Polar substituent effect of the ester group on conformational equilibria of O-mono-substituted cyclohexanesùthe para-substituent effect in cyclohexyl benzoates
- Together with the nonsubstituted reference compound, para-methoxy- and para-nitro cyclohexyl benzoates have been synthesized and their conformational equilibria studied by low temperature NMR spectroscopy and theoretical DFT calculations. The free energy differences ;G° between axial and equatorial conformers were examined with respect to polar substituent influences on the conformational equilibrium of O-mono-substituted cyclohexane.
Verfasserangaben: | Erich KleinpeterORCiDGND, Ute Bölke, Andrea Frank |
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URL: | http://www.sciencedirect.com/science/article/pii/S0040402008013082 |
DOI: | https://doi.org/10.1016/j.tet.2008.07.024 |
Publikationstyp: | Wissenschaftlicher Artikel |
Sprache: | Englisch |
Jahr der Erstveröffentlichung: | 2008 |
Erscheinungsjahr: | 2008 |
Datum der Freischaltung: | 24.03.2017 |
Quelle: | Tetrahedron. - 64 (2008), 42, S. 10014 - 10017 |
Organisationseinheiten: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
Peer Review: | Referiert |