The 10 most recently published documents
EnGeoMAP 2.0
(2017)
Algorithms for a rapid analysis of hyperspectral data are becoming more and more important with planned next generation spaceborne hyperspectral missions such as the Environmental Mapping and Analysis Program (EnMAP) and the Japanese Hyperspectral Imager Suite (HISUI), together with an ever growing pool of hyperspectral airborne data. The here presented EnGeoMAP 2.0 algorithm is an automated system for material characterization from imaging spectroscopy data, which builds on the theoretical framework of the Tetracorder and MICA (Material Identification and Characterization Algorithm) of the United States Geological Survey and of EnGeoMAP 1.0 from 2013. EnGeoMAP 2.0 includes automated absorption feature extraction, spatio-spectral gradient calculation and mineral anomaly detection. The usage of EnGeoMAP 2.0 is demonstrated at the mineral deposit sites of Rodalquilar (SE-Spain) and Haib River (S-Namibia) using HyMAP and simulated EnMAP data. Results from Hyperion data are presented as supplementary information.
Model-Based attribution of high-resolution streamflow trends in two alpine basins of Western Austria
(2017)
Several trend studies have shown that hydrological conditions are changing considerably in the Alpine region. However, the reasons for these changes are only partially understood and trend analyses alone are not able to shed much light. Hydrological modelling is one possible way to identify the trend drivers, i.e., to attribute the detected streamflow trends, given that the model captures all important processes causing the trends. We modelled the hydrological conditions for two alpine catchments in western Austria (a large, mostly lower-altitude catchment with wide valley plains and a nested high-altitude, glaciated headwater catchment) with the distributed, physically-oriented WaSiM-ETH model, which includes a dynamical glacier module. The model was calibrated in a transient mode, i.e., not only on several standard goodness measures and glacier extents, but also in such a way that the simulated streamflow trends fit with the observed ones during the investigation period 1980 to 2007. With this approach, it was possible to separate streamflow components, identify the trends of flow components, and study their relation to trends in atmospheric variables. In addition to trends in annual averages, highly resolved trends for each Julian day were derived, since they proved powerful in an earlier, data-based attribution study. We were able to show that annual and highly resolved trends can be modelled sufficiently well. The results provide a holistic, year-round picture of the drivers of alpine streamflow changes: Higher-altitude catchments are strongly affected by earlier firn melt and snowmelt in spring and increased ice melt throughout the ablation season. Changes in lower-altitude areas are mostly caused by earlier and lower snowmelt volumes. All highly resolved trends in streamflow and its components show an explicit similarity to the local temperature trends. Finally, results indicate that evapotranspiration has been increasing in the lower altitudes during the study period.
A series of new fluorescent dye bearing monomers, including glycomonomers, based on maleamide and maleic esteramide was synthesized. The dye monomers were incorporated by radical copolymerization into thermo-responsive poly(N-vinyl-caprolactam) that displays a lower critical solution temperature (LCST) in aqueous solution. The effects of the local molecular environment on the polymers' luminescence, in particular on the fluorescence intensity and the extent of solvatochromism, were investigated below as well as above the phase transition. By attaching substituents of varying size and polarity in the close vicinity of the fluorophore, and by varying the spacer groups connecting the dyes to the polymer backbone, we explored the underlying structure-property relationships, in order to establish rules for successful sensor designs, e.g., for molecular thermometers. Most importantly, spacer groups of sufficient length separating the fluorophore from the polymer backbone proved to be crucial for obtaining pronounced temperature regulated fluorescence responses.
Die Gründung des Europäischen Stabilitätsmechanismus (ESM) durch einen völkerrechtlichen Vertrag außerhalb der EU-Verträge ist mit mehreren Nachteilen verbunden. So schwächt die Zersplitterung der Rechtsquellen die europäischen Institutionen und deren Legitimation. Auch kann der ESM nicht ohne weiteres auf die Strukturen und das Personal der Europäischen Kommission zurückgreifen. Daher ist eine Integration des ESM in das Gemeinschaftsrecht sinnvoll. Dies setzt eine Rechtsgrundlage voraus. Die Arbeit kommt unter Berücksichtigung der deutschen und französischen Positionen sowie der einschlägigen Rechtsprechung des EuGH zu dem Ergebnis, dass die bestehenden EUVerträge keine Rechtsgrundlage für die Integration des ESM in das Gemeinschaftsrecht enthalten. Vor diesem Hintergrund ist eine Änderung des AEUV gemäß dem ordentlichen Vertragsänderungsverfahren unumgänglich. Damit sollte eine ausdrückliche Rechtsgrundlage für einen gemeinschaftsrechtlichen Stabilitätsmechanismus geschaffen werden. In der Arbeit wird ein konkreter Formulierungsvorschlag für eine derartige Rechtsgrundlage entwickelt, auf deren Basis der Rat mit einer Verordnung einen gemeinschaftsrechtlichen Stabilitätsmechanismus schaffen kann. Außerdem werden die wesentlichen Strukturprinzipien für den gemeinschaftsrechtlichen Stabilitätsmechanismus entwickelt, im Hinblick auf Trägerschaft, Governance, Finanzierung, demokratische Kontrolle und die verfügbaren Finanzhilfeinstrumente.
For the first time a molecularly imprinted polymer (MIP) with direct electron transfer (DET) and bioelectrocatalytic activity of the target protein is presented. Thin films of MIPs for the recognition of a hexameric tyrosine-coordinated heme protein (HTHP) have been prepared by electropolymerization of scopoletin after oriented assembly of HTHP on a self-assembled monolayer (SAM) of mercaptoundecanoic acid (MUA) on gold electrodes. Cavities which should resemble the shape and size of HTHP were formed by template removal. Rebinding of the target protein sums up the recognition by non-covalent interactions between the protein and the MIP with the electrostatic attraction of the protein by the SAM. HTHP bound to the MIP exhibits quasi-reversible DET which is reflected by a pair of well pronounced redox peaks in the cyclic voltammograms (CVs) with a formal potential of −184.4 ± 13.7 mV vs. Ag/AgCl (1 M KCl) at pH 8.0 and it was able to catalyze the cathodic reduction of peroxide. At saturation the MIP films show a 12-fold higher electroactive surface concentration of HTHP than the non-imprinted polymer (NIP).
This study aimed to determine the relative and absolute reliability of ultrasound (US) measurements of the thickness and echogenicity of the plantar fascia (PF) at different measurement stations along its length using a standardized protocol. Twelve healthy subjects (24 feet) were enrolled. The PF was imaged in the longitudinal plane. Subjects were assessed twice to evaluate the intra-rater reliability. A quantitative evaluation of the thickness and echogenicity of the plantar fascia was performed using Image J, a digital image analysis and viewer software. A sonography evaluation of the thickness and echogenicity of the PF showed a high relative reliability with an Intra class correlation coefficient of 0.88 at all measurement stations. However, the measurement stations for both the PF thickness and echogenicity which showed the highest intraclass correlation coefficient (ICCs) did not have the highest absolute reliability. Compared to other measurement stations, measuring the PF thickness at 3 cm distal and the echogenicity at a region of interest 1 cm to 2 cm distal from its insertion at the medial calcaneal tubercle showed the highest absolute reliability with the least systematic bias and random error. Also, the reliability was higher using a mean of three measurements compared to one measurement. To reduce discrepancies in the interpretation of the thickness and echogenicity measurements of the PF, the absolute reliability of the different measurement stations should be considered in clinical practice and research rather than the relative reliability with the ICC.
Ionogels (IGs) based on poly(methyl methacrylate) (PMMA) and the metal-containing ionic liquids (ILs) bis-1-butyl-3-methlimidazolium tetrachloridocuprate(II), tetrachloride cobaltate(II), and tetrachlorido manganate(II) have been synthesized and their mechanical and electrical properties have been correlated with their microstructure. Unlike many previous examples, the current IGs show a decreasing stability in stress-strain experiments on increasing IL fractions. The conductivities of the current IGs are lower than those observed in similar examples in the literature. Both effects are caused by a two-phase structure with micrometer-sized IL-rich domains homogeneously dispersed an IL-deficient continuous PMMA phase. This study demonstrates that the IL-polymer miscibility and the morphology of the IGs are key parameters to control the (macroscopic) properties of IGs.
Planar bis(1,2-dithiooxalato)nickelate(II), [Ni(dto)]2− reacts in aqueous solutions with lanthanide ions (Ln3+) to form pentanuclear, hetero-bimetallic complexes of the general composition [{Ln(H2O)n}2{Ni(dto)2}3]·xH2O. (n = 4 or 5; x = 9–12). The complex [{Ho(H2O)5}2{Ni(dto)2}3]·10H2O, Ho2Ni3, was synthesized and characterized by single crystal X-ray structure analysis and powder diffraction. The Ho2Ni3 complex crystallizes as monoclinic crystals in the space group P21/c. The channels and cavities, appearing in the crystal packing of the complex molecules, are occupied by a varying amount of non-coordinated water molecules.
Materials based on biodegradable polyesters, such as poly(butylene terephthalate) (PBT) or poly(butylene terephthalate-co-poly(alkylene glycol) terephthalate) (PBTAT), have potential application as pro-regenerative scaffolds for bone tissue engineering. Herein, the preparation of films composed of PBT or PBTAT and an engineered spider silk protein, (eADF4(C16)), that displays multiple carboxylic acid moieties capable of binding calcium ions and facilitating their biomineralization with calcium carbonate or calcium phosphate is reported. Human mesenchymal stem cells cultured on films mineralized with calcium phosphate show enhanced levels of alkaline phosphatase activity suggesting that such composites have potential use for bone tissue engineering.
Meteorological extreme events have great potential for damaging railway infrastructure and posing risks to the safety of train passengers. In the future, climate change will presumably have serious implications on meteorological hazards in the Alpine region. Hence, attaining insights on future frequencies of meteorological extremes with relevance for the railway operation in Austria is required in the context of a comprehensive and sustainable natural hazard management plan of the railway operator. In this study, possible impacts of climate change on the frequencies of so-called critical meteorological conditions (CMCs) between the periods 1961-1990 and 2011-2040 are analyzed. Thresholds for such CMCs have been defined by the railway operator and used in its weather monitoring and early warning system. First, the seasonal climate change signals for air temperature and precipitation in Austria are described on the basis of an ensemble of high-resolution Regional Climate Model (RCM) simulations for Europe. Subsequently, the RCM-ensemble was used to investigate changes in the frequency of CMCs. Finally, the sensitivity of results is analyzed with varying threshold values for the CMCs. Results give robust indications for an all-season air temperature rise, but show no clear tendency in average precipitation. The frequency analyses reveal an increase in intense rainfall events and heat waves, whereas heavy snowfall and cold days are likely to decrease. Furthermore, results indicate that frequencies of CMCs are rather sensitive to changes of thresholds. It thus emphasizes the importance to carefully define, validate, andif neededto adapt the thresholds that are used in the weather monitoring and warning system of the railway operator. For this, continuous and standardized documentation of damaging events and near-misses is a pre-requisite.
