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We provide new insights into the prograde evolution of HP/LT metasedimentary rocks on the basis of detailed petrologic examination, element-partitioning analysis, and thermodynamic modelling of well-preserved Fe-Mg-carpholite- and Fe-Mg-chloritoid-bearing rocks from the Afyon Zone (Anatolia). We document continuous and discontinuous compositional (ferromagnesian substitution) zoning of carpholite (overall X-Mg = 0.27-0.73) and chloritoid (overall X-Mg = 0.07-0.30), as well as clear equilibrium and disequilibrium (i.e., reaction-related) textures involving carpholite and chloritoid, which consistently account for the consistent enrichment in Mg of both minerals through time, and the progressive replacement of carpholite by chloritoid. Mg/Fe distribution coefficients calculated between carpholite and chloritoid vary widely within samples (2.2-20.0). Among this range, only values of 7-11 correlate with equilibrium textures, in agreement with data from the literature. Equilibrium phase diagrams for metapelitic compositions are calculated using a newly modified thermodynamic dataset, including most recent data for carpholite, chloritoid, chlorite, and white mica, as well as further refinements for Fe-carpholite, and both chloritoid end-members, as required to reproduce accurately petrologic observations (phase relations, experimental constraints, Mg/Fe partitioning). Modelling reveals that Mg/Fe partitioning between carpholite and chloritoid is greatly sensitive to temperature and calls for a future evaluation of possible use as a thermometer. In addition, calculations show significant effective bulk composition changes during prograde metamorphism due to the fractionation of chloritoid formed at the expense of carpholite. We retrieve P-T conditions for several carpholite and chloritoid growth stages (1) during prograde stages using unfractionated, bulk-rock XRF analyses, and (2) at peak conditions using compositions fractionated for chloritoid. The P-T paths reconstructed for the Kutahya and Afyon areas shed light on contrasting temperature conditions for these areas during prograde and peak stages.
We herein reappraise the pressure-temperature (PT) evolution of the high-pressure and low-temperature (HP-LT) Tavsanli zone (western Turkey) in order to (i) better characterize rock units exhumed along a cooling subduction interface, from birth to steady state and (ii) constrain exhumation and detachment dynamics, as well as mechanical coupling between plates. Based on PT estimates and field observations three oceanic complexes are recognized between the HP-LT continental margin and the obducted ophiolite, with PT estimates ranging from incipient metamorphism to blueschist-fades conditions. PT conditions for the continental unit are reappraised to 24 kbar and similar to 500 degrees C on the basis of pseudosection modelling and Raman spectroscopy on carbonaceous material. A tentative reconstruction of the subduction zone evolution is proposed using available radiometric and palaeogeographic data and recent thermomechanical modelling. Both PT conditions and field observations point out to the slicing of km-sized units at different preferred depths along the subduction interface, thus providing constraints on the dynamics of accretion and underplating. In particular, the comparison of PT estimates for the Tavsanli zone and for other broadly similar fossil subduction settings (i.e., Oman, Corsica, New Caledonia, Franciscan, Schistes Lustres) suggests that units are detached preferentially from the slab at specific depths of 30-40 km (i.e., downdip of the seismogenic zone) and similar to 80 km. We propose that these depths are controlled by major changes in mechanical coupling along the plate interface, whereas exhumation through time would rather be controlled by large-scale geodynamic boundary conditions. (C) 2015 Elsevier B.V. All rights reserved.