TY - BOOK A1 - Rolfes, Manfred A1 - Weith, Thomas A1 - Aehnelt, Reinhard A1 - Schreiber, Karsten A1 - Schultz, Heiko A1 - Werth, Manfred A1 - Neumann, Uwe A1 - Wilhelm, Jan Lorenz A1 - Jessel, Beate A1 - Herberg, Alfred A1 - Kaether, Johann A1 - Zillmer, Sabine A1 - Wiechmann, Thorsten ED - Rolfes, Manfred ED - Weith, Thomas T1 - Evaluation in der Praxis: : Aktuelle Beispiele aus der Stadt-, Regional- und Umweltentwicklung T3 - Praxis Kultur- und Sozialgeographie | PKS - 33 Y1 - 2005 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-53069 SN - 978-3-937786-50-6 ER - TY - JOUR A1 - Strauch, Peter A1 - Neumann, Mike A1 - Kelling, Alexandra A1 - Schilde, Uwe T1 - Bis(1,2-dithiosquarato)nickelates(II): Synthesis, Structure, EPR and Thermal Behavior JF - Acta chimica Slovenica N2 - 1,2-Dithiosquaratonickelates are available by direct synthesis from metal salts with dipotassium-1,2-dithiosquarate and the appropriate counter cations. The synthesis and characterization, including mass spectrometry, of a series 1,2-dithiosquaratonickelates(II), [Ni(dtsq)(2)](2-), with several "onium" cations is reported and the X-ray structures of two diamagnetic complexes, (HexPh(3)P)(2)[Ni(dtsq)(2)] and (BuPh3P)(2)[Ni(dtsq)(2)] with sterically demanding counter ions are presented. The diamagnetic nickel complexes have been doped as host lattices with traces of Cu(II) to measure EPR for additional structural information. The thermal behavior of this series is studied by thermogravimetry and differential thermal analysis (TG/DTA). The thermolysis in air as well as under nitrogen atmosphere of these complexes results in nickel oxide nano-particles in all cases, which are characterized by X-ray powder diffraction. KW - 1,2-Dithiosquarate,1,2-Dithiosquaratonickelate KW - X-ray structure KW - TG/DTA KW - Nickel oxide KW - EPR spectroscopy Y1 - 2015 SN - 1318-0207 SN - 1580-3155 VL - 62 IS - 2 SP - 288 EP - 296 PB - Drustvo CY - Ljubljana ER - TY - RPRT A1 - Müller, Kai-Uwe A1 - Neumann, Michael A1 - Wrohlich, Katharina T1 - Labor supply under participation and hours constraints BT - An extended structural model for policy evaluations T2 - CEPA Discussion Papers N2 - The paper extends a static discrete-choice labor supply model by adding participation and hours constraints. We identify restrictions by survey information on the eligibility and search activities of individuals as well as actual and desired hours. This provides for a more robust identification of preferences and constraints. Both, preferences and restrictions are allowed to vary by and are related through observed and unobserved characteristics. We distinguish various restrictions mechanisms: labor demand rationing, working hours norms varying across occupations, and insufficient public childcare on the supply side of the market. The effect of these mechanisms is simulated by relaxing different constraints at a time. We apply the empirical frame- work to evaluate an in-work benefit for low-paid parents in the German institutional context. The benefit is supposed to increase work incentives for secondary earners. Based on the structural model we are able to disentangle behavioral reactions into the pure incentive effect and the limiting impact of constraints at the intensive and extensive margin. We find that the in-work benefit for parents substantially increases working hours of mothers of young children, especially when they have a low education. Simulating the effects of restrictions shows their substantial impact on employment of mothers with young children. T3 - CEPA Discussion Papers - 3 KW - labor supply KW - hours restrictions KW - involuntary unemployment KW - gender Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-427656 SN - 2628-653X IS - 3 ER -