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The super massive binary system, η Car, experienced periastron passage in the summer of 2014. We observed the star twice around the maximum (forb =0.97, 2014 June 6) and just before the minimum (ϕorb =0.99, 2014 July 28) of its wind-wind colliding (WWC) X-ray emis-sion using the XMM-Newton and NuSTAR observatories, the latter of which is equipped with extremely hard X-ray (>10 keV) focusing mirrors. In both observations, NuSTAR detected the thermal X-ray tail up to 40-50 keV. The hard slope is consistent with an electron tem- perature of ∼6 keV, which is significantly higher than the ionization temperature (kT ∼4 keV) measured from the Fe K emission lines, assuming collisional equilibrium plasma. The spectrum did not show a hard power-law component above this energy range, unlike earlier detections with INTEGRAL and Suzaku. In the second NuSTAR observation, the X-ray flux above 5 keV declined gradually in ∼1 day. This result suggests that the WWC apex was gradually hidden behind the optically thick primary wind around conjunction.