TY - JOUR A1 - Schneider, Sebastian A1 - Bytyqi, Kushtrim A1 - Kohaut, Stephan A1 - Bügel, Patrick A1 - Weinschenk, Benjamin A1 - Marz, Michael A1 - Kimouche, Amina A1 - Fink, Karin A1 - Hoffmann-Vogel, Regina T1 - Molecular self-assembly of DBBA on Au(111) at room temperature JF - Physical chemistry, chemical physics : a journal of European Chemical Societies N2 - We have investigated the self-assembly of the graphene nanoribbon molecular precursor 10,10'-dibromo-9,9'-bianthryl (DBBA) on Au(111) with frequency modulation scanning force microscopy (FM-SFM) at room temperature combined with ab initio calculations. For low molecular coverages, the molecules aggregate along the substrate herringbone reconstruction main directions while remaining mobile. At intermediate coverage, two phases coexist, zigzag stripes of monomer chains and decorated herringbones. For high coverage, the molecules assemble in a dimer-striped phase. The adsorption behaviour of DBBA molecules and their interactions are discussed and compared with the results from ab initio calculations. Y1 - 2022 U6 - https://doi.org/10.1039/d2cp02268k SN - 1463-9076 SN - 1463-9084 VL - 24 IS - 46 SP - 28371 EP - 28380 PB - Royal Society of Chemistry CY - Cambridge ER -