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Laser-controlled switching of molecular arrays in an dissipative environment

  • The optical switching of molecular ensembles in a dissipative environment is a subject of various fields of chemical physics and physical chemistry. Here we try to switch arrays of molecules from a stable collective ground state to a state in which all molecules have been transferred to another stable higher-energy configuration. In our model switching proceeds through electronically excited intermediates which are coherently coupled to each other through dipolar interactions, and which decay incoherently within a finite lifetime by coupling to a dissipative environment. The model is quite general, but parameters are chosen to roughly resemble the all-trans -> all-cis isomerization of an array of azobenzene molecules on a surface. Using analytical and optimal control pulses and the concept of "laser distillation," we demonstrate that for various aggregates (dimers up to hexamers), controlled and complete switching should be possible.

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Metadaten
Author:Gereon Floss, Tillmann Klamroth, Peter SaalfrankORCiDGND
DOI:https://doi.org/10.1103/PhysRevB.83.104301
ISSN:1098-0121 (print)
Parent Title (English):Physical review : B, Condensed matter and materials physics
Publisher:American Physical Society
Place of publication:College Park
Document Type:Article
Language:English
Year of first Publication:2011
Year of Completion:2011
Release Date:2017/03/26
Volume:83
Issue:10
Pagenumber:9
Funder:Deutsche Forschungsgemeinschaft [SFB 658, C2]
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Physik und Astronomie
Peer Review:Referiert