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Mosses are a major component of the arctic vegetation, particularly in wetlands. We present C / N atomic ratio, delta C-13 and delta N-15 data of 400 brown-moss samples belonging to 10 species that were collected along hydrological gradients within polygonal mires located on the southern Taymyr Peninsula and the Lena River delta in northern Siberia. Additionally, n-alkane patterns of six of these species (16 samples) were investigated. The aim of the study is to see whether the inter-and intraspecific differences in C / N, isotopic compositions and n-alkanes are indicative of habitat, particularly with respect to water level. Overall, we find high variability in all investigated parameters for two different moisture-related groups of moss species. The C / N ratios range between 11 and 53 (median: 32) and show large variations at the intraspecific level. However, species preferring a dry habitat (xero-mesophilic mosses) show higher C / N ratios than those preferring a wet habitat (meso-hygrophilic mosses). The delta C-13 values range between 37.0 and 22.5% (median D 27.8 %). The delta N-15 values range between 6.6 and C 1.7%(median D 2.2 %). We find differences in delta C-13 and delta N-15 compositions between both habitat types. For some species of the meso-hygrophilic group, we suggest that a relationship between the individ-ual habitat water level and isotopic composition can be inferred as a function of microbial symbiosis. The n-alkane distribution also shows differences primarily between xeromesophilic and meso-hygrophilic mosses, i. e. having a dominance of n-alkanes with long (n-C29, n-C31 /and intermediate (n-C25 /chain lengths, respectively. Overall, our results reveal that C / N ratios, isotopic signals and n-alkanes of studied brown-moss taxa from polygonal wetlands are characteristic of their habitat.
From November 2006 to January 2010, a sediment trap that was cleared monthly was deployed in Lake Challa, a deep stratified freshwater lake on the eastern slope of Mt. Kilimanjaro in southern Kenya. Geochemical data from sediment trap samples were compared with a broad range of limnological and meteorological parameters to characterize the effect of single parameters on productivity and sedimentation processes in the crater basin. During the southern hemisphere summer (November-March), when the water temperature is high and the lake is biologically productive (nondiatom algae), calcite predominated in the sediment trap samples. During the "long rain" season (March-May) a small amount of organic matter and lithogenic material caused by rainfall appeared. This was followed by the cool and windy months of the southern hemisphere winter (June-October) when diatoms were the main component, indicating a diatom bloom initiated by improvement of nutrient availability related to upwelling processes. The sediment trap data support the hypothesis that the light-dark lamination couplets, which are abundant in Lake Challa cores, reflect seasonal delivery to the sediments of diatom-rich particulates during the windy months and diatom-poor material during the wet season. However, interannual and spatial variability in upwelling and productivity patterns, as well as El Nino-Southern Oscillation (ENSO)-related rainfall and drought cycles, exert a strong influence on the magnitude and geochemical composition of particle export to the hypolimnion of Lake Challa.
Recognition of an inferred Miocene marine incursion affecting areas from Colombia through Peru and Bolivia and into Argentina is essential to delineate the South American Seaway. In Bolivia, corresponding strata of inferred marine origin have been assigned to the late Miocene Yecua Formation. We carried out high-resolution delta C-13 and delta O-18 isotopic studies on 135 in situ carbonates from 3 outcrops, combined with detailed sedimentologic, paleontologic, and ichnologic analysis. Four less negative delta C-13 excursion levels were recorded that coincide well with beds containing marine body (barnacle) and trace (Ophiomorpha) fossils. These strata are interbedded with red-green beds containing mudcracks, plant roots, gypsum, and trace fossils of the continental Scoyenia ichnofacies. Our data are significant in that they show for the first time four possible short-lived marine incursions in the Bolivian central Andes during the late Miocene. The result is constrained by a new U-Pb date of 7.17 +/- 0.34 Ma at the top of Yecua strata.
The Tibetan Plateau (TP), including its surrounding mountain ranges, represents the largest store of ice outside the polar regions. It hosts numerous lakes as well as the head waters of major Asian rivers, on which billions of people depend, and it is particularly sensitive to climate change. The moisture transport to the TP is controlled by the Indian and Pacific monsoon and the Westerlies. Understanding the evolution of the interaction of these circulation systems requires studies on climate archives in different spatial and temporal contexts. The objective of this study is to learn more about the interannual variability of precipitation patterns across the TP and how different hydrologic systems react to different climatic factors.
Aragonite shells of the aquatic gastropod Radix, which is widely distributed in the region, may represent suitable archives for inferring hydrologic and climatic signals in particularly high resolution. Therefore, sclerochronological studies of delta O-18 and delta C-13 ratios in Radix shells from seven lakes were conducted, each representing a different hydrologic and climatic setting, on a transect from the Pamirs across the TP.
The shell patterns exhibit an increasing influence of precipitation and a decreasing influence of evaporation on the isotope compositions from west to east. delta O-18 values of shells from lakes on the eastern and central TP (Donggi Cona, Yamdrok Yumco, Tarab Co) mirror monsoon signals, indicated by more negative values and higher variabilities compared to the more western lakes (Karakul, Bangong/Nyak, Manasarovar). In Yadang Co, located on the central southern TP, the monsoon rains did not reach the lake in the sampling year, although it is located in a region which is usually affected by monsoon circulation. The delta O-18 values are used to differentiate the annual hydrological cycle into ice cover period, melt water period, precipitation period and evaporation period. delta C-13 compositions in the shells particularly depend on specific habitats, which vary in biological productivity and in carbon sources. delta O-18 and delta C-13 patterns show a positive covariance in shells originating from large closed basins. The results show that Radix shells mirror general climatic differences between the seven lake regions. These differences reflect both regional and local climate signals in sub-seasonal resolution, without noticeable dependence on the particular lake system.
After a comprehensive geophysical prospecting the Quaternary MA 1/2 tina Maar, located on a line between the two Quaternary scoria cones Komorni could be revealed by a scientific drilling at the German-Czech border in 2007. Further geophysical field investigations led to the discovery of another geological structure about 2.5 km ESE of the small town Neualbenreuth (NE-Bavaria, Germany), inferred to be also a maar structure, being the fourth volcanic feature aligned along the NW-SE trending Tachov fault zone. It is only faintly indicated as a partial circular rim in the digital elevation model. Though not expressed by a clear magnetic anomaly, geoelectric and refraction seismic tomography strongly indicates a bowl-shaped depression filled with low-resistivity and low-velocity material, correlating well with the well-defined negative gravity anomaly of - 2.5 mGal. Below ca. 15 m-thick debris layer, successions of mostly laminated sediments were recovered in a 100 m-long sediment core in 2015. Sections of finely laminated layers, likely varves, rich in organic matter and tree pollen, were recognized in the upper (22-30 m) and lower (70-86 m) part of the core, respectively, interpreted as interglacials, whereas mostly minerogenic laminated deposits, poor in organic matter, and (almost) barren of tree pollen are interpreted as clastic glacial deposits. According to a preliminary age model based on magnetostratigraphy, palynology, radiocarbon dating, and cyclostratigraphy, the recovered sediments span the time window from about 85 ka back to about 270 ka, covering marine isotope stages 5-8. Sedimentation rates are in the range of 10 cm ka(-1) in interglacials and up to 100 cm ka(-1) in glacial phases. The stratigraphic record resembles the one from MA 1/2 tina Maar, with its eruption date being derived from a nearby tephra deposit at 288 +/- 17 ka, thus supporting the age model of the inferred Neualbenreuth Maar.
Fixed nitrogen ( N) is a limiting nutrient for algae in the low- latitude ocean, and its oceanic inventory may have been higher during ice ages, thus helping to lower atmospheric CO2 during those intervals. In organic matter within planktonic foraminifera shells in Caribbean Sea sediments, we found that the N-15/N-14 ratio from the last ice age is higher than that from the current interglacial, indicating a higher nitrate N-15/N-14 ratio in the Caribbean thermocline. This change and other species- specific differences are best explained by less N fixation in the Atlantic during the last ice age. The fixation decrease was most likely a response to a known ice age reduction in ocean N loss, and it would have worked to balance the ocean N budget and to curb ice age- interglacial change in the N inventory.
Concerns about the regional impact of global climate change in a warming scenario have highlighted the gaps in our understanding of the Indian Summer Monsoon (ISM, also referred to as the Indian Ocean summer monsoon) and the absence of long term palaeoclimate data from the central Indian core monsoon zone (CMZ). Here we present the first high resolution, well-dated, multiproxy reconstruction of Holocene palaeoclimate from a 10 m long sediment core raised from the Lonar Lake in central India. We show that while the early Holocene onset of-intensified monsoon in the CMZ is similar to that reported from other ISM records, the Lonar data shows two prolonged droughts (PD, multidecadal to centennial periods of weaker monsoon) between 4.6-3.9 and 2-0.6 cal ka. A comparison of our record with available data from other ISM influenced sites shows that the impact of these PD was observed in varying degrees throughout the ISM realm and coincides with intervals of higher solar irradiance. We demonstrate that (i) the regional warming in the Indo-Pacific Warm Pool (IPWP) plays an important role in causing ISM PD through changes in meridional overturning circulation and position of the anomalous Walker cell; (ii) the long term influence of conditions like El Nino-Southern Oscillation (ENSO) on the ISM began only ca. 2 cal ka BP and is coincident with the warming of the southern IPWP; (iii) the first settlements in central India coincided with the onset of the first PD and agricultural populations flourished between the two PD, highlighting the significance of natural climate variability and PD as major environmental factors affecting human settlements.
The first 1400-year floating varve chronology for north-eastern Germany covering the late Allered to the early Holocene has been established by microscopic varve counts from the Rehwiese palaeolake sediment record. The Laacher See Tephra (LST), at the base of the studied interval, forms the tephrochronological anchor point. The fine laminations were examined using a combination of micro-facies and mu XRF analyses and are typical of calcite varves, which in this case provide mainly a warm season signal. Two varve types with different sub-layer structures have been distinguished: (I) complex varves consisting of up to four seasonal sub-layers formed during the Allered and early Holocene periods, and, (II) simple two sub-layer type varves only occurring during the Younger Dryas. The precision of the chronology has been improved by varve-to-varve comparison of two independently analyzed sediment profiles based on well-defined micro-marker layers. This has enabled both (1) the precise location of single missing varies in one of the sediment profiles, and, (2) the verification of varve interpolation in disturbed varve intervals in the parallel core. Inter-annual and decadal-scale variability in sediment deposition processes were traced by multi-proxy data series including seasonal layer thickness, high-resolution element scans and total organic and inorganic carbon data at a five-varve resolution. These data support the idea of a two-phase Younger Dryas, with the first interval (12,675-12,275 varve years BP) characterised by a still significant but gradually decreasing warm-season calcite precipitation and a second phase (12,275-11,690 varve years BP) with only weak calcite precipitation. Detailed correlation of these two phases with the Meerfelder Maar record based on the LST isochrone and independent varve counts provides clues about regional differences and seasonal aspects of YD climate change along a transect from a location proximal to the North Atlantic in the west to a more continental site in the east
The sediment profile from Lake Goscia(z) over dot in central Poland comprises a continuous, seasonally resolved and exceptionally well-preserved archive of the Younger Dryas (YD) climate variation. This provides a unique opportunity for detailed investigation of lake system responses during periods of rapid climate cooling (YD onset) and warming (YD termination). The new varve record of Lake Goscia(z) over dot presented here spans 1662 years from the late Allerod (AL) to the early Preboreal (PB). Microscopic varve counting provides an independent chronology with a YD duration of 1149+14/-22 years, which confirms previous results of 1140 +/- 40 years. We link stable oxygen isotopes and chironomid-based air temperature reconstructions with the response of various geochemical and varve microfacies proxies especially focusing on the onset and termination of the YD. Cooling at the YD onset lasted similar to 180 years, which is about a century longer than the terminal warming that was completed in similar to 70 years. During the AL/YD transition, environmental proxy data lagged the onset of cooling by similar to 90 years and revealed an increase of lake productivity and internal lake re-suspension as well as slightly higher detrital sediment input. In contrast, rapid warming and environmental changes during the YD/PB transition occurred simultaneously. However, initial changes such as declining diatom deposition and detrital input occurred already a few centuries before the rapid warming at the YD/PB transition. These environmental changes likely reflect a gradual increase in summer air temperatures already during the YD. Our data indicate complex and differing environmental responses to the major climate changes related to the YD, which involve different proxy sensitivities and threshold processes.
High resolution isotopic (delta O-18 and delta C-13) investigations on endogenic carbonates (calcite/aragonite) from Tso Moriri Lake, NW Himalaya show dramatic fluctuations during the late glacial and the early Holocene, and a persistent enrichment trend during the late Holocene. Changes in this lake are largely governed by the [input (meltwater + monsoon precipitation)/evaporationj (WE) ratio, also reflected in changes in the carbonate mineralogy with aragonite being formed during periods of lowest I/E. Using new isotopic data on endogenic carbonates in combination with the available data on geochemistry, mineralogy, and reconstructed mean annual precipitation, we demonstrate that the late glacial and early Holocene carbonate delta O-18 variability resulted from fluctuating Indian summer monsoon (ISM) precipitation in NW Himalaya. This region experienced increasing ISM precipitation between ca. 13.1 and 11.7 cal ka and highest ISM precipitation during the early Holocene (11.2-8.5 cal ka). However, during the late Holocene, evaporation was the dominant control on the carbonate delta O-18. Regional comparison of reconstructed hydrological changes from Tso Moriri Lake with other archives from the Asian summer monsoon and westerlies domain shows that the intensified westerly influence that resulted in higher lake levels (after 8 cal ka) in central Asia was not strongly felt in NW Himalaya. (C) 2015 Elsevier B.V. All rights reserved.
We present the results of biogeochemical and mineralogical analyses on a sediment core that covers the Holocene sedimentation history of the climatically sensitive, closed, saline, and alkaline Lonar Lake in the core monsoon zone in central India. We compare our results of C/N ratios, stable carbon and nitrogen isotopes, grain-size, as well as amino acid derived degradation proxies with climatically sensitive proxies of other records from South Asia and the North Atlantic region. The comparison reveals some more or less contemporaneous climate shifts. At Lonar Lake, a general long term climate transition from wet conditions during the early Holocene to drier conditions during the late Holocene, delineating the insolation curve, can be reconstructed. In addition to the previously identified periods of prolonged drought during 4.6-3.9 and 2.0-0.6 cal ka that have been attributed to temperature changes in the Indo Pacific Warm Pool, several additional phases of shorter term climate alteration superimposed upon the general climate trend can be identified. These correlate with cold phases in the North Atlantic region. The most pronounced climate deteriorations indicated by our data occurred during 62-5.2,4.6-3.9, and 2.0-0.6 cal ka BP. The strong dry phase between 4.6 and 3.9 cal ka BP at Lonar Lake corroborates the hypothesis that severe climate deterioration contributed to the decline of the Indus Civilisation about 3.9 ka BP. (C) 2014 Elsevier B.V. All rights reserved.
The Cheb Basin (CZ) is a shallow Neogene intracontinental basin filled with fluvial and lacustrine sediments that is located in the western part of the Eger Rift. The basin is situated in a seismically active area and is characterized by diffuse degassing of mantle-derived CO2 in mofette fields. The Hartousov mofette field shows a daily CO2 flux of 23-97 tons of CO2 released over an area of 0.35 km(2) and a soil gas concentration of up to 100% CO2. The present study aims to explore the geo-bio interactions provoked by the influence of elevated CO2 concentrations on the geochemistry and microbial community of soils and sediments. To sample the strata, two 3-m cores were recovered. One core stems from the center of the degassing structure, whereas the other core was taken 8 m from the ENE and served as an undisturbed reference site. The sites were compared regarding their geochemical features, microbial abundances, and microbial community structures. The mofette site is characterized by a low pH and high TOC/sulfate contents. Striking differences in the microbial community highlight the substantial impact of elevated CO2 concentrations and their associated side effects on microbial processes. The abundance of microbes did not show a typical decrease with depth, indicating that the uprising CO2-rich fluid provides sufficient substrate for chemolithoautotrophic anaerobic microorganisms. Illumine MiSeq sequencing of the 16S rRNA genes and multivariate statistics reveals that the pH strongly influences microbial composition and explains around 38.7% of the variance at the mofette site and 22.4% of the variance between the mofette site and the undisturbed reference site. Accordingly, acidophilic microorganisms (e.g., OTUs assigned to Acidobacteriaceae and Acidithiobacillus) displayed a much higher relative abundance at the mofette site than at the reference site. The microbial community at the mofette site is characterized by a high relative abundance of methanogens and taxa involved in sulfur cycling. The present study provides intriguing insights into microbial life and geo-bio interactions in an active seismic region dominated by emanating mantle-derived CO2-rich fluids, and thereby builds the basis for further studies, e.g., focusing on the functional repertoire of the communities. However, it remains open if the observed patterns can be generalized for different time-points or sites.
The Hartousov mofette system is a natural CO2 degassing site in the central Cheb Basin (Eger Rift, Central Europe). In early 2016 a 108 m deep core was obtained from this system to investigate the impact of ascending mantle-derived CO2 on indigenous deep microbial communities and their surrounding life habitat. During drilling, a CO2 blow out occurred at a depth of 78.5 meter below surface (mbs) suggesting a CO2 reservoir associated with a deep low-permeable CO2-saturated saline aquifer at the transition from Early Miocene terrestrial to lacustrine sediments. Past microbial communities were investigated by hopanoids and glycerol dialkyl glycerol tetraethers (GDGTs) reflecting the environmental conditions during the time of deposition rather than showing a signal of the current deep biosphere. The composition and distribution of the deep microbial community potentially stimulated by the upward migration of CO2 starting during Mid Pleistocene time was investigated by intact polar lipids (IPLs), quantitative polymerase chain reaction (qPCR), and deoxyribonucleic acid (DNA) analysis. The deep biosphere is characterized by microorganisms that are linked to the distribution and migration of the ascending CO2-saturated groundwater and the availability of organic matter instead of being linked to single lithological units of the investigated rock profile. Our findings revealed high relative abundances of common soil and water bacteria, in particular the facultative, anaerobic and potential iron-oxidizing Acidovorax and other members of the family Comamonadaceae across the whole recovered core. The results also highlighted the frequent detection of the putative sulfate-oxidizing and CO2-fixating genus Sulfuricurvum at certain depths. A set of new IPLs are suggested to be indicative for microorganisms associated to CO2 accumulation in the mofette system.
Northeastern (NE) India experiences extraordinarily pronounced seasonal climate, governed by the Indian summer monsoon (ISM). The vulnerability of this region to floods and droughts calls for detailed and highly resolved paleoclimate reconstructions to assess the recurrence rate and driving factors of ISM changes. We use stable oxygen and carbon isotope ratios (delta O-18 and delta C-13) from stalagmite MAW-6 from Mawmluh Cave to infer climate and environmental conditions in NE India over the last deglaciation (16-6ka). We interpret stalagmite delta O-18 as reflecting ISM strength, whereas delta C-13 appears to be driven by local hydroclimate conditions. Pronounced shifts in ISM strength over the deglaciation are apparent from the delta O-18 record, similarly to other records from monsoonal Asia. The ISM is weaker during the late glacial (LG) period and the Younger Dryas, and stronger during the BOlling-Allerod and Holocene. Local conditions inferred from the delta C-13 record appear to have changed less substantially over time, possibly related to the masking effect of changing precipitation seasonality. Time series analysis of the delta O-18 record reveals more chaotic conditions during the late glacial and higher predictability during the Holocene, likely related to the strengthening of the seasonal recurrence of the ISM with the onset of the Holocene.
In general, a moderate drying trend is observed in mid-latitude arid Central Asia since the Mid-Holocene, attributed to the progressively weakening influence of the mid-latitude Westerlies on regional climate. However, as the spatio-temporal pattern of this development and the underlying climatic mechanisms are yet not fully understood, new high-resolution paleoclimate records from this region are needed. Within this study, a sediment core from Lake Son Kol (Central Kyrgyzstan) was investigated using sedimentological, (bio) geochemical, isotopic, and palynological analyses, aiming at reconstructing regional climate development during the last 6000 years. Biogeochemical data, mainly reflecting summer moisture conditions, indicate predominantly wet conditions until 4950 cal. yr BP, succeeded by a pronounced dry interval between 4950 and 3900 cal. yr BP. In the following, a return to wet conditions and a subsequent moderate drying trend until present times are observed. This is consistent with other regional paleoclimate records and likely reflects the gradual Late Holocene diminishment of the amount of summer moisture provided by the mid-latitude Westerlies. However, climate impact of the Westerlies was apparently not only restricted to the summer season but also significant during winter as indicated by recurrent episodes of enhanced allochthonous input through snowmelt, occurring before 6000 cal. yr BP and at 5100-4350, 3450-2850, and 1900-1500 cal. yr BP. The distinct similar to 1500year periodicity of these episodes of increased winter precipitation in Central Kyrgyzstan resembles similar cyclicities observed in paleoclimate records around the North Atlantic, likely indicating a hemispheric-scale climatic teleconnection and an impact of North Atlantic Oscillation (NAO) variability in Central Asia.
Lake sediments are increasingly explored as reliable paleoflood archives. In addition to established flood proxies including detrital layer thickness, chemical composition, and grain size, we explore stable oxygen and carbon isotope data as paleoflood proxies for lakes in catchments with carbonate bedrock geology. In a case study from Lake Mondsee (Austria), we integrate high-resolution sediment trapping at a proximal and a distal location and stable isotope analyses of varved lake sediments to investigate flood-triggered detrital sediment flux. First, we demonstrate a relation between runoff, detrital sediment flux, and isotope values in the sediment trap record covering the period 2011-2013 CE including 22 events with daily (hourly) peak runoff ranging from 10 (24) m(3) s(-1) to 79 (110) m(3) s(-1). The three- to ten-fold lower flood-triggered detrital sediment deposition in the distal trap is well reflected by attenuated peaks in the stable isotope values of trapped sediments. Next, we show that all nine flood-triggered detrital layers deposited in a sediment record from 1988 to 2013 have elevated isotope values compared with endogenic calcite. In addition, even two runoff events that did not cause the deposition of visible detrital layers are distinguished by higher isotope values. Empirical thresholds in the isotope data allow estimation of magnitudes of the majority of floods, although in some cases flood magnitudes are overestimated because local effects can result in too-high isotope values. Hence we present a proof of concept for stable isotopes as reliable tool for reconstructing flood frequency and, although with some limitations, even for flood magnitudes.
Based on Proxy records from western Black Sea cores, we provide a comprehensive Study of climate change during the last glacial maximum and late-glacial period in the Black Sea region. For the first time we present a record of relative changes in precipitation for NW Anatolia based on variations in the terrigenous supply expressed as detrital carbonate concentration. The good correspondence between reconstructed rainfall intensity in NW Anatolia and past western Mediterranean sea Surface temperatures (SSTs) implies that during the glacial period the precipitation variability was controlled, like today, by Mediterranean cyclonic disturbances. Periods of reduced precipitation correlate well with low SSTs in the Mediterranean related to Heinrich events H1 and H2. Stable oxygen isotopes and lithological and mineralogical data point to a significant modification in the dominant freshwater/sediment source concomitant to the meltwater inflow after 16.4 cal ka BP. This change implies intensification of the northern sediment source and, with other records from the Mediterranean region, consistently suggests a reorganization of the atmospheric circulation pattern affecting the hydrology of the European continent. The early deglacial northward retreat of both atmospheric and oceanic polar fronts was responsible for the warming in the Mediterranean region, leading simultaneously to more humid conditions in central and northern Europe.
The hypersaline crater lake and its catchment on seabird island Isabel (Pacific, off Mexico) was studied to explore the influence of strong seasonal variations in rainfall/evaporation and guano contribution on its limnology. The hypersaline lake water (HSW, 78 %) is up to 2.2-times enriched in inert ions relative to mean seawater. Rainfall during summer dilutes the HSW to form a less saline rainwater body (RWB) above a chemolimnion between 2 and 4 m water depth. The RWB is inhabited first by diatoms and ostracods followed later on by cyanobacteria and ciliates. Evaporation of > 1.5 m depth of lake water over the dry season increases the salinity of the RWB until the water column becomes isohaline at HSW concentrations in the late dry season. Differences in the stable isotope composition of water and primary producers in RWB and HSW reflect this development. Introduction of seabird guano and the decrease of salinity fuel a high primary production in the RWB with higher delta(CDIC)-C-13 and delta(13)Corg of particulate organic matter than in the HSW. The high N supply leads to high delta N-15 NH4 values (+ 39 % in the HSW) as the consequence of ammonia volatilization that is strongest during guano maturation and with evaporative salinity increase from the HSW. Precipitation of carbonate (calcite and aragonite) from the RWB and the HSW is hindered by the high concentration of guano-derived P. This inhibition may be overcome with evaporative supersaturation during particularly dry conditions. Carbonate may also precipitate during particularly wet conditions from the dilute RWB, where the P-concentration is reduced during an active phytoplankton production that raises the pH. Differences in the stable isotope signatures of carbon and oxygen in HSW and RWB (+ 5 % delta(CDIC)-C-13 and -3 % d18OH2O) suggest the processes of carbonate precipitation can be distinguished based on the isotope signature of the carbonates deposited. Changes in the lake system are indicated when lower temperatures and higher rainfall in the 2006 wet season introduced more and less mature guano to the lake. The lower pH was accompanied by lower ammonia volatilization and carbonate precipitation as indicated by an increased concentration of NH4, Ca, Sr and DIC, while delta H-2, delta(NNH4)-N-15, and salinity were lower. According to our results, the observed sediment laminations should reflect the introduction of catchment material (including guano) with runoff, the RWB plankton production, and the carbonate precipitation in relation to its origin and seasonality.
The hydrology of western Central Asia is highly sensitive to climatic perturbations. In order to understand its long-term variability and to infer linkages between precipitation and atmospheric and oceanic systems, we conducted a thorough sedimentary and geochemical study on a composite core retrieved in lake Son Kul (central Kyrgyzstan). A multi-proxy approach was conducted on lake sediments based on grain size analyses, magnetic susceptibility, total organic carbon (TOC), total nitrogen (TN) and carbon and oxygen isotope analyses on bulk and biogenic materials (ostracoda and molluscs shells) at a resolution equivalent to ca 40 years, aiming to characterise the sequence of palaeolimnological changes in Son Kul.
As indicated by delta O-18 record of bulk carbonates, mainly consisting of aragonite, the Holocene hydrological balance was negative during most of time, suggesting an excess of evaporation (E) over precipitation (P). Limnological conditions fluctuated rapidly before 5000 cal yr BP indicating significant changes in regional hydrology and climate. In particular, the long-term negative hydrological balance was impeded by several short stages with marked increase of precipitation, lasting several decades to a few centuries (e.g., 8300-8200, 6900-6700, 6300-6100, 5500-5400, 5300-5200 and 3100 -3000 cal yr BP). Precipitation changes as inferred from 8180 data are also documented by increased minerogenic detritus and higher TOC. We propose that the seasonal pattern of precipitation varied transiently in western Central Asia during the Holocene, although evaporation changes may also account for the rapid changes observed in delta O-18 data. When the annual water balance was less critical (P <= E), the excess of water might be ascribed to increased precipitation during cold seasons mainly because winter precipitation has more negative delta O-18 than its summer equivalent. Conversely, when the annual water balance is negative (P E), the moisture was mainly delivered during the warm season, as between 5000 and 2000 cal yr BP. Our results thus imply that moisture sources could have changed as well during the Holocene. Moisture was delivered as today mainly during summer from the extended Caspian-Aral Basin and eastern Mediterranean, although Arctic and even North Atlantic seas might be important moisture sources when seasonal precipitation was dominated by winter precipitation. We hypothesise that warming Arctic and North Atlantic seas were important for the North Hemisphere circulation during the cold season. (C) 2014 Elsevier Ltd. All rights reserved.
This paper aims to highlight the potential of using elemental and stable isotope analyses of aquatic macrophytes in palaeolimnological studies. Potamogeton pectinatus material was collected from modem plants (n=68) and from late glacial and Holocene-aged sediments from Koucha Lake (northeastern Tibetan Plateau; 34.0 degrees N; 97.2 degrees E; 4540 m a.s.l.). It was analyzed for delta C-13(Potamogeton) (modern: -23 to 0 parts per thousand, fossil: -19 to -4 parts per thousand) and delta N-15(Potamogeton) (modern: -11.0 to +13.8 parts per thousand, fossil: -9.5 to +6.7 parts per thousand) in addition to elemental carbon and nitrogen (modem C/N-Potamogeton: 7 to 29; fossil: 13 to 68) and sulfur (fossil: 188-899 mu mol/g dry weight). Fossil data were interpreted in terms of palaeo-nutrient availability and palaeo-productivity based on the modem relationships between various proxies and certain environmental data. Productivity of Potamogeton pectinatus mats at Koucha Lake as indicated by palaeo-epsilon(Potamogeton-TIC) (i.e. the enrichment of delta C-13(Potamogeton) relative to the delta(CTIC)-C-13) was reduced during periods of high conductivity, especially between 10.3 and 7.4 cal kyr BP. Potamogeton pectinatus material from these periods was also characterized by high S-Potamogeton indicating high sulfide concentrations and anoxic conditions within the sediments. However, C/N- Potamogeton ratios and delta N-15(Potamogeton) from the lower core section were found to have been altered by decompositional processes. A pronounced shift in the aquatic productivity of Lake Koucha occurred at similar to 7.4 cal kyr BP when the hydrological conditions shifted towards an open lake system and water depth increased. At this time a strong increase in productivity led to a strong decrease in the water HCO3- concentration as inferred from the application of a epsilon-(Potamogeton-TIC)-InHCO3- transfer function. A comparison of reconstructed productivity changes from Koucha Lake with further environmental proxies suggests that primary productivity changes are probably a function of internal lake dynamics and were only indirectly triggered by climate change.