TY - JOUR A1 - Hoehnel, Desirée A1 - Reimold, Wolf Uwe A1 - Altenberger, Uwe A1 - Hofmann, Axel A1 - Mohr-Westheide, Tanja A1 - Oezdemir, Seda A1 - Köberl, Christian T1 - Petrographic and Micro-XRF analysis of multiple archean impact-derived spherule layers in drill core CT3 from the northern Barberton Greenstone Belt (South Africa) JF - Journal of African earth sciences / Geological Society of Africa N2 - The Archean spherule layers (SLs) of the Barberton Greenstone Belt (BGB, South Africa) and Pilbara Craton (Australia) are the only known evidence of early, large impact events on Earth. Spherules in these layers have been, alternatively, interpreted as molten impact ejecta, condensation products from an impact vapor cloud, or ejecta from impact craters melted during atmospheric re-entry. Recently, a new exploration drill core (CT3) from the northern BGB revealed 17 SL intersections. Spherules are densely packed, sand-sized, and variably rounded or deformed. The CT3 SLs are intercalated with black and brown shale, and laminated chert. The determination of the original number of impact events that are represented by these multiple SLs is central to the present paper. A comprehensive study of the sedimentary and petrographic characteristics of these SLs involved the determination of the size, shape and types of individual spherules, as well as their mineralogy. CT3 SLs consist of K-feldspar, phyllosilicate, siderite, dolomite, quartz, Ti- and Fe-oxides, as well as apatite. In addition, small amounts of carbonaceous, presumably organic material are observed in several spherules at 145 and 149 m depth. Only Ni-rich Cr-spinel (up to 11 wt% NiO) crystals, rare zircon grains, and alloys of platinum group elements ± Fe or Ni represent primary phases in these thoroughly altered strata. The 0.3 to 2.6-mm-sized spherules can be classified into four types: 1. Spherules crystallized completely with secondary K-feldspar (subtype 1A) or phyllosilicate (subtype 1B); spherules completely filled with Ti- and Fe-oxides (subtype 1C); spherules containing disordered or radially oriented, fibrous and lath-shaped K-feldspar textures (subtype 1D); or subtype 1B spherules that contain significant Cr-spinel (subtype 1E); 2. zoned compositions with these types 1A and/or 1B minerals (subtype 2A); spherules that contain central or marginal vesicles (subtype 2B); subtype 1B spherules whose rims consist of Ti and Fe-oxides (subtype 2C); 3. deformed spherules (subtype 3A) - of all types; (B) subtype 1B spherules are assimilated into groundmass; (C) open spherules or spherules with collapsed rims; and 4. interconnected spherules of type 1A. A few spherules show botryoidal devitrification textures interpreted to result from rapid cooling/devitrification of former melt droplets. SL 15 at a depth of 145 m is unique in being the only grain-size sorted SL; this bed may have been deposited by fallout through a water column. The SL and their host rocks can be easily distinguished by their significant differences in micro-XRF elemental distribution maps. Depending on which aspects of the SLs are primarily considered (such as similar geochemistry, similar layering, SL occurrences abundant at three different depth intervals), the 17 CT3 SLs can be assigned to three or up to 13 individual impact events. Uncertainty about the actual number of impact events represented remains, however, due to the complex folding deformation observed throughout the drill core. KW - Archean spherule layers KW - Barberton Greenstone Belt KW - Petrography KW - Micro-XRF KW - Record of multiple impacts Y1 - 2017 U6 - https://doi.org/10.1016/j.jafrearsci.2017.11.020 SN - 1464-343X SN - 1879-1956 VL - 138 SP - 264 EP - 288 PB - Elsevier Science CY - Oxford ER - TY - JOUR A1 - Reimold, Wolf Uwe A1 - Fischer, Luise A1 - Müller, Jan A1 - Kenkmann, Thomas A1 - Schmitt, Ralf-Thomas A1 - Altenberger, Uwe A1 - Kowitz, Astrid T1 - Impact-generated pseudotachylitic breccia in drill core BH-5 Hattberg, Siljan impact structure, Sweden JF - GFF N2 - Pseudotachylitic breccia (PTB) in the form of cm-wide melt breccia veinlets locally occurs on the exposed central uplift of the 380Ma Siljan impact structure. The host rock to the PTBs is the so-called Jarna granite of quartz monzonitic to syenodioritic composition. The nearly 603m long BH-5 drill core from Hattberg, near the centre of the Siljan central uplift, contains numerous veins and pods of PTB. In particular, two major zones of 60m combined width contain extensive PTB network breccias (30% actual melt breccia component), with individual melt breccia occurrences up to >1m in length. Core logging and petrographic and geochemical analysis of the core have been performed, and the data are interpreted to suggest the following. (1) The impact event caused low to moderate (at essentially <20GPa) shock deformation in the host rock and in clasts of this lithology within the PTB. (2) Macroscopic deformation of the basement mainly comprises fracturing, with only localised cataclasis. (3) No evidence for shock melting (i.e. compression/decompression melting early in the cratering process) could be observed. (4) Optical and scanning electron microscopy showed that dark PTB contains a definite melt component. (5) Shearing has significantly affected this part of the central uplift, but its effects are limited to very short displacements and likely did not result in extensive melting. (6) A frictional heating component upon melt generation can, however, not be excluded, as many PTB samples contain clasts of a mafic (gabbroic) component, although only in one place along the entire core, a 1.2cm-wide section through such material in direct contact to host rock was observed. Consequently, we suggest that, upon uplift in the central part of the impact structure, considerable melt volumes were generated locally, especially in areas that had been affected by extensive cataclasis and where grain size comminution favoured melt formation. Rapid decompression related to central uplift formation is the preferred process for the generation of the PTB melt breccias. Y1 - 2015 U6 - https://doi.org/10.1080/11035897.2015.1015264 SN - 1103-5897 SN - 2000-0863 VL - 137 IS - 2 SP - 141 EP - 162 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - CHAP A1 - Wannek, Dshamilja L. M. A1 - Reimold, Wolf Uwe A1 - Thirlwall, Matthew A1 - Hansen, Bent T. A1 - Schulz, Toni A1 - Hoffmann, Michael A1 - Zaag, Patrice T. A1 - Hauser, Natalia A1 - Siegert, Susann T1 - Are there two types of vredefort granophyre? T2 - Meteoritics & planetary science : journal of the Meteoritical Society Y1 - 2015 SN - 1086-9379 SN - 1945-5100 VL - 50 PB - Wiley-Blackwell CY - Hoboken ER -