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The P and S wave velocity structure of the D" layer beneath the southwestern Pacific was investigated by using short-period data from 12 deep events in the Tonga-Fiji region recorded by the J-Array and the Hi-net (two large- aperture seismic arrays) in Japan. Reflected wave beam forming (RWB) and a migration method were used to extract weak signals originating from heterogeneities in the lowermost mantle. In order to acquire high resolution a double-array method was applied to the data. The results of the RWB method indicate that seismic energy is reflected at discontinuities near the depths of 2520 and 2650 km, which have a negative P wave velocity contrast of 1% at the most. In addition, there is a positive seismic discontinuity at a depth of 2800 km. In the case of the S wave, reflected energy is produced almost at the same depth (2550 km depth). An apparent depth shift (50 km) of the discontinuity at the depth of 2850 km may indicate that the S wave velocity reduction in the lowermost mantle is similar to2-3 times stronger than that of P. A two-dimensional cross section, constructed with the RWB method, suggests that the observed discontinuities can be characterized as intermittent lateral heterogeneities whose lateral extent is a few hundred kilometers. The migration shows weak evidence of scattering objects which belong to the seismic discontinuities detected by the RWB method. These anomalous structures may represent a part of hot plume generated beneath the southwestern Pacific in the lowermost mantle
To address one of the central questions of plate tectonics-How do large transform systems work and what are their typical features?-seismic investigations across the Dead Sea Transform (DST), the boundary between the African and Arabian plates in the Middle East, were conducted for the first time. A major component of these investigations was a combined reflection/ refraction survey across the territories of Palestine, Israel and Jordan. The main results of this study are: (1) The seismic basement is offset by 3-5 km under the DST, (2) The DST cuts through the entire crust, broadening in the lower crust, (3) Strong lower crustal reflectors are imaged only on one side of the DST, (4) The seismic velocity sections show a steady increase in the depth of the crust-mantle transition (Moho) from 26 km at the Mediterranean to 39 km under the Jordan highlands, with only a small but visible, asymmetric topography of the Moho under the DST. These observations can be linked to the left-lateral movement of 105 km of the two plates in the last 17 Myr, accompanied by strong deformation within a narrow zone cutting through the entire crust. Comparing the DST and the San Andreas Fault (SAF) system, a strong asymmetry in subhorizontal lower crustal reflectors and a deep reaching deformation zone both occur around the DST and the SAF. The fact that such lower crustal reflectors and deep deformation zones are observed in such different transform systems suggests that these structures are possibly fundamental features of large transform plate boundaries
The Arabidopsis tandem-pore K+ (TPK) channels displaying four transmembrane domains and two pore regions share structural homologies with their animal counterparts of the KCNK family. In contrast to the Shaker-like Arabidopsis channels (six transmembrane domains/one pore region), the functional properties and the biological role of plant TPK channels have not been elucidated yet. Here, we show that AtTPK4 (KCO4) localizes to the plasma membrane and is predominantly expressed in pollen. AtTPK4 (KCO4) resembles the electrical properties of a voltage-independent K+ channel after expression in Xenopus oocytes and yeast. Hyperpolarizing as well as depolarizing membrane voltages elicited instantaneous K+ currents, which were blocked by extracellular calcium and cytoplasmic protons. Functional complementation assays using a K+ transport-deficient yeast confirmed the biophysical and pharmacological properties of the AtTPK4 channel. The features of AtTPK4 point toward a role in potassium homeostasis and membrane voltage control of the growing pollen tube. Thus, AtTPK4 represents a member of plant tandem-pore-K+ channels, resembling the characteristics of its animal counterparts as well as plant-specific features with respect to modulation of channel activity by acidosis and calcium
The remaining carbon stocks in wet tropical forests are currently at risk because of anthropogenic deforestation, but also because of the possibility of release driven by climate change. To identify the relative roles of CO2 increase, changing temperature and rainfall, and deforestation in the future, and the magnitude of their impact on atmospheric CO2 concentrations, we have applied a dynamic global vegetation model, using multiple scenarios of tropical deforestation (extrapolated from two estimates of current rates) and multiple scenarios of changing climate (derived from four independent offline general circulation model simulations). Results show that deforestation will probably produce large losses of carbon, despite the uncertainty about the deforestation rates. Some climate models produce additional large fluxes due to increased drought stress caused by rising temperature and decreasing rainfall. One climate model, however, produces an additional carbon sink. Taken together, our estimates of additional carbon emissions during the twenty-first century, for all climate and deforestation scenarios, range from 101 to 367 Gt C, resulting in CO2 concentration increases above background values between 29 and 129 p.p.m. An evaluation of the method indicates that better estimates of tropical carbon sources and sinks require improved assessments of current and future deforestation, and more consistent precipitation scenarios from climate models. Notwithstanding the uncertainties, continued tropical deforestation will most certainly play a very large role in the build-up of future greenhouse gas concentrations
The ethyl acetate extract of the stem bark of Erythrina abyssinica showed anti-plasmodial activity against the chloroquine-sensitive (D6) and chloroquine-resistant (W2) strains of Plasmodium falciparum with IC50 values of 7.9 +/- 1.1 and 5.3 +/- 0.7 mug/ml, respectively. From this extract, a new chalcone, 2,3,4,4'-tetrahydroxy-5- prenylchalcone (trivial name 5-prenylbutein) and a new flavanone, 4',7-dihydroxy-3'-methoxy-5'- prenylflavanone (trivial name, 5-deoxyabyssinin II) along with known flavonoids have been isolated as the anti- plasmodial principles. The structures were determined on the basis of spectroscopic evidence. (C) 2004 Elsevier Ltd. All rights reserved
Nordau, Max
(2004)
We study the effects of mutual and external chaotic phase synchronization in ensembles of bursting oscillators. These oscillators (used for modeling neuronal dynamics) are essentially multiple time scale systems. We show that a transition to mutual phase synchronization takes place on the bursting time scale of globally coupled oscillators, while on the spiking time scale, they behave asynchronously. We also demonstrate the effect of the onset of external chaotic phase synchronization of the bursting behavior in the studied ensemble by a periodic driving applied to one arbitrarily taken neuron. We also propose an explanation of the mechanism behind this effect. We infer that the demonstrated phenomenon can be used efficiently for controlling bursting activity in neural ensembles
We study phase synchronization effects of chaotic oscillators with a type-I intermittency behavior. The external and mutual locking of the average length of the laminar stage for coupled discrete and continuous in time systems is shown and the mechanism of this synchronization is explained. We demonstrate that this phenomenon can be described by using results of the parametric resonance theory and that this correspondence enables one to predict and derive all zones of synchronization
Zimzum
(2004)
We derive a slip rate for a thrust at the central Qilian Shan mountain front by combining structural investigations, satellite imagery, topographic profiling, luminescence dating, and Be-10 exposure dating. The seismically active Zhangye thrust transects late Pleistocene alluvial fan deposits and forms a prominent north facing scarp. The fault consists of two segments that differ in orientation, scarp height, and age. A series of loess-covered terraces records the uplift history of the western thrust segment. Loess accumulation on all terraces started at 8.5 +/- 1.5 kyr and postdates terrace formation. Gravels from the highest terrace yielded a Be-10 exposure age of 90 +/- 11 kyr, which dates the onset of faulting. With a displacement of 55-60 m derived from fault scarp profiles, this yields a vertical slip rate of 0.64 +/- 0.08 mm yr(-1). Along the eastern thrust segment, three Be-10 ages from the uplifted alluvial fan constrain that faulting started at similar to31 +/- 5 kyr. Together with a displacement of 25-30 m this leads to a vertical faulting rate of 0.88 +/- 0.16 mm yr(-1). A dip estimate of 40degrees to 60degrees for the fault plane combined with lower and upper limits of similar to0.6 and similar to0.9 mm yr(-1) for the vertical slip rate gives minimum and maximum horizontal shortening rates of 0.4 and 1.1 mm yr(-1) across the Zhangye thrust. Our results are consistent with geologic and GPS constraints, which suggest that NNE directed shortening across the northeastern Tibetan Plateau is distributed on several active faults with a total shortening rate of 4 to 10 mm yr(-1)
[1] The development of topography within and erosional removal of material from an orogen exerts a primary control on its structure. We develop a model that describes the temporal development of a frontally accreting, critically growing Coulomb wedge whose topography is largely limited by bedrock fluvial incision. We present general results for arbitrary initial critical wedge geometries and investigate the temporal development of a critical wedge with no initial topography. Increasing rock erodibility and/or precipitation, decreasing mass flux accreting to the wedge front, increasing wedge sole-out depth, decreasing wedge and basal decollement overpressure, and increasing basal decollement friction lead to narrow wedges. Large power law exponent values cause the wedge geometry to quickly reach a condition in which all material accreted to the front of the wedge is removed by erosion. We apply our model to the Aconcagua fold-and-thrust belt in the central Andes of Argentina where wedge development over time is well constrained. We solve for the erosional coefficient K that is required to recreate the field-constrained wedge growth history, and these values are within the range of independently determined values in analogous rock types. Using qualitative observations of rock erodibilities within the wedge, we speculate that power law exponents of 1/3 less than or equal to m less than or equal to 0.4 and 2/3 less than or equal to n less than or equal to 1 characterize the erosional growth of the Aconcagua fold-and-thrust belt. This general model may be used to understand the development of mountain belts where orogenic wedges grow as they deform at their Coulomb failure limit
[1] Orogenic structure appears to be partially controlled by the addition to and removal of material from the mountain belt by tectonic accretion and geomorphic erosion, respectively. We developed a coupled erosion-deformation model for orogenic wedges that are in erosional steady state and deform at their Coulomb failure limit. Erosional steady state is reached when all material introduced into the wedge is removed by erosion that is limited by the rate at which rivers erode through bedrock. We found that the ultimate form of a wedge is controlled by the wedge mechanical properties, sole-out depth of the basal decollement, erosional exponents, basin geometry, and the ratio of the added material flux to the erosional constant. As this latter ratio is increased, wedge width and surface slopes increase. We applied these models to the Taiwan and Himalayan orogenic wedges and found that despite a higher flux of material entering the former, the inferred ratio was larger for the latter. Calculated values for the erodibility of each wedge showed at least an order of magnitude lower value for the Himalaya relative to Taiwan. These values are consistent with the lower precipitation regime in the Himalaya relative to Taiwan and the exposure of crystalline rocks within the Himalayan orogenic wedge. Independently determined rock erodibility estimates are consistent with the accretionary wedge sediments and metasediments and the crystalline and high-grade metamorphic rocks exposed within Taiwan and the Himalaya, respectively. Therefore differences in rock type and climate apparently lead to key differences in the erosion and hence orogenic structure of these two mountain belts
A fault scaling law suggests that, over eight orders of magnitude, fault length L is linearly related to maximum displacement D. Individual faults may therefore retain a constant ratio of D/L as they grow. If erosion is minor compared with tectonic uplift, the length and along-strike relief of young mountain ranges should thus reflect fault growth. Topographic profiles along the crests of mountain ranges in the actively deforming foreland of north-east Tibet exhibit a characteristic shape with maximum height near their centre and decreasing elevation toward the tips. We interpret the along-strike relief of these ranges to reflect the slip distribution on high-angle reverse faults. A geometric model illustrates that the lateral propagation rate of such mountain ranges may be deciphered if their length- to-height ratio has remained constant. As an application of the model, we reconstruct the growth of the Heli Shan using a long-term uplift rate of similar to1.3 mm yr(-1) derived from Ne-21 and Be-10 exposure dating
We argue that there is a crucial difference between determiner and adverbial quantification. Following Herburger [2000] and von Fintel [1994], we assume that determiner quantifiers quantify over individuals and adverbial quantifiers over eventualities. While it is usually assumed that the semantics of sentences with determiner quantifiers and those with adverbial quantifiers basically come out the same, we will show by way of new data that quantification over events is more restricted than quantification over individuals. This is because eventualities in contrast to individuals have to be located in time which is done using contextual information according to a pragmatic resolution strategy. If the contextual information and the tense information given in the respective sentence contradict each other, the sentence is uninterpretable. We conclude that this is the reason why in these cases adverbial quantification, i.e. quantification over eventualities, is impossible whereas quantification over individuals is fine.
Being one of the fundamental phenomena in nonlinear science, synchronization of oscillations has permanently remained an object of intensive research. Development of many asymptotic methods and numerical simulations has allowed an understanding and explanation of various phenomena of self-synchronization. But even in the classical case of coupled van der Pol oscillators a full description of all possible dynamical regimes, their mutual transitions and characteristics is still lacking. We present here a study of the phenomenon of mutual synchronization for two non-scalar- coupled non-identical limit-cycle oscillators and analyze phase, frequency and amplitude characteristics of synchronization regimes. A series of bifurcation diagrams that we obtain exhibit various regions of qualitatively different behavior. Among them we find mono-, bi- and multistability regions, beating and "oscillation death" ones; also a region, where one of the oscillators dominates the other one is observed. The frequency characteristics that we obtain reveal three qualitatively different types of synchronization: (i) on the mean frequency (the in-phase synchronization), (ii) with a shift from the mean frequency caused by a conservative coupling term (the anti-phase synchronization), and (iii) on the frequency of one of the oscillators (when one oscillator dominates the other). (C) 2003 Elsevier B.V. All rights reserved
In addition to salinity and temperature, nutrient concentrations in surface waters are known to have a significant impact on distribution of carbonate-producing biota, but have never been quantitatively evaluated against different temperatures along a latitudinal transect. The western coast of the Gulf of California, Mexico, presents a natural laboratory for investigating the influence of oceanographic parameters such as salinity, temperature, and chlorophyll a, a proxy for nutrients, on the composition of a range of modern heterozoan and photozoan carbonate environments along a north-south latitudinal gradient spanning the entire warm-temperate realm (29degreesN-23degreesN). Chlorophyll a, measured in situ at half-hour resolution, is highly variable throughout the year due to short-term upwelling, and increases significantly from the southern to northern Gulf of California. Salinity, in contrast, fluctuates little and remains at an average of 35%. From south to north, carbonate production ranges from oligotrophic- mesotrophic, coral reefdominated shallow-water areas (minimum temperature 18.6 degreesC) through mesotrophic-eutrophic, red algal-dominated, inner-shelf carbonate production in the central gulf (minimum temperature 16 degreesC), and to molluscan-bryozoan, eutrophic inner- to outer-shelf environments (minimum temperature 13.7 degreesC). The Gulf of California data, supplemented with oceanographic and compositional information from a database compiled from a spectrum of modern carbonate systems worldwide, demonstrates the significance of nutrient control in the formation of heterozoan, photozoan, and transitional heterozoan-photozoan carbonate systems and serves as a basis for more accurately interpreting fossil carbonates
delta(18)O(benthic), values from Leg 194 Ocean Drilling Program Sites 1192 and 1195, (drilled on the Marion Plateau) were combined with deep-sea values to reconstruct the magnitude range of the late middle Miocene sea-level fall (13.6-11.4 Ma). In parallel, an estimate for the late middle Miocene sea-level fall was calculated from the stratigraphic relationship identified during Leg 194 and the structural relief of carbonate platforms that form the Marion Plateau. Corrections for thermal subsidence induced by Late Cretaceous rifting, flexural sediment loading, and sediment compaction were taken into account. The response of the lithosphere to sediment loading was considered for a range of effective elastic thicknesses (10 < T-e < 40 km). By overlapping the sea-level range of both the deep-sea isotopes and the results from the backstripping analysis, we demonstrate that the amplitude of the late middle Miocene sea-level fall was 45-68 m (56.5 +/- 11.5 m). Including an estimate for sea-level variation using the delta(18)O(benthic) results from the subtropical Marion Plateau, the range of sea-level fall is tightly constrained between 45 and 55 in (50.0 +/- 5.0 m). This result is the first precise quantitative estimate for the amplitude of the late middle Miocene eustatic fall that sidesteps the errors inherent in using benthic foraminifera assemblages to predict paleo-water depth. The estimate also includes an error analysis for the flexural response of the lithosphere to both water and sediment loads. Our result implies that the extent of ice buildup in the Miocene was larger than previously estimated, and conversely that the amount of cooling associated with this event was less important
It is commonly adopted that X-rays from O stars are produced deep inside the stellar wind, and transported outwards through the bulk of the expanding matter which attenuates the radiation and affects the shape of emission line profiles. The ability of the X-ray observatories Chandra and XMM-Newton to resolve these lines spectroscopically provided a stringent test for the theory of the X-ray production. It turned out that none of the existing models was able to fit the observations consistently. The possible caveat of these models was the underlying assumption of a smooth stellar wind. Motivated by the evidence that the stellar winds are in fact structured, we present a 2-D numerical model of a stochastic, inhomogeneous wind. Small parcels of hot, X-ray emitting gas are permeated by cool, absorbing wind material which is compressed into thin shell fragments. Wind fragmentation alters the radiative transfer drastically, compared to homogeneous models of the same mass-loss rate. X-rays produced deep inside the wind, which would be totally absorbed in a homogeneous flow, can effectively escape from a fragmented wind. The wind absorption becomes wavelength independent if the individual fragments are optically thick. The X-ray line profiles are flat-topped in the blue part and decline steeply in the red part for the winds with a short acceleration zone. For the winds where the acceleration extends over significant distances, the lines can appear nearly symmetric and only slightly blueshifted, in contrast to the skewed, triangular line profiles typically obtained from homogeneous wind models of high optical depth. We show that profiles from a fragmented wind model can reproduce the observed line profiles from zeta Orionis. The present numerical modeling confirms the results from a previous study, where we derived analytical formulae from a statistical treatment
The information content of data on rotationally periodic recurrent discrete absorption components (DACs) in hot star wind emission lines is discussed. The data comprise optical depths tau(w,phi) as a function of dimensionless Doppler velocity w=(Deltalambda/lambda(0))(c/v(infinity)) and of time expressed in terms of stellar rotation angle phi. This is used to study the spatial distributions of density, radial and rotational velocities, and ionisation structures of the corotating wind streams to which recurrent DACs are conventionally attributed. The simplifying assumptions made to reduce the degrees of freedom in such structure distribution functions to match those in the DAC data are discussed and the problem then posed in terms of a bivariate relationship between tau(w, phi) and the radial velocity v(r)(r), transverse rotation rate Omega(r) and density rho(r, phi) structures of the streams. The discussion applies to cases where: the streams are equatorial; the system is seen edge on; the ionisation structure is approximated as uniform; the radial and transverse velocities are taken to be functions only of radial distance but the stream density is allowed to vary with azimuth. The last kinematic assumption essentially ignores the dynamical feedback of density on velocity and the relationship of this to fully dynamical models is discussed. The case of narrow streams is first considered, noting the result of Hamann et al. (2001) that the apparent acceleration of a narrow stream DAC is higher than the acceleration of the matter itself, so that the apparent slow acceleration of DACs cannot be attributed to the slowness of stellar rotation. Thus DACs either involve matter which accelerates slower than the general wind flow, or they are formed by structures which are not advected with the matter flow but propagate upstream (such as Abbott waves). It is then shown how, in the kinematic model approximation, the radial speed of the absorbing matter can be found by inversion of the apparent acceleration of the narrow DAC, for a given rotation law. The case of broad streams is more complex but also more informative. The observed tau(w,phi) is governed not only by v(r)(r) and Omega(r) of the absorbing stream matter but also by the density profile across the stream, determined by the azimuthal (phi(0)) distribution function F- 0(phi(0)) of mass loss rate around the stellar equator. When F-0(phi(0)) is fairly wide in phi(0), the acceleration of the DAC peak tau(w, phi) in w is generally slow compared with that of a narrow stream DAC and the information on v(r)(r), Omega(r) and F-0(phi(0)) is convoluted in the data tau(w, phi). We show that it is possible, in this kinematic model, to recover by inversion, complete information on all three distribution functions v(r)(r), Omega(r) and F- 0(phi(0)) from data on tau(w, phi) of sufficiently high precision and resolution since v(r)(r) and Omega(r) occur in combination rather than independently in the equations. This is demonstrated for simulated data, including noise effects, and is discussed in relation to real data and to fully hydrodynamic models
K-Ar ages of 37 samples collected from the Bicol peninsula, the Luzon island, Philippines, were determined by the unspiked sensitivity method in order to constrain the timing of initiation of subduction along the Philippine Trench. The measured K-Ar ages range from 0 to 7 Ma with two old outliers of 27 and 43 Ma. Together with K-Ar ages previously reported on volcanics in Leyte and eastern Mindanao, subduction volcanism has likely propagated from north to south: similar to 6.6 Ma in Bicol and similar to 3.5 Ma in Leyte and its vicinity. The temporal and spatial distribution suggests that the subduction volcanism started earlier in the north than in the south. This is consistent with the southern propagation of subduction along the Philippine Trench from similar to 8 Ma. (C) 2003 Elsevier Ltd. All rights reserved
A recent K-Ar study elucidated that eruptive style in the eastern Izu peninsula changed from polygenetic to monogenetic volcano at 0.3-0.2 Ma. To narrow down the time of change, we determined 10 K-Ar ages on Togasayama Andesite of Amagi volcano, the youngest polygenetic volcano in the area, and Togasayama Monogenetic Volcano, one of the oldest monogenetic volcanoes in the area, which overlies a part of the Togasayama Andesite. Dating results showed that the Togasayama Andesite effused at least from 0.34 to 0.20 Ma, whereas the Togasayama Monogenetic Volcano erupted at 0.26- 0.29 Ma, suggesting that the northern part of the Togasayama Andesite effused after the eruption of the Togasayama Monogenetic Volcano. Considering previous data, it is therefore inferred that change of eruptive style in the eastern Izu area occurred during the period 0.29-0.20 Ma, with considerable overlap of both polygenetic and monogenetic volcanism
Along the Southern Himalayan Front (SHF), areas with concentrated precipitation coincide with rapid exhumation, as indicated by young mineral cooling ages. Twenty new, young ( < 1-5 Ma) apatite fission track (AFT) ages have been obtained from the Himalayan Crystalline Core along the Sutlej Valley, NW India. The AFT ages correlate with elevation, but show no spatial relationship to tectonic structures, such as the Main Central Thrust or the Southern Tibetan Fault System. Monsoonal precipitation in this region exerts a strong influence on erosional surface processes. Fluvial erosional unloading along the SHF is focused on high mountainous areas, where the orographic barrier forces out > 80% of the annual precipitation. AFT cooling ages reveal a coincidence between rapid erosion and exhumation that is focused in a similar to 50-70-km-wide sector of the Himalaya, rather than encompassing the entire orogen. Assuming simplified constant exhumation rates, the rocks of two age vs. elevation transects were exhumed at similar to 1.4 +/- 0.2 and similar to 1.1 +/- 0.4 mm/a with an average cooling rate of similar to 40-50degreesC/Ma during Pliocene-Quarternary time. Following other recently published hypotheses regarding the relation between tectonics and climate in the Himalaya, we suggest that this concentrated loss of material was accommodated by motion along a back-stepping thrust to the south and a normal fault zone to the north as part of an extruding wedge. Climatically controlled erosional processes focus on this wedge and suggest that climatically controlled surface processes determine tectonic deformation in the internal part of the Himalaya. (C) 2004 Elsevier B.V. All rights reserved
Ferroelectric polyamide 11 films were prepared by melt-quenching, cold-drawing and electrical poling. Their ferroelectricity was studied by means of dielectric-hysteresis measurements. A remnant polarisation of up to 35 mC/m(2) and a coercive field of 75 MV/m were obtained. The piezoelectric d(33) coefficient and the pyroelectric coefficient of the films are reduced by annealing just below the melting region, but remain at about 3 pC/N and 8 muC/(m(2)K), respectively, during further heat treatment. Differential scanning calorimetry (DSC), dielectric relaxation spectroscopy (DRS) and thermally stimulated depolarisation (TSD) were applied for investigating the conformational changes induced by melt-quenching, cold-drawing and annealing. The results indicate that the cold-drawn film mainly consists of a rigid amorphous phase which exhibits considerably lower conductivity, no glass transition and consequently no dielectric a relaxation. Instead, an a, relaxation is found, which is related to chain motions in regions of the rigid amorphous phase where the amide-group dipoles are not perfectly ordered. Annealing removes imperfectly ordered structures, but does not affect the ferroelectric polarisation. Therefore, it may be concluded that essentially the a, relaxation causes the thermally non-stable part of the piezo- and pyroelectricity in polyamide 11
Organic materials with non-centrosymmetric chromophores are known to be susceptible to a number of photochemical processes, including reversible isomerization reactions as well as irreversible photo-oxidation or photo- reduction reactions. Reversible isomerization is the basis for a variety of applications, such as photo-induced poling, optical data storage and optical grating formation. The irreversible processes that involve the destruction of the chromophores have been found useful for the fabrication of optical waveguides, but they also limit the life times of polymeric photonic devices. In this paper, it is demonstrated that dielectric measurements allow for an in-depth investigation of non-reversible chromophore degradation processes in a typical side-chain polymer. The time- and temperature-dependent dielectric function of the polymer at 1 kHz enables us to follow the chromophore-degradation kinetics and to monitor the bleaching depth as a function of time at room and elevated temperatures
The stability of space charge in electrets such as polytetrafluoroethylene (PTFE), polyethylene terephthalate (PETP) and polypropylene (PP) under ultraviolet irradiation has been investigated using photostimulated discharge spectroscopy. While only weak discharge currents were observed in PTFE coated with semitransparent gold electrodes, up to 15 pA/cm(2) were found in PETP around the UV absorption edge near 310 nm. Space charge profiles obtained with the piezoelectrically generated pressure step method indicate that near-surface charges were almost completely removed. In PP foam, recent findings of a UV-reduced d(33) coefficient were confirmed for exposure times of up to 3.5 h, and a discharge peak at 200 urn could be assigned to the charges stored on the surfaces of the voids. The unique morphology and the (quasi-) piezoelectric properties of cellular PP make it a role model for the future investigation of charge storage in electrets
Ferroelectrets : electrically charged polymer foams as quasi-piezoelectric transducer materials
(2004)
Voided space-charge electrets : piezoelectric transducer materials for electro-acoustic applications
(2004)
In cellular, electromechanically active polymer films, the so-called ferroelectrets, the cell size and shape distributions can be varied through a controlled inflation process. Up to now, high-pressure treatments were usually performed at elevated temperatures. There are, however, significant experimental limitations and complications if the pressure and temperature treatments are performed at the same time. Here, we demonstrate the controlled inflation of cellular polypropylene films by means of sepal-ate pressure and temperature treatments. Separate procedures are Much easier to implement. Excellent electromechanical properties were achieved with Such a two-step inflation process. The technique has significant potential for inflating large-area transducer films for electromechanical and electroacoustical applications
Piezo-, pyro- and ferroelectricity in poly (vinylidene fluoride-hexafluoropropylene) copolymer films
(2004)
Thin films of poly(vinylidene fluoride-hexafluoropropylene) P(VDF-HFP) show significant electroactive properties, such as piezoelectricity, pyroelectricity and electrostriction. Suitable polar P(VDF-HFP) copolymer films can be prepared by melt-pressing or solution-casting. Dipolar orientation causes the macroscopic polarization and thus also the symmetry breaking necessary for electroactive properties. We discuss the polarization build-up in thin, stretched and non-stretched, films of P(VDF-HFP) copolymer with a HFP content of 15%. Poling currents measured in-situ during electric poling are analyzed and the polarization is calculated. Suitable electric poling leads to hysteresis phenomena of the polarization as a function of the electric field as well as to significant polarization during switching experiments. Our results indicate dipolar orientation also in non-stretched P(VDF-HFP) films
When exposed to sufficiently high electric fields, polymer-foam electret materials with closed cells exhibit ferroelectric-like behavior and may therefore be called ferroelectrets. In cellular ferroelectrets, the influence of the cell size and shape distributions on the application-relevant properties is not yet understood. Therefore, controlled inflation experiments were carried out on cellular polypropylene films, and the resulting elastical and electromechanical parameters were determined. The elastic modulus in the thickness direction shows a minimum with a corresponding maximum in the electromechanical transducer coefficient. The resonance frequency shifts as a function of the elastic modulus and the relative density of the inflated cellular films. Therefore, the transducer properties of cellular ferroelectrets can be optimized by means of controlled inflation. (C) 2004 American Institute of Physics
UN-Reform und Menschenrechte
(2004)
Wechselwirkungen zwischen UN-Politik und UN-Forschung in Deutschland
I. Einleitung
II. Zur UN-Forschung in Deutschland
III. Wechselbeziehungen in und zwischen UN-Forschung und UN Politikin Thesen
IV. Ansatzpunkte für künftige Diskussionen
Wechselwirkungen zwischen UN-Politik und UN-Forschung in Deutschland - Diskussionszusammenfassung
Ziviles Personal in Friedenseinsätzen und Wahlbeobachtung - Die Rolle des Zentrums für Internationale Friedenseinsätze (ZIF) // Winrich Kühne in Zusammenarbeit mit Wibke Hansen und Julia Hett
Ziviles Personal in Friedenseinsätzen und Wahlbeobachtung - Die Rolle des Zentrums für Internationale Friedenseinsätze (ZIF) - Diskussionszusammenfassung // Norman Weiß