TY - JOUR A1 - Sturzbecher, Dietmar A1 - Freytag, Ronald A1 - Großmann, Heidrun A1 - Ehmke-Pfeifer, I. A1 - Stahnke-Jungheim, D. A1 - Waltz, Christine T1 - Kindliche Wahrnehmung von Interaktion mit Erziehungspersonen (KIWIE) Y1 - 1998 SN - 3-7841-1106-8 ER - TY - JOUR A1 - Sturzbecher, Dietmar A1 - Großmann, Heidrun A1 - Ehmke-Pfeifer, I. A1 - Langner, Winfried A1 - Stahnke-Jungheim, D. A1 - Waltz, Christine T1 - Konflikt als Chance : ein Forschungs- und Interventionsprogramm zur Förderung von sozialer Kompetenz und Patizipation bei fünf- bis achtjährigen Kindern in Kindergarten und Schule Y1 - 1998 SN - 3-7841-1106-8 ER - TY - JOUR A1 - Fandrich, Nick A1 - Falkenhagen, Jana A1 - Weidner, Steffen M. A1 - Pfeifer, Dietmar A1 - Staal, Bastiaan A1 - Thuenemann, Andreas F. A1 - Laschewsky, André T1 - Characterization of new amphiphilic block copolymers of N-vinyl pyrrolidone and vinyl acetate, 1-analysis of copolymer composition, end groups, molar masses and molar mass distributions N2 - New amphiphilic block copolymers consisting of N-vinyl pyrrolidone and vinyl acetate were synthesized via controlled radical polymerization using a reversible addition/fragmentation chain transfer (RAFT)/macromolecular design via the interchange of xanthates (MADIX) system. The synthesis was carried out in 1,4-dioxane as process solvent. In order to get conclusions on the mechanism of the polymerization the molecular structure of formed copolymers was analysed by means of different analytical techniques. C-13 NMR spectroscopy was used for the determination of the monomer ratios. End groups were analysed by means of matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. This technique was also used to determine possible fragmentations of the RAFT end groups. By means of a combination of size exclusion chromatography, C-13 NMR and static light scattering molar mass distributions and absolute molar masses could be analysed. The results clearly show a non-ideal RAFT mechanism. Y1 - 2010 UR - http://www3.interscience.wiley.com/journal/10003495/home U6 - https://doi.org/10.1002/macp.200900466 SN - 1022-1352 ER -