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Gate effects in a hexagonal zinc-imidazolate-4-amide-5-imidate framework with flexible methoxy substituents and CO2 selectivity
- A new imidazolate-4-amide-5-imidate based MOF, IFP-7, is generated, having flexible methoxy groups, which act as molecular gates for guest molecules. This allows highly selective CO2 sorption over N2 and CH4 gases.
Author details: | Suvendu Sekhar MondalORCiDGND, Asamanjoy Bhunia, Igor A. Baburin, Christian Jäger, Alexandra Kelling, Uwe SchildeORCiDGND, Gotthard Seifert, Christoph Janiak, Hans-Jürgen HoldtORCiD |
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URN: | urn:nbn:de:kobv:517-opus4-94341 |
Publication series (Volume number): | Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe (233) |
Publication type: | Postprint |
Language: | English |
Date of first publication: | 2013/06/28 |
Publication year: | 2013 |
Publishing institution: | Universität Potsdam |
Release date: | 2016/08/09 |
Tag: | adsorption; capacity; carbon-dioxide capture; coordination polymer; flexibility; hydrogen storage; ligand; metal-organic frameworks; mixed-matrix membranes; separation |
First page: | 7599 |
Last Page: | 7601 |
Source: | Chem. Commun. (2013) 49, S. 7599-7601. - DOI: 10.1039/C3CC42156B |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
DDC classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Peer review: | Referiert |
Publishing method: | Open Access |
License (German): | Keine öffentliche Lizenz: Unter Urheberrechtsschutz |