-2.51 and -2.21, and a hydrogen ionization fraction of 98.9%- 99.5%. Toward NGC 7469, we derive sub-solar abundance ratios for [Si/O], [Fe/O], and [Al/O], indicating the presence of dust in the MS. The high-ion column densities are too large to be explained by photoionization, but also cannot be explained by a single-temperature collisional ionization model (equilibrium or non-equilibrium). This suggests that the high-ion plasma is multi-phase, with an Si IV region, a hotter O VI region, and C IV potentially contributing to each. Summing over the low-ion and high-ion phases, we derive conservative lower limits on the ratio N(total H II)/N(H I) of greater than or similar to 19 toward NGC 7469 and greater than or similar to 330 toward Mrk 335, showing that along these two directions the vast majority of the Stream has been ionized. The presence of warm-hot plasma together with the small-scale structure observed at 21 cm provides evidence for an evaporative interaction with the hot Galactic corona. This scenario, predicted by hydrodynamical simulations, suggests that the fate of the MS will be to replenish the Galactic corona with new plasma, rather than to bring neutral fuel to the disk.
The statistical distribution of energies among particles responsible for long gamma-ray burst (GRB) emission is analyzed in light of recent results of the Fermi Observatory. The all-sky flux, F., recorded by the Gamma-Ray Burst Monitor (GBM) is shown, despite its larger energy range, to be not significantly larger than that reported by the Burst and Transient Explorer, suggesting a relatively small flux in the 3-30MeV energy range. The present-day energy input rate in gamma-rays recorded by the GBM from long GRBs is found, assuming star formation rates in the literature, to be W(0) = 0.5F gamma H/c = 5x10(42) erg Mpc(-3) yr(-1). The Large Area Telescope fluence, when observed, is about 5%-10% per decade of the total, in good agreement with the predictions of saturated, nonlinear shock acceleration. The high- energy component of long GRBs, as measured by Fermi, is found to contain only similar to 10-2.5 of the energy needed to produce ultrahigh-energy cosmic rays (UHECRs) above 4 EeV, assuming the latter to be extragalactic, when various numerical factors are carefully included, if the cosmic-ray source spectrum has a spectral index of -2. The observed. - ray fraction of the required UHECR energy is even smaller if the source spectrum is softer than E-2. The AMANDA II limits rule out such a GRB origin for UHECRs if much more than 10(-2) of the cosmic-ray energy goes into neutrinos that are within, and simultaneous with, the gamma-ray beam. It is suggested that "orphan" neutrinos out of the gamma-ray beam might be identifiable via orphan afterglow or other wide angle signatures of GRBs in lieu of coincidence with prompt gamma-rays, and it is recommended that feasible single neutrino trigger criteria be established to search for such coincidences.
Amphibole and mica Ar-40/Ar-39 ages as well as zircon, rutile and titanite U-Pb geochronology of eclogites and associated host rocks from the Higher Himalayan Crystalline Nappes (Indian Plate) in the Upper Kaghan Valley, Pakistan allow distinction of a multistage exhumation history. An Eocene age for peak-pressure metamorphism has been obtained by phengite Ar-40/Ar-39 (47.3 +/- 0.3 Ma) and zircon U-Pb (47.3 +/- 0.4 and 47.4 +/- 0.3 Ma) ages from cover and basement gneisses. A very short-lived metamorphic peak and rapid cooling is documented by an amphibole Ar-40/Ar-39 age of 46.6 +/- 0.5 Ma and a rutile U-Pb age of 44.1 +/- 1.3 Ma from eclogites. Phengite and biotite ages from cover and basement sequences metamorphosed during the Himalayan orogeny are 34.5 +/- 0.2 to 28.1 +/- 0.2 Ma whereas youngest biotites, yielding 23.6 +/- 0.1 and 21.7 +/- 0.2 Ma, probably reflect argon partial resetting. The amphibole age, together with those derived from phengite and zircon demonstrate a rate of initial exhumation of 86-143 mm/a i.e. an extremely rapid transport of the Indian Plate continental crust from ultra-high pressure (UHP) conditions back to crustal levels (47-46 Ma for transport from 140 to 40 km depth). Subsequent exhumation (46-41 Ma, 40-35 km) slowed to about 1 mm/a at the base of the continental crust but increased again later towards slightly higher exhumation rates of ca. 2 mm/a (41-34 Ma, 35- 20 km). This indicates a change from buoyancy-driven exhumation at mantle depths to compression forces related to continent-continent collision and accompanied crustal folding, thrusting and stacking that finally exposed the former deeply-buried rocks.
The Eastern Cordillera of the Colombian Andes represents an inverted Cretaceous basin where Cretaceous magmatism is characterized by rare mafic dykes and sills. We use Ar-40/Ar-39, Sr-Nd-Pb isotopes, as well as major and trace elements analyses of Cretaceous intrusions from both flanks of the Eastern Cordillera in combination with structural data to document the complex evolution of the basin. Magmatism, which is diachronous and geochemically diverse, seems to be related to mantle melting beneath the most subsiding segments of each sub-basin during enhanced extensional tectonics. The mafic intrusions display two different compositional series: an alkaline one with OIB-like pattern and a tholeiitic one with MORB-like features. This indicates at least two diverse mantle sources. Trace-element patterns suggest that the intrusions were emplaced in an extensional setting. Ar-40/Ar-39 dating on primary plagioclase and hornblende provides plateau ages between similar to 136 and similar to 74 Ma. The geochemical and temporal diversities show that the emplacement of the magmas was tectonically controlled, each sub-basin reflecting an individual subsidence event.
The influence of the solvent-evaporation rate on the formation of of. and P crystalline phases in solution-cast poly(vinylidene fluoride) (PVDF) films was systematically investigated. Films were crystallized from PVDF/N,N- dimethylformamide solutions with concentrations of 2.5, 5.0, 10, and 20 wt % at different temperatures. During crystallization, the solvent evaporation rate was monitored in situ by means of a semianalytic balance. With this system, it was possible to determine the evaporation rate for different concentrations and temperatures of the solution under specific ambient conditions (pressure, temperature, and humidity). Fourier-Transform InfraRed spectroscopy with Attenuated Total Reflectance revealed the P-phase content in the PVDF films and its dependence on previous evaporation rates. Based on the relation between the evaporation rate and the PVDF phase composition, a consistent explanation for the different amounts of P phase observed at the upper and lower sample surfaces is achieved. Furthermore, the role of the sample thickness has also been studied. The experimental results show that not only the temperature but also the evaporation rate have to be controlled to obtain the desired crystalline phases in solution-cast PVDF films.
A new arrangement of the optical elements in a Thermal-Pulse-Tomography (TPT) setup allows to scan micrometer structures in composite and heterogeneous samples such as polymer-dispersed liquid crystals (PDLCs). The non-destructive TPT technique allows the determination of three-dimensional profiles of polarization and space charge in dielectrics. The samples under study were 12 mu m thick films of a copolymer of vinylidene fluoride with trifluoroethylene P(VDF- TrFE) (65/35) with embedded liquid-crystal droplets. The poling process was performed in direct contact well above the coercive field of the copolymer. The 3D map obtained from scanning with a 10 mu m wide spot shows elliptically shaped areas with liquid-crystal droplets. Considering the droplets as oblate spheroids, their major axis lies in the x-y plane, while their minor axis in the z direction measures 0.5 mu m or more. This result is in good agreement with scanning electron micrographs. It is believed that the major axis is overestimated due to imaging of liquid-crystal clusters.
Scope of this work was the synthesis of homogeneously dispersed silver nanoparticles in the ferroelectric polymer poly(vinylidene fluoride) (PVDF) and the study of the resulting properties affecting both the electro-active matrix and the optically-active nanofiller. In the nanocomposites surface plasmon resonances can be tuned across the UV- vis to the NIR spectral range. From IR spectra and DSC measurements it is concluded that the - to -phase transformation is observed and no degradation of the polymer matrix occurs. Finally, electrical poling was performed in order to investigate the influence of the embedded silver particles on the polarization behavior of the ferroelectric polymer.
Cellular polyethylene-naphthalate (PEN) ferroelectrets are useful as soft and flexible electromechanical transducer materials. Improved cellular PEN foams are prepared by means of a "voiding + inflation + stretching" process and investigated with respect to their structure and their applications-relevant properties. It is found that most of the cellular voids have heights below 8 mu m. The polymer walls do not allow sufficient gas exchange between the voids and the ambient atmosphere, when the cellular films are exposed to atmospheric pressures between a millibar and a few bars. As expected for ferroelectrets, a threshold voltage for charging is observed: A reasonable piezoelectric coefficient d(33) is only found when the charging voltage is higher than 4 kV. Furthermore, d(33) increases with charging voltage and reaches saturation at approximately 8 kV. Annealing after charging or charging at elevated temperatures may enhance the thermal stability of the PEN ferroelectrets. The d(33) of properly annealed samples is stable up to the respective annealing temperatures, but the annealing process reduces the piezoelectric activity of charged ferroelectret films to some extent. Samples charged at suitable elevated temperatures show much better thermal stability than those charged at room temperature, but the charging temperature should be limited to values below the material's glass-transition temperature T-g. Furthermore, the relevant elastic modulus c(33) of PEN ferroelectrets may decrease upon thermal treatment.
The iron-containing ionic liquid (IL) 1-butyl-3-methylimidazolium tetrachloroferrate(III) [Bmim][FeCl4] has been used as a building block in the synthesis of transparent, ion-conducting, and paramagnetic ionogels. UV/Vis spectroscopy shows that the coordination around the Fe(III) ion does slightly change upon incorporation of the IL into PMMA. The thermal stability of the PMMA increases significantly with IL incorporation. In particular, the onset weight loss observed at ca. 265 degrees C for pure PMMA is completely suppressed. The ionic conductivity shows a strong temperature dependence and increases with increasing IL weight fractions. The magnetic properties are similar to those reported for the pure IL and are not affected by the incorporation into the PMMA matrix. The resulting ionogel is thus an interesting prototype for soft, flexible, and transparent materials combining the mechanical properties of the matrix with the functionality of the metal-containing IL, such as magnetism.
This study models maximum temperatures in Switzerland monitored in twelve locations using the generalised extreme value (GEV) distribution. The parameters of the GEV distribution are determined within a Bayesian framework. We find that the parameters of the underlying distribution underwent a substantial change in the beginning of the 1980s. This change is characterised by an increase both in the level and the variability. We assess the likelihood of the heat wave of the summer 2003 using the fitted GEV distribution by accounting for the presence of a structural break. The estimation results do suggest that the heat wave of 2003 is not that statistically improbable if an appropriate methodology is used for dealing with nonstationarity.