TY - JOUR A1 - Zhang, Su-Yun A1 - Guo, Wen-Bin A1 - Tang, Ying-Ying A1 - Xu, Jin-Qiu A1 - He, Zhang-Zhen T1 - Observation of Spin Relaxation in a Vanadate Chloride with Quasi-One-Dimensional Linear Chain JF - Crystal growth & design : integrating the fields of crystal engineering and crystal growth for the synthesis and applications of new materials N2 - A new cobalt(II) vanadate chloride, Pb2Co(OH)(V2O7)Cl, has been synthesized under mild hydrothermal conditions. It contains quasi-one-dimensional (1D) linear chains built by edge-sharing of (CoO6)-O-II octahedra. The cobalt(II) oxide chains are further interconnected by (V2O7)(4-) dimers into a three-dimensional (3D) anionic framework with Pb2+ and Cl- ions residing in Co4V8 12-member ring tunnels. The intrachain Co center dot center dot center dot Co distance is 3.041 angstrom, while the interchain distances are 8.742 and 9.256 angstrom. Magnetic measurements suggest the ferromagnetic intrachain and the antiferromagnetic interchain interactions with a specific value of J(intra)/J(inter) = 1.7 x 10(3). Zero-field heat capacity demonstrates the magnetic long-range ordering at 5.5 K. Alternating current (AC) magnetic susceptibility under zero external direct current (DC) fields displays two slow magnetic relaxations at low temperatures, giving characteristic relaxations (tau(0)) of 1.2(3) x 10(-12) and 1.9(4) x 10(-10) s with effective energy barriers (Delta(r)) of 76.1(2) and 48.4(5) K. The energy barrier between the spin up and spin-down states can be ascribed to the ferromagnetic spin chain and the Ising-like magnetic anisotropy in Pb2Co(OH)(V2O7)Cl. Y1 - 2019 U6 - https://doi.org/10.1021/acs.cgd.8b01839 SN - 1528-7483 SN - 1528-7505 VL - 19 IS - 4 SP - 2228 EP - 2234 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Hu, Ting-Li A1 - Cheng, Feng A1 - Xu, Zhen A1 - Chen, Zhong-Zheng A1 - Yu, Lei A1 - Ban, Qian A1 - Li, Chun-Lin A1 - Pan, Tao A1 - Zhang, Bao-Wei T1 - Molecular and morphological evidence for a new species of the genus Typhlomys (Rodentia: Platacanthomyidae) JF - Zoological research : ZR = Dongwuxue-yanjiu : jikan / published by Kunming Institute of Zoology, Chinese Academy of Sciences, Zhongguo Kexueyuan Kunming Dongwu Yanjiusuo zhuban, Dongwuxue-yanjiu Bianji Weiyuanhui bianji N2 - In this study, we reassessed the taxonomic position of Typhlomys (Rodentia: Platacanthomyidae) from Huangshan, Anhui, China, based on morphological and molecular evidence. Results suggested that Typhlomys is comprised of up to six species, including four currently recognized species ( Typhlomys cinereus, T. chapensis, T. daloushanensis, and T. nanus), one unconfirmed candidate species, and one new species ( Typhlomys huangshanensis sp. nov.). Morphological analyses further supported the designation of the Huangshan specimens found at mid-elevations in the southern Huangshan Mountains (600 m to 1 200 m a.s.l.) as a new species. KW - Morphology KW - Phylogenetics KW - Species delimitation KW - Taxonomy Y1 - 2021 U6 - https://doi.org/10.24272/j.issn.2095-8137.2020.132 SN - 2095-8137 VL - 42 IS - 1 SP - 100 EP - 107 PB - Yunnan Renmin Chubanshe CY - Kunming ER -