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DyeIonogels: proton-responsive ionogels based on a dye-ionic liquid exhibiting reversible color change

  • Transparent, ion-conducting, and flexible ionogels based on the room temperature ionic liquid (IL) 1-butyl-3-methylimidazolium bis(trifluoromethane sulfonyl) imide [Bmim][N(Tf)(2)], the dye-IL (DIL) 1-butyl-3-methylimidazolium methyl orange [Bmim][MO], and poly(methylmethacrylate) (PMMA) are prepared. Upon IL incorporation the thermal stability of the PMMA matrix significantly increases from 220 to 280 degrees C. The ionogels have a relatively high ionic conductivity of 10(-4) S cm(-1) at 373 K. Most importantly, the ionogels exhibit a strong and reversible color change when exposed to aqueous or organic solutions containing protons or hydroxide ions. The resulting material is thus a prototype of soft multifunctional matter featuring ionic conductivity, easy processability, response to changes in the environment, and a strong readout signal, the color change, that could be used in optical data storage or environmental sensing.

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Metadaten
Author:Zai-Lai Xie, Xing Huang, Andreas TaubertORCiDGND
DOI:https://doi.org/10.1002/adfm.201303016
ISSN:1616-301X (print)
ISSN:1616-3028 (online)
Parent Title (English):Advanced functional materials
Publisher:Wiley-VCH
Place of publication:Weinheim
Document Type:Article
Language:English
Year of first Publication:2014
Year of Completion:2014
Release Date:2017/03/27
Volume:24
Issue:19
Pagenumber:7
First Page:2837
Last Page:2843
Funder:Max Planck Institute of Colloids and Interfaces (Colloid Chemistry Department); University of Potsdam
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer Review:Referiert