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Raumwissen als Raumpolitik?
(2018)
Weltweit verursachen Städte etwa 70 % der Treibhausgasemissionen und sind daher wichtige Akteure im Klimaschutz bzw. eine wichtige Zielgruppe von Klimapolitiken. Gleichzeitig sind Städte besonders stark von möglichen Auswirkungen des Klimawandels betroffen: Insbesondere extreme Wetterereignisse wie Hitzewellen oder Starkregenereignisse mit Überflutungen verursachen in Städten hohe Sachschäden und wirken sich negativ auf die Gesundheit der städtischen Bevölkerung aus. Daher verfolgt das Projekt ExTrass das Ziel, die städtische Resilienz gegenüber extremen Wetterereignissen in enger Zusammenarbeit mit Stadtverwaltungen, Strukturen des Bevölkerungsschutzes und der Zivilgesellschaft zu stärken. Im Fokus stehen dabei (kreisfreie) Groß- und Mittelstädte mit 50.000 bis 500.000 Einwohnern, insbesondere die Fallstudienstädte Potsdam, Remscheid und Würzburg.
Der vorliegende Bericht beinhaltet die Ergebnisse der 14-monatigen Definitionsphase von ExTrass, in der vor allem die Abstimmung eines Arbeitsprogramms im Mittelpunkt stand, das in einem nachfolgenden dreijährigen Forschungsprojekt (F+E-Phase) gemeinsam von Wissenschaft und Praxispartnern umgesetzt werden soll. Begleitend wurde eine Bestandsaufnahme von Klimaanpassungs- und Klimaschutzstrategien/-plänen in 99 deutschen Groß- und Mittelstädten vorgenommen. Zudem wurden für Potsdam und Würzburg Pfadanalysen für die Klimapolitik durchgeführt. Darin wird insbesondere die Bedeutung von Schlüsselakteuren deutlich. Weiterhin wurden im Rahmen von Stakeholder-Workshops Anpassungsherausforderungen und aktuelle Handlungsbedarfe in den Fallstudienstädten identifiziert und Lösungsansätze erarbeitet, die in der F+E-Phase entwickelt und getestet werden sollen. Neben Maßnahmen auf gesamtstädtischer Ebene und auf Stadtteilebene wurden Maßnahmen angestrebt, die die Risikowahrnehmung, Vorsorge und Selbsthilfefähigkeit von Unternehmen und Bevölkerung stärken können. Daher wurde der Stand der Risikokommunikation in Deutschland für das Projekt aufgearbeitet und eine erste Evaluation von Risikokommunikationswerkzeugen durchgeführt. Der Bericht endet mit einer Kurzfassung des Arbeitsprogramms 2018-2021.
This study adopts a cognitive approach to the analysis of the use of the Spanish imperfecto as a construal form for the conceptualization of state of affairs in certain journalistic texts. In doing so, the main focus of the study is to investigate cognitive processes like modalization and subjectivization, which are related to the speaker’s standpoint and to his subjective, not grammatically motivated, decision to use the imperfective instead of the perfective form. By the help of the corpus programmes GlossaNet and CREA (corpus of the Real Academia Española) we analyze the imperfective use of some Spanish verbs, which are semantically perfective in nature so that the normative use would require a perfective form. In other words, we investigate how the speaker/journalist construes a reality or situation to be expressed by means of the imperfecto and show that this use of the imperfect is typical for journalistic discourse.
Aus dem Inhalt:
▪ Die Interpretation von Menschenrechtsnormen durch die Vertragsausschüsse der Vereinten Nationen
▪ Kinderrechtliche Aspekte zur Aussetzung des Familiennachzugs zu subsidiär Schutzberechtigten nach § 104 Abs. 13 AufenthG
▪ 25 Jahre nach dem „Asylkompromiss“ – die neopragmatische Entwicklung der Menschenrechte von Asylsuchenden
▪ Zur Historie und Zukunft der Meinungsfreiheit. Der dauernde Kampf um ein bewegtes Gut
Im Rahmen des Berliner Projekts „Sprachen-Bilden-Chancen. Innovationen für das Berliner Lehramt“ wurde unter anderem das „Instrument zur sprachbildenden Analyse von Aufgaben im Fach (isaf)“ entwickelt, welches eine Hilfestellung bei der Analyse sprachlicher Anforderungen von (Lern-)Aufgaben darstellt. Ziel des Instruments ist die Förderung der Analyse- und Planungskompetenzen von (angehenden) Lehrkräften. Im Rahmen des Teilprojekts „Sprachliche Heterogenität als Herausforderung für die Lehrerbildung“ des Projekts „PSI (Professionalisierung, Schulpraktische Studien und Inklusion)“ an der Universität Potsdam wurde isaf in der Didaktik der Physik erprobt. Auf Basis der Erprobungsergebnisse sowie der Ergebnisse eines fächerübergreifenden Workshops wurde die hier vorliegende Adaption entwickelt, die um Begriffserläuterungen und Literaturhinweise ergänzt wurde.
Due to a challenging population growth and environmental changes, a need for new routes to provide required chemicals for human necessities arises. An effective solution discussed in this thesis is industrial heterogeneous catalysis. The development of an advanced industrial heterogeneous catalyst is investigated herein by considering porous carbon nano-material as supports and modifying their surface chemistry structure with heteroatoms. Such modifications showed a significant influence on the performance of the catalyst and provided a deeper insight regarding the interaction between the surface structure of the catalyst and the surrounding phase. This thesis contributes to the few present studies about heteroatoms effect on the catalyst performance and emphasizes on the importance of understanding surface structure functionalization in a catalyst in different phases (liquid and gaseous) and for different reactions (hydrogenolysis, oxidation, and hydrogenation/ polymerization). Herein, the heteroatoms utilized for the modifications are hydrogen (H), oxygen (O), and nitrogen (N). The heteroatoms effect on the metal particle size, on the polarity of the support/ the catalyst, on the catalytic performance (activity, selectivity, and stability), and on the interaction with the surrounding phase has been explored. First hierarchical porous carbon nanomaterials functionalized with heteroatoms (N) is synthesized and applied as supports for nickel nanoparticles for hydrogenolysis process of kraft lignin in liquid phase. This reaction has been performed in batch and flow reactors for three different catalysts, two of comparable hierarchical porosity, yet one is modified with N and the other is not, and a third is a prepared catalyst from a commercial carbon support. The reaction production and analyses show that the catalysts with hierarchical porosity perform catalytically much better than in presence of a commercial carbon support with lower surface area. Moreover, the modification with N-heteroatoms enhanced the catalytic performance because the heteroatom modified porous carbon material with nickel nanoparticles catalyst (Ni-NDC) performed highest among the other catalysts. In the flow reactor, Ni-NDC selectively degraded the ether bonds (β-O-4) in kraft lignin with an activity of 2.2 x10^-4 mg lignin mg Ni-1 s-1 for 50 h at 350°C and 3.5 mL min-1 flow, providing ~99 % conversion to shorter chained chemicals (mainly guaiacol derivatives). Then, the functionalization of carbon surface was further studied in selective oxidation of glucose to gluconic acid using < 1 wt. % of gold (Au) deposited on the previously-mentioned synthesized carbon (C) supports with different functionalities (Au-CGlucose, Au-CGlucose-H, Au-CGlucose-O, Au-CGlucoseamine). Except for Au-CGlucose-O, the other catalysts achieved full glucose conversion within 40-120 min and 100% selectivity towards gluconic acid with a maximum activity of 1.5 molGlucose molAu-1 s-1 in an aqueous phase at 45 °C and pH 9. Each heteroatom influenced the polarity of the carbon differently, affecting by that the deposition of Au on the support and thus the activity of the catalyst and its selectivity. The heteroatom effect was further investigated in a gas phase. The Fischer-Tropsch reaction was applied to convert synthetic gas (CO and H2) to short olefins and paraffins using surface-functionalized carbon nanotubes (CNTs) with heteroatoms as supports for ion (Fe) deposition in presence and absence of promoters (Na and S). The results showed the promoted Fe-CNT doped with nitrogen catalyst to be stable up to 180 h and selective to the formation of olefins (~ 47 %) and paraffins (~6 %) with a conversion of CO ~ 92 % at a maximum activity of 94 *10^-5 mol CO g Fe-1 s-1. The more information given regarding this topic can open wide range of applications not only in catalysis, but in other approaches as well. In conclusion, incorporation of heteroatoms can be the next approach for an advanced industrial heterogeneous catalyst, but also for other applications (e.g. electrocatalysis, gas adsorption, or supercapacitors).
In welcher Beziehung steht die praktische Philosophie zur Wirklichkeit der Menschenrechtsfragen in Recht und Politik? Wie kann und soll sie sich ihrem komplexen Gegenstand nähern? Inwieweit kommt ihr die Aufgabe zu, politisches Geschehen konkret zu kommentieren und Vorschläge für die Implementierung menschenrechtstheoretischer Annahmen zu machen? Wie lässt sie sich als anwendungsorientierte Disziplin denken, die jenseits reiner Begründungsdiskurse einen Beitrag zur globalen Stärkung der Menschenrechtsidee leistet?
Der vorliegende Sammelband geht diesen und verwandten Fragen in acht Beiträgen mit jeweils einem Kommentar nach und regt damit zum Nachdenken über das Selbstverständnis zeitgenössischer Menschenrechtsphilosophie an.
Der Jüdische Kalender für das Jahr 5779 des Judaica-Portal Berlin-Brandenburg stellt jede der beteiligten Bibliothek auf einem Kalenderblatt vor. Auf der Vorderseite befindet sich jeweils ein doppeltes Kalendarium: Die Kalenderblätter folgen dem christlichen Jahr, parallel dazu sind die entsprechenden jüdischen Monatsangaben angegeben. Jüdische Feiertage werden durch hervorgehobene Zahlen im Kalendarium angezeigt. Auf der Rückseite finden sich diese Feiertage aufgelistet, ebenso wie die jüdischen Monatsnamen in lateinischer Schrift.
Zudem befindet sich auf der Vorderseite jeweils ein repräsentatives Bild der Bibliothek, mit dem daneben befindlichen QR-Code gelangt man direkt zum jeweiligen Bucheintrag im Judiaca-Portal. Auf der Rückseite gibt es eine kurze Bildbeschreibung zum abgedruckten Bild.
Zusätzlich stellt sich auf der Rückseite jede Bibliothek vor. Hier findet man die wichtigsten Informationen und Kontaktdaten.
Das Judaica-Portal Berlin-Brandenburg ist ein Gemeinschaftsprojekt des Selma Stern Zentrums für Jüdische Studien Berlin-Brandenburg in Zusammenarbeit mit dem Kooperativen Bibliotheksverbund Berlin-Brandenburg (KOBV). Sie stellen sich gemeinsam auf einem Kalenderblatt vor. Daneben finden Sie Kalenderblätter folgender Bibliotheken:
• UB der Universität Potsdam
• UB der Freien Universität Berlin
• UB der Humboldt-Universität Berlin
• UB der Europa-Universität Viadrina Frankfurt (Oder)
• Staatsbibliothek zu Berlin – Preußischer Kulturbesitz
• Bibliothek des Zentrum für Antisemitismusforschung der Technischen Universität Berlin
• Bibliothek des Abraham Geiger Kollegs
• Bibliothek des Moses Mendelssohn Zentrums für europäisch-jüdische Studien
• Bibliothek des Jüdischen Museums Berlin
• Bibliothek der Jüdischen Gemeinde zu Berlin
• Bibliothek Institut Kirche und Judentum
• UB Johann Christian Senckenberg Frankfurt am Main
• Israelische Nationalbibliothek Jerusalem (RAMBI)
Three Essays on EFRAG
(2018)
This cumulative doctoral thesis consists of three papers that deal with the role of one specific European accounting player in the international accounting standard-setting, namely the European Financial Reporting Advisory Group (EFRAG). The first paper examines whether and how EFRAG generally fulfills its role in articulating Europe’s interests toward the International Accounting Standards Board (IASB). The qualitative data from the conducted interviews reveal that EFRAG influences the IASB’s decision making at a very early stage, long before other constituents are officially asked to comment on the IASB’s proposals. The second paper uses quantitative data and investigates the formal participation behavior of European constituents that seek to determine EFRAG’s voice. More precisely, this paper analyzes the nature of the constituents’ participation in EFRAG’s due process in terms of representation (constituent groups and geographical distribution) and the drivers of their participation behavior. EFRAG’s official decision making process is dominated by some specific constituent groups (such as preparers and the accounting profession) and by constituents from some specific countries (e.g. those with effective enforcement regimes). The third paper investigates in a first step who of the European constituents choose which lobbying channel (participation only at IASB, only at EFRAG, or at both institutions) and unveils in a second step possible reasons for their lobbying choices. The paper comprises quantitative and qualitative data. It reveals that English skills, time issues, the size of the constituent, and the country of origin are factors that can explain why the majority participates only in the IASB’s due process.
Holocene climate variability is generally characterized by low frequency changes than compared to the last glaciations including the Lateglacial. However, there is vast evidence for decadal to centennial scale oscillations and millennial scale climate trends, which are within and beyond a human lifetime perception, respectively. Within the Baltic realm, a transitional zone between oceanic and continental climate influence, the impact of Holocene and Lateglacial climate and environmental change is currently partly understood. This is mainly attributed to the scarcity of well-dated and high-resolution sediment records and to the lacking continuity of already investigated archives.
The aim of this doctoral thesis is to reconstruct Holocene and Late Glacial climate variability on local to (over)regional scales based on varved (annually laminated) sediments from Lake Czechowskie down to annual resolution. This project was carried out within the Virtual Institute for Integrated Climate and Landscape Evolution Analyses (ICLEA) and funded by the Helmholtz Association and the Helmholtz Climate Initiative REKLIM (Regional Climate Change). ICLEA intended to gain a better understanding of climate variability and landscape evolution processes in the Northern Central European lowlands since the last deglaciation. REKLIM Topic 8 “Abrupt climate change derived from proxy data” aims at identifying spatiotemporal patterns of climate variability between e.g. higher and lower latitudes. The main aim of this thesis was (i) to establish a robust chronology based on a multiple dating approach for Lake Czechowskie covering the Late Glacial and Holocene and for the Trzechowskie palaeolake for the Lateglacial, respectively, (ii) to reconstruct past climatic and environmental conditions on centennial to multi-millennial time scales and (iii) to distinguish between local to regional different sediments responses to climate change.
Addressing the first aim, the Lake Czechowskie chronology has been established by a multiple dating approach comprising information from varve counting, tephrochronology, AMS 14C dating of terrestrial plant remains, biostratigraphy and 137Cs activity concentration measurements. Those independent age constraints covering the Lateglacial and the entire Holocene and have been further implemented in a Bayesian age model by using OxCal v.4.2. Thus, even within non-varved sediment intervals, robust chronological information has been used for absolute age determination. The identification of five cryptotephras, of which three are used as unambiguous isochrones, is furthermore a significant improvement of the Czechowskie chronology and currently unique for the Holocene within Poland. The first findings of coexisting early Holocene Hässeldalen and Askja-S cryptotephras within a varved sequence even allowed differential dating between both volcanic ashes and stimulated the discussion of revising the absolute ages of the Askja-S tephra.
The Trzechowskie palaeolake chronology has been established by a multiple dating approach comprising varve counting, tephrochronology, AMS 14C dating of terrestrial plant remains and biostratigraphy, covers the Lateglacial period (Allerød and Younger Dryas) and has been implemented in OxCal v.4.2. Those age constraints allowed regional correlation to other high-resolution climate archives and identifying leads and lags of proxy responses at the onset of the Younger Dryas.
The second aim has been accomplished by detailed micro-facies and geochemical analyses of the Czechowskie sediments for the entire Holocene. Thus, especially micro-facies changes had been linked to enhanced productivity at Lake Czechowskie. Most prominent changes have been recorded at 7.3, 6.5, 4.3 and 2.8 varve kyrs BP and are linked to a stepwise increasing influence of Atlantic air masses. Especially, the mid-Holocene change, which had been widely reported from palaeohydrological records in low latitudes, has been identified and linked to large scale reorganization of atmospheric circulation patterns. Thus, especially long-term changes of climatic and environmental boundary conditions are widely recorded by the Czechowskie sediments. The pronounced response to (multi)millennial scale changes is further corroborated by the lack of clear sediment responses to early Holocene centennial scale climate oscillations (e.g. the Preboreal Oscillation).
However, decadal scale changes at Lake Czechowskie during the most recent period (last 140 years) have been investigated in a lake comparison study. To fulfill the third aim of the doctoral thesis, three lakes in close vicinity to each other have been investigated in order to better distinguish how local, site-specific parameters, may superimpose regional climate driven changes. All lakes haven been unambiguously linked by the Askja AD1875 cryptotephra and independent varve chronologies. As a result, climate warming has only been recorded by sedimentation changes at the smallest and best sheltered lake (Głęboczek), whereas the largest lake (Czechowskie) and the shallowest lake (Jelonek) showed attenuated and less clear sediment responses, respectively. The different responses have been linked to morphological lake characteristics (lake size and depth, catchment area). This study highlights the potential of high-resolution lake comparison for robust proxy based climate reconstructions.
In summary, the doctoral thesis presents a high-resolution sediment record with an underlying age model, which is prerequisite for unprecedented age control down to annual resolution. Sediment proxy based climate reconstructions demonstrate the importance of the Czechowskie sediments for better understanding climate variability in the southern Baltic realm. Case studies showed the clear response on millennial time scale, while decadal scale fluctuations are either less well expressed or superimposed by local, site-specific parameters. The identification of volcanic ash layers is not only used for unambiguous isochrones, those are key tie lines for local to supra regional archive synchronization and establish the Lake Czechowskie as a key climate archive.
d.art
(2018)
Der Konzeptband dokumentiert den Aufbau und die Durchführung der pädagogischen Weiterbildung „d.art“. Der Band richtet sich an zukünftige Weiterbildungsanbietende und Weiterbildende, die ähnliche pädagogische Weiterbildungen durchführen wollen. Das vom BMBF (Bundesministerium für Bildung und Forschung) geförderte Projekt umfasste zwei Teilprojekte: erstens die Entwicklung eines Konzepts für die pädagogische Weiterbildung von Kunstschaffenden und zweitens die Evaluation der Bildungs- und Lernprozesse, welche die Kunstschaffenden im Verlauf der Weiterbildung durchliefen. Es werden Anregungen und Begründungen für eine pädagogische Weiterbildung von Kunstschaffenden geboten, mit der die Qualität ästhetischer Bildungsprojekte steigt. Die Professur für Erwachsenenbildung an der Universität Potsdam (Prof. Dr. Joachim Ludwig) hat mit insgesamt 41 Brandenburger und Berliner Künstler*innen (KuK) aller Kunstsparten in drei Weiterbildungsdurchgängen (2014-2017) dieses Konzept erprobt und entwickelt. Die KuK planen im Rahmen der Weiterbildung außerunterrichtliche Angebote ästhetischer Bildung an Ganztagsschulen, führen zwei Praxisprojekte durch und reflektieren in den Workshops ihre Erfahrungen. Eine Didaktik vom Standpunkt der Lernenden ist die Leitidee der Weiterbildung. Die Selbstbildungsprozesse der KuK werden in dieser Weiterbildung zum Ausgangspunkt gemacht, unterstützt und begleitet. Aus der Perspektive der Weiterbildungsanbietenden standen vier Themenfelder im Vordergrund, die mit den Anliegen der KuK gekoppelt wurden. Dabei fällt auf, dass methodische Fragen weitgehend ausgespart wurden. Dies war möglich, weil KuK eigene ästhetische Weltzugänge anbieten können. Stattdessen wurde die pädagogische Beziehung mit ihren grundlegenden Spannungsverhältnissen in den Vordergrund gestellt. Im ersten Teil des Bandes werden der Weiterbildungsverlauf, die Inhalte der vier Themenfelder (künstlerisches Selbstverständnis, ästhetische Bildung, didaktische Herausforderungen, Schule als Projektraum) und die Lernbegleitungsformate detailliert vorgestellt. Im zweiten Teil werden ausführliche bildungs- und lerntheoretische Grundlagen beschrieben, auf denen das Konzept aufbaut.
Magnetotellurics (MT) is a geophysical method that is able to image the electrical conductivity structure of the subsurface by recording time series of natural electromagnetic (EM) field variations. During the data processing these time series are divided into small segments and for each segment spectral values are computed which are typically averaged in a statistical manner to obtain MT transfer functions. Unfortunately, the presence of man-made EM noise sources often deteriorates a significant amount of the recorded time series resulting in disturbed transfer functions. Many advanced processing techniques, e.g. robust statistics, pre-stack data selection or remote reference, have been developed to tackle this problem. The first two techniques reduce the amount of outliers and noise in the data whereas the latter approach removes noise by using data from another MT station. However, especially in populated regions the data processing is still quite challenging even with these approaches. In this thesis, I present two novel pre-stack data confinement and selection criteria for the detection of outliers and noise affected data based on (i) a distance measure of each data segment with regard to the entire sample distribution and (ii) the evaluation of the magnetic polarisation direction of all segments. The first criterion is able to remove data points that scatter around the desired MT distribution and furthermore it can, under some circumstances, even reject complete data cluster originating from noise sources. The second criterion eliminates data points caused by a strongly polarised magnetic signal. Both criteria have been successfully applied to many stations with different noise contaminations showing that they can significantly improve the transfer function estimation. The novel criteria were used to evaluate a MT data set from the Eastern Karoo Basin in South Africa. The corresponding field experiment is part of an extensive research programme to collect information of the current e.g. geological setting in this region prior to a potential shale gas exploitation. The aim was to investigate whether a three-dimensional (3D) inversion of the newly measured data fosters a more realistic mapping of physical properties of the target horizon. For this purpose, a comprehensive 3D model was derived by using all available data. In a second step, I analysed parameters of the target horizon, e.g. its conductivity, that are proxies for physical properties such as thermal maturity and porosity.
Verbrannte Erde
(2018)
Innerhalb des öffentlichen und politischen Diskurses in Deutschland nehmen die Verbrechen in den ehemaligen Kolonien des Deutschen Kaiserreichs einen kaum wahrnehmbaren Platz ein. Rückt der Völkermord an den Herero und Nama in Deutsch-Südwestafrika seit ein paar Jahren vermehrt ins Licht der Öffentlichkeit, so sind die Kolonialkriege in Deutsch-Ostafrika, die mehrere Hunderttausend Afrikaner das Leben kosteten, nahezu vergessen. Frederik Haug analysiert den erinnerungspolitischen Umgang der Bundesregierung mit den Verbrechen, die die deutsche „Schutztruppe“ in Ostafrika vor über einem Jahrhundert verübte. Er untersucht dabei sowohl die Charakteristika dieser Haltung als auch die Gründe für eine solche Positionierung.
Die 8. Fachtagung für Hochschuldidaktik der Informatik (HDI) fand im September 2018 zusammen mit der Deutschen E-Learning Fachtagung Informatik (DeLFI) unter dem gemeinsamen Motto „Digitalisierungswahnsinn? - Wege der Bildungstransformationen“ in Frankfurt statt.
Dabei widmet sich die HDI allen Fragen der informatischen Bildung im Hochschulbereich. Schwerpunkte bildeten in diesem Jahr u. a.:
- Analyse der Inhalte und anzustrebenden Kompetenzen in Informatikveranstaltungen
- Programmieren lernen & Einstieg in Softwareentwicklung
- Spezialthemen: Data Science, Theoretische Informatik und Wissenschaftliches Arbeiten
Die Fachtagung widmet sich ausgewählten Fragestellungen dieser Themenkomplexe, die durch Vorträge ausgewiesener Experten und durch eingereichte Beiträge intensiv behandelt werden.
Inhalt:
-Ulrich Päßler: Die edition humboldt digital. Dokumente zur Neuausgabe der Ideen zu einer Geographie der Pflanzen (1825–1826)
-Reinhard Andress: Eduard Dorsch and his unpublished poem on the occasion of Humboldt’s 100th birthday
-Vicente Durán Casas: Immanuel Kant, Alexander von Humboldt and the Tequendama Fall. Two Prussians linked by Geography
-Ottmar Ette: Languages about Languages: Two Brothers and one Humboldtian Science
-Dagmar Hülsenberg: Alexander von Humboldts Erläuterungen zu Öfen
für die Herstellung von Keramik- und Glaserzeugnissen
-Thomas Schmuck: Missglückte Begegnung. Der kurze Briefwechsel zwischen Leopold von Buch und Goethe
-Werner Sundermann: Alexander von Humboldt und das Persische
Earth's climate varies continuously across space and time, but humankind has witnessed only a small snapshot of its entire history, and instrumentally documented it for a mere 200 years. Our knowledge of past climate changes is therefore almost exclusively based on indirect proxy data, i.e. on indicators which are sensitive to changes in climatic variables and stored in environmental archives. Extracting the data from these archives allows retrieval of the information from earlier times. Obtaining accurate proxy information is a key means to test model predictions of the past climate, and only after such validation can the models be used to reliably forecast future changes in our warming world. The polar ice sheets of Greenland and Antarctica are one major climate archive, which record information about local air temperatures by means of the isotopic composition of the water molecules embedded in the ice. However, this temperature proxy is, as any indirect climate data, not a perfect recorder of past climatic variations. Apart from local air temperatures, a multitude of other processes affect the mean and variability of the isotopic data, which hinders their direct interpretation in terms of climate variations. This applies especially to regions with little annual accumulation of snow, such as the Antarctic Plateau. While these areas in principle allow for the extraction of isotope records reaching far back in time, a strong corruption of the temperature signal originally encoded in the isotopic data of the snow is expected. This dissertation uses observational isotope data from Antarctica, focussing especially on the East Antarctic low-accumulation area around the Kohnen Station ice-core drilling site, together with statistical and physical methods, to improve our understanding of the spatial and temporal isotope variability across different scales, and thus to enhance the applicability of the proxy for estimating past temperature variability. The presented results lead to a quantitative explanation of the local-scale (1–500 m) spatial variability in the form of a statistical noise model, and reveal the main source of the temporal variability to be the mixture of a climatic seasonal cycle in temperature and the effect of diffusional smoothing acting on temporally uncorrelated noise. These findings put significant limits on the representativity of single isotope records in terms of local air temperature, and impact the interpretation of apparent cyclicalities in the records. Furthermore, to extend the analyses to larger scales, the timescale-dependency of observed Holocene isotope variability is studied. This offers a deeper understanding of the nature of the variations, and is crucial for unravelling the embedded true temperature variability over a wide range of timescales.
The present paper discusses the relationship between evidentiality and (inter-) subjectivity and argues that the two semantic-functional categories need not be mutually exclusive. In the use of certain means of expression and in certain contexts, both evidentiality and (inter-) subjectivity may be conveyed simultaneously. I thereby differentiate between two meanings of intersubjectivity, namely ‘intersubjectivity1’ and ‘intersubjectivity2’. Intersubjectivity1 refers to the notion of common or general knowledge: certain means of expression are seen as being intersubjectively used when the speaker shares or assumes sharing knowledge with the interlocutor. Intersubjectivity2 is related to particular discourse functions of certain means of expression in interactional settings, paying attention to the speaker-hearer constellation.
In order to substantiate the theoretical part of the paper, I then present a qualitative analysis of Portuguese, Spanish and English examples, which are taken from the Corpus do Português, Corpus del Español and the Corpus of Contemporary American English.
Reversible-deactivation radical polymerization (RDRP) is without any doubt one of the most prevalent and powerful strategies for polymer synthesis, by which well-defined living polymers with targeted molecular weight (MW), low molar dispersity (Ɖ) and diverse morphologies can be prepared in a controlled fashion. Atom transfer radical polymerization (ATRP) as one of the most extensive studied types of RDRP has been particularly emphasized due to the high accessibility to hybrid materials, multifunctional copolymers and diverse end group functionalities via commercially available precursors. However, due to catalyst-induced side reactions and chain-chain coupling termination in bulk environment, synthesis of high MW polymers with uniform chain length (low Ɖ) and highly-preserved chain-end fidelity is usually challenging. Besides, owing to the inherited radical nature, the control of microstructure, namely tacticity control, is another laborious task. Considering the applied catalysts, the utilization of large amounts of non-reusable transition metal ions which lead to cumbersome purification process, product contamination and complicated reaction procedures all delimit the scope ATRP techniques.
Metal-organic frameworks (MOFs) are an emerging type of porous materials combing the properties of both organic polymers and inorganic crystals, characterized with well-defined crystalline framework, high specific surface area, tunable porous structure and versatile nanochannel functionalities. These promising properties of MOFs have thoroughly revolutionized academic research and applications in tremendous aspects, including gas processing, sensing, photoluminescence, catalysis and compartmentalized polymerization. Through functionalization, the microenvironment of MOF nanochannel can be precisely devised and tailored with specified functional groups for individual host-guest interactions. Furthermore, properties of high transition metal density, accessible catalytic sites and crystalline particles all indicate MOFs as prominent heterogeneous catalysts which open a new avenue towards unprecedented catalytic performance. Although beneficial properties in catalysis, high agglomeration and poor dispersibility restrain the potential catalytic capacity to certain degree.
Due to thriving development of MOF sciences, fundamental polymer science is undergoing a significant transformation, and the advanced polymerization strategy can eventually refine the intrinsic drawbacks of MOF solids reversely. Therefore, in the present thesis, a combination of low-dimensional polymers with crystalline MOFs is demonstrated as a robust and comprehensive approach to gain the bilateral advantages from polymers (flexibility, dispersibility) and MOFs (stability, crystallinity). The utilization of MOFs for in-situ polymerizations and catalytic purposes can be realized to synthesize intriguing polymers in a facile and universal process to expand the applicability of conventional ATRP methodology. On the other hand, through the formation of MOF/polymer composites by surface functionalization, the MOF particles with environment-adjustable dispersibility and high catalytic property can be as-prepared.
In the present thesis, an approach via combination of confined porous textures from MOFs and controlled radical polymerization is proposed to advance synthetic polymer chemistry. Zn2(bdc)2(dabco) (Znbdc) and the initiator-functionalized Zn MOFs, ZnBrbdc, are utilized as a reaction environment for in-situ polymerization of various size-dependent methacrylate monomers (i.e. methyl, ethyl, benzyl and isobornyl methacrylate) through (surface-initiated) activators regenerated by electron transfer (ARGET/SI-ARGET) ATRP, resulting in polymers with control over dispersity, end functionalities and tacticity with respect to distinct molecular size. While the functionalized MOFs are applied, due to the strengthened compartmentalization effect, the accommodated polymers with molecular weight up to 392,000 can be achieved. Moreover, a significant improvement in end-group fidelity and stereocontrol can be observed. The results highlight a combination of MOFs and ATRP is a promising and universal methodology to synthesize versatile well-defined polymers with high molecular weight, increment in isotactic trial and the preserved chain-end functionality.
More than being a host only, MOFs can act as heterogeneous catalysts for metal-catalyzed polymerizations. A Cu(II)-based MOF, Cu2(bdc)2(dabco), is demonstrated as a heterogeneous, universal catalyst for both thermal or visible light-triggered ARGET ATRP with expanded monomer range. The accessible catalytic metal sites enable the Cu(II) MOF to polymerize various monomers, including benzyl methacrylate (BzMA), styrene, methyl methacrylate (MMA), 2-(dimethylamino)ethyl methacrylate (DMAEMA) in the fashion of ARGET ATRP. Furthermore, due to the robust frameworks, surpassing the conventional homogeneous catalyst, the Cu(II) MOF can tolerate strongly coordinating monomers and polymerize challenging monomers (i.e. 4-vinyl pyridine, 2-vinyl pyridine and isoprene), in a well-controlled fashion. Therefore, a synthetic procedure can be significantly simplified, and catalyst-resulted chelation can be avoided as well. Like other heterogeneous catalysts, the Cu(II) MOF catalytic complexes can be easily collected by centrifugation and recycled for an arbitrary amount of times.
The Cu(II) MOF, composed of photostimulable metal sites, is further used to catalyze controlled photopolymerization under visible light and requires no external photoinitiator, dye sensitizer or ligand. A simple light trigger allows the photoreduction of Cu(II) to the active Cu(I) state, enabling controlled polymerization in the form of ARGET ATRP. More than polymerization application, the synergic effect between MOF frameworks and incorporated nucleophilic monomers/molecules is also observed, where the formation of associating complexes is able to adjust the photochemical and electrochemical properties of the Cu(II) MOF, altering the band gap and light harvesting behavior. Owing to the tunable photoabsorption property resulting from the coordinating guests, photoinduced Reversible-deactivation radical polymerization (PRDRP) can be achieved to further simplify and fasten the polymerization.
More than the adjustable photoabsorption ability, the synergistic strategy via a combination of controlled/living polymerization technique and crystalline MOFs can be again evidenced as demonstrated in the MOF-based heterogeneous catalysts with enhanced dispersibility in solution. Through introducing hollow pollen pivots with surface immobilized environment-responsive polymer, PDMAEMA, highly dispersed MOF nanocrystals can be prepared after associating on polymer brushes via the intrinsic amine functionality in each DMAEMA monomer. Intriguingly, the pollen-PDMAEMA composite can serve as a “smart” anchor to trap nanoMOF particles with improved dispersibility, and thus to significantly enhance liquid-phase photocatalytic performance. Furthermore, the catalytic activity can be switched on and off via stimulable coil-to-globule transition of the PDMAEMA chains exposing or burying MOF catalytic sites, respectively.
www.BrAnD2.Wissen.
(2018)
Mit „Wissen“ kommt der zweite Durchgang des insgesamt dreijährigen Brandenburger Antike-Denkwerks zum Abschluss, das der Zusammenarbeit zwischen der Klassischen Philologie der Universität Potsdam und ausgewählten Brandenburger Gymnasien dient und von der Robert Bosch Stiftung gefördert wird.
Der vorliegende Band enthält zum einen die beiden Impulsvorträge vom Potsdamer Lateintag im Oktober 2017: Prof. Dr. Claudia Tiersch zeigt, inwiefern sich im antiken Rom Raumwissen als Raumpolitik offenbarte, und Frau PD Dr. Nicola Hömke beleuchtet den Streit um die „richtige“ Wissensvermittlung an römische Schüler in der ausgehenden Republik. Zum anderen sind die fantasievollen Ergebnisse dokumentiert, die die Schüler zusammen mit ihren studentischen Mentoren in der mehrmonatigen Projektphase zum Thema „Wissen“ erarbeiteten und auf einem eigenen Schülerkongress im März 2018 präsentierten.