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Renewable pyridinium ionic liquids from the continuous hydrothermal decarboxylation of furfural-amino acid derived pyridinium zwitterions

  • Fully renewable pyridinium ionic liquids were synthesised via the hydrothermal decarboxylation of pyridinium zwitterions derived from furfural and amino acids in flow. The functionality of the resulting ionic liquid (IL) can be tuned by choice of different amino acids as well as different natural carboxylic acids as the counterions. A representative member of this new class of ionic liquids was successfully used for the synthesis of ionogels and as a solvent for the Heck coupling.

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Author:Sarah Kirchhecker, Steffen Tröger-MüllerORCiD, Sebastian Bake, Markus AntoniettiORCiDGND, Andreas TaubertORCiDGND, Davido Esposito
ISSN:1463-9262 (print)
ISSN:1463-9270 (online)
Parent Title (English):Green chemistry
Publisher:Royal Society of Chemistry
Place of publication:Cambridge
Document Type:Article
Date of first Publication:2015/06/22
Year of Completion:2015
Publishing Institution:Universität Potsdam
Release Date:2015/09/28
First Page:4151
Last Page:4156
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Peer Review:Referiert
Publication Way:Open Access
Licence (English):License LogoCreative Commons - Attribution 3.0 unported
Notes extern:Zweitveröffentlichung in der Schriftenreihe Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe ; 198