The structural order of some novel ionic polymers; 2. : Models of molecular packing

  • The molecular packing and spatial correlations of two isomeric zwitterionic polymethacrylates and one polyacrylate analog are studied by means of X-ray analysis and conformational calculations. The analysis of the correlation functions and density distribution profiles suggest a double-layered molecular packing which is discussed for the three polymers investigated, with respect to their different chemical structures. Whereas the zwitterionic polymethacrylates studied exhibit liquid-like short-range order, the polyacrylate analog exhibits an ordered double-layered superstructure.

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Metadaten
Author:Vladimir Tsukruk, Nikolay Mischenko, Peter Köberle, André Laschewsky
URN:urn:nbn:de:kobv:517-opus-17256
Series (Serial Number):Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe (paper 096)
Document Type:Postprint
Language:English
Date of Publication (online):2009/02/13
Year of Completion:1992
Publishing Institution:Universität Potsdam
Release Date:2009/02/13
Source:Die Makromolekulare Chemie, 193 (1992) S. 1829-1838, ISSN: 0025-116X, DOI 10.1002/macp.1992.021930804
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Licence (German):License LogoKeine Nutzungslizenz vergeben - es gilt das deutsche Urheberrecht
Notes extern:
The original publication is available at www3.interscience.wiley.com:
Die Makromolekulare Chemie. - 193 (1992) Issue 8, S. 1829-1838
ISSN 0025-116X
DOI 10.1002/macp.1992.021930804