Synthesis of a Co(II)–imidazolate framework from an anionic linker precursor
- A Co(II)–imidazolate-4-amide-5-imidate based MOF, IFP-5, is synthesized by using an imidazolate anion-based novel ionic liquid as a linker precursor under solvothermal conditions. IFP-5 shows significant amounts of gas (N2, CO2, CH4 and H2) uptake capacities. IFP-5 exhibits an independent high spin Co(II) centre and antiferromagnetic coupling.
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| Author details: | Suvendu Sekhar MondalORCiDGND, Asamanjoy Bhunia, Serhiy Demeshko, Alexandra Kelling, Uwe SchildeORCiDGND, Christoph Janiak, Hans-Jürgen HoldtORCiD |
|---|---|
| URN: | urn:nbn:de:kobv:517-opus4-94424 |
| Subtitle (English): | gas-sorption and magnetic properties |
| Publication series (Volume number): | Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe (235) |
| Publication type: | Postprint |
| Language: | English |
| Date of first publication: | 2013/10/25 |
| Publication year: | 2013 |
| Publishing institution: | Universität Potsdam |
| Release date: | 2016/08/11 |
| Tag: | building-blocks; carbon-dioxide capture; exchange; ionic liquids; ionothermal synthesis; ligand; metal-organic frameworks; solvent; surface; zeolitic imidazolate frameworks |
| First page: | 39 |
| Last Page: | 42 |
| Source: | CrystEngComm (2014) Nr. 16, S. 39-42. - DOI: 10.1039/C3CE42040J |
| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
| DDC classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Peer review: | Referiert |
| Publishing method: | Open Access |
| License (German): |  Keine öffentliche Lizenz: Unter Urheberrechtsschutz |
