TY - JOUR A1 - Chipman, Ariel D. A1 - Ferrier, David E. K. A1 - Brena, Carlo A1 - Qu, Jiaxin A1 - Hughes, Daniel S. T. A1 - Schroeder, Reinhard A1 - Torres-Oliva, Montserrat A1 - Znassi, Nadia A1 - Jiang, Huaiyang A1 - Almeida, Francisca C. A1 - Alonso, Claudio R. A1 - Apostolou, Zivkos A1 - Aqrawi, Peshtewani A1 - Arthur, Wallace A1 - Barna, Jennifer C. J. A1 - Blankenburg, Kerstin P. A1 - Brites, Daniela A1 - Capella-Gutierrez, Salvador A1 - Coyle, Marcus A1 - Dearden, Peter K. A1 - Du Pasquier, Louis A1 - Duncan, Elizabeth J. A1 - Ebert, Dieter A1 - Eibner, Cornelius A1 - Erikson, Galina A1 - Evans, Peter D. A1 - Extavour, Cassandra G. A1 - Francisco, Liezl A1 - Gabaldon, Toni A1 - Gillis, William J. A1 - Goodwin-Horn, Elizabeth A. A1 - Green, Jack E. A1 - Griffiths-Jones, Sam A1 - Grimmelikhuijzen, Cornelis J. P. A1 - Gubbala, Sai A1 - Guigo, Roderic A1 - Han, Yi A1 - Hauser, Frank A1 - Havlak, Paul A1 - Hayden, Luke A1 - Helbing, Sophie A1 - Holder, Michael A1 - Hui, Jerome H. L. A1 - Hunn, Julia P. A1 - Hunnekuhl, Vera S. A1 - Jackson, LaRonda A1 - Javaid, Mehwish A1 - Jhangiani, Shalini N. A1 - Jiggins, Francis M. A1 - Jones, Tamsin E. A1 - Kaiser, Tobias S. A1 - Kalra, Divya A1 - Kenny, Nathan J. A1 - Korchina, Viktoriya A1 - Kovar, Christie L. A1 - Kraus, F. Bernhard A1 - Lapraz, Francois A1 - Lee, Sandra L. A1 - Lv, Jie A1 - Mandapat, Christigale A1 - Manning, Gerard A1 - Mariotti, Marco A1 - Mata, Robert A1 - Mathew, Tittu A1 - Neumann, Tobias A1 - Newsham, Irene A1 - Ngo, Dinh N. A1 - Ninova, Maria A1 - Okwuonu, Geoffrey A1 - Ongeri, Fiona A1 - Palmer, William J. A1 - Patil, Shobha A1 - Patraquim, Pedro A1 - Pham, Christopher A1 - Pu, Ling-Ling A1 - Putman, Nicholas H. A1 - Rabouille, Catherine A1 - Ramos, Olivia Mendivil A1 - Rhodes, Adelaide C. A1 - Robertson, Helen E. A1 - Robertson, Hugh M. A1 - Ronshaugen, Matthew A1 - Rozas, Julio A1 - Saada, Nehad A1 - Sanchez-Gracia, Alejandro A1 - Scherer, Steven E. A1 - Schurko, Andrew M. A1 - Siggens, Kenneth W. A1 - Simmons, DeNard A1 - Stief, Anna A1 - Stolle, Eckart A1 - Telford, Maximilian J. A1 - Tessmar-Raible, Kristin A1 - Thornton, Rebecca A1 - van der Zee, Maurijn A1 - von Haeseler, Arndt A1 - Williams, James M. A1 - Willis, Judith H. A1 - Wu, Yuanqing A1 - Zou, Xiaoyan A1 - Lawson, Daniel A1 - Muzny, Donna M. A1 - Worley, Kim C. A1 - Gibbs, Richard A. A1 - Akam, Michael A1 - Richards, Stephen T1 - The first myriapod genome sequence reveals conservative arthropod gene content and genome organisation in the centipede Strigamia maritima JF - PLoS biology N2 - Myriapods (e. g., centipedes and millipedes) display a simple homonomous body plan relative to other arthropods. All members of the class are terrestrial, but they attained terrestriality independently of insects. Myriapoda is the only arthropod class not represented by a sequenced genome. We present an analysis of the genome of the centipede Strigamia maritima. It retains a compact genome that has undergone less gene loss and shuffling than previously sequenced arthropods, and many orthologues of genes conserved from the bilaterian ancestor that have been lost in insects. Our analysis locates many genes in conserved macro-synteny contexts, and many small-scale examples of gene clustering. We describe several examples where S. maritima shows different solutions from insects to similar problems. The insect olfactory receptor gene family is absent from S. maritima, and olfaction in air is likely effected by expansion of other receptor gene families. For some genes S. maritima has evolved paralogues to generate coding sequence diversity, where insects use alternate splicing. This is most striking for the Dscam gene, which in Drosophila generates more than 100,000 alternate splice forms, but in S. maritima is encoded by over 100 paralogues. We see an intriguing linkage between the absence of any known photosensory proteins in a blind organism and the additional absence of canonical circadian clock genes. The phylogenetic position of myriapods allows us to identify where in arthropod phylogeny several particular molecular mechanisms and traits emerged. For example, we conclude that juvenile hormone signalling evolved with the emergence of the exoskeleton in the arthropods and that RR-1 containing cuticle proteins evolved in the lineage leading to Mandibulata. We also identify when various gene expansions and losses occurred. The genome of S. maritima offers us a unique glimpse into the ancestral arthropod genome, while also displaying many adaptations to its specific life history. Y1 - 2014 U6 - https://doi.org/10.1371/journal.pbio.1002005 SN - 1545-7885 VL - 12 IS - 11 PB - PLoS CY - San Fransisco ER - TY - JOUR A1 - Neumann, Bernhard A1 - Horstkemper, Marianne A1 - Krüger, Wolfgang A1 - Wilkens, Martin A1 - Bohlen, Andreas A1 - Frübing, Peter A1 - Wegener, Michael A1 - Scheff, Ullrich A1 - Neher, Dieter A1 - Brehmer, Ludwig A1 - Kleinpeter, Erich A1 - Wolf, Gunter A1 - Koetz, Joachim A1 - Peter, Martin G. A1 - Senkbeil, Sigrid A1 - Meyer, Till T1 - Portal = Im Trend: Physiker und Chemiker erforschen "Soft Matter" BT - Die Potsdamer Universitätszeitung N2 - Aus dem Inhalt: Im Trend: Physiker und Chemiker erforschen „Soft Matter“ -Brandenburger Netzwerk für Existenzgründer erhält Förderung -Universität leistet Beitrag zum Romantik-Jahr -Musiksender MTV und Bryan Adams auf dem Campus T3 - Portal: Das Potsdamer Universitätsmagazin - 06/2002 Y1 - 2002 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-501441 SN - 1618-6893 VL - 2002 ER - TY - JOUR A1 - Höpfner, Ulf A1 - Frübing, Peter A1 - Neumann, Werner A1 - Kaminorz, Yvette A1 - Brehmer, Ludwig T1 - Polarization Processes of poly(DMDAAC) films studied by TSD current Y1 - 1996 ER - TY - JOUR A1 - Saupe, Gabriele A1 - Neumann, Peter T1 - Vom Zentrum zur Peripherie - Raumstrukturen und -prozesse im Norden von Berlin Y1 - 1995 ER - TY - JOUR A1 - Neumann, Meina A1 - Mittelstaedt, Gerd A1 - Iobbi-Nivol, Chantal A1 - Saggu, Miguel A1 - Lendzian, Friedhelm A1 - Hildebrandt, Peter A1 - Leimkühler, Silke T1 - A periplasmic aldehyde oxidoreductase represents the first molybdopterin cytosine dinucleotide cofactor containing molybdo-flavoenzyme from Escherichia coli N2 - Three DNA regions carrying genes encoding putative homologs of xanthine dehydrogenases were identified in Escherichia coli, named xdhABC, xdhD, and yagTSRQ. Here, we describe the purification and characterization of gene products of the yagTSRQ operon, a molybdenum-containing iron-sulfur flavoprotein from E. coli, which is located in the periplasm. The 135 kDa enzyme comprised a noncovalent (alpha beta gamma) heterotrimer with a large (78.1 kDa) molybdenum cofactor (Moco)-containing YagR subunit, a medium (33.9 kDa) FAD-containing YagS subunit, and a small (21.0 kDa) 2 x [2Fe2S]-containing YagT subunit. YagQ is not a subunit of the mature enzyme, and the protein is expected to be involved in Moco modification and insertion into YagTSR. Analysis of the form of Moco present in YagTSR revealed the presence of the molybdopterin cytosine dinucleotide cofactor. Two different [2Fe2S] clusters, typical for this class of enzyme, were identified by EPR. YagTSR represents the first example of a molybdopterin cytosine dinucleotide-containing protein in E. coli. Kinetic characterization of the enzyme revealed that YagTSR converts a broad spectrum of aldehydes, with a preference for aromatic aldehydes. Ferredoxin instead of NAD(+) or molecular oxygen was used as terminal electron acceptor. Complete growth inhibition of E. coli cells devoid of genes from the yagTSRQ operon was observed by the addition of cinnamaldehyde to a low-pH medium. This finding shows that YagTSR might have a role in the detoxification of aromatic aldehydes for E. coli under certain growth conditions. Y1 - 2009 UR - http://www3.interscience.wiley.com/cgi-bin/issn?DESCRIPTOR=PRINTISSN&VALUE=1742-464X U6 - https://doi.org/10.1111/j.1742-4658.2009.07000.x SN - 1742-464X ER - TY - JOUR A1 - King, Turi E. A1 - Gonzalez-Fortes, Gloria M. A1 - Balaresque, Patricia A1 - Thomas, Mark G. A1 - Balding, David A1 - Delser, Pierpaolo Maisano A1 - Neumann, Rita A1 - Parson, Walther A1 - Knapp, Michael A1 - Walsh, Susan A1 - Tonasso, Laure A1 - Holt, John A1 - Kayser, Manfred A1 - Appleby, Jo A1 - Forster, Peter A1 - Ekserdjian, David A1 - Hofreiter, Michael A1 - Schuerer, Kevin T1 - Identification of the remains of King Richard III JF - Nature Communications Y1 - 2014 U6 - https://doi.org/10.1038/ncomms6631 SN - 2041-1723 VL - 5 PB - Nature Publ. Group CY - London ER - TY - JOUR A1 - Neumann, Mike A1 - Noeske, Robert A1 - Bach, Grete A1 - Glaubauf, Thomas A1 - Bartoszek, Michael A1 - Strauch, Peter T1 - A procedure for rapid determination of the silicon content in plant materials JF - Zeitschrift für Naturforschung : B, Chemical sciences N2 - An efficient, reliable and low-cost procedure to determine the silicon content in plant material is presented which allows to monitor the agricultural aspects like growth and yield. The presented procedure consists of a hydrochloric acid pre-treatment and a subsequent thermal oxidation. The method is compared to other processes like dissolution in hydrofluoric acid combined with ICP OES, energy-dispersive X-ray fluorescence spectroscopy (EDXRF) or aqua regia treatment. KW - Silica Determination KW - Silicon Content KW - Plant Material Y1 - 2011 SN - 0932-0776 VL - 66 IS - 3 SP - 289 EP - 294 PB - De Gruyter CY - Tübingen ER - TY - JOUR A1 - Strauch, Peter A1 - Neumann, Mike A1 - Kelling, Alexandra A1 - Schilde, Uwe T1 - Bis(1,2-dithiosquarato)nickelates(II): Synthesis, Structure, EPR and Thermal Behavior JF - Acta chimica Slovenica N2 - 1,2-Dithiosquaratonickelates are available by direct synthesis from metal salts with dipotassium-1,2-dithiosquarate and the appropriate counter cations. The synthesis and characterization, including mass spectrometry, of a series 1,2-dithiosquaratonickelates(II), [Ni(dtsq)(2)](2-), with several "onium" cations is reported and the X-ray structures of two diamagnetic complexes, (HexPh(3)P)(2)[Ni(dtsq)(2)] and (BuPh3P)(2)[Ni(dtsq)(2)] with sterically demanding counter ions are presented. The diamagnetic nickel complexes have been doped as host lattices with traces of Cu(II) to measure EPR for additional structural information. The thermal behavior of this series is studied by thermogravimetry and differential thermal analysis (TG/DTA). The thermolysis in air as well as under nitrogen atmosphere of these complexes results in nickel oxide nano-particles in all cases, which are characterized by X-ray powder diffraction. KW - 1,2-Dithiosquarate,1,2-Dithiosquaratonickelate KW - X-ray structure KW - TG/DTA KW - Nickel oxide KW - EPR spectroscopy Y1 - 2015 SN - 1318-0207 SN - 1580-3155 VL - 62 IS - 2 SP - 288 EP - 296 PB - Drustvo CY - Ljubljana ER - TY - JOUR A1 - Scheller, Frieder W. A1 - Kleinjung, Frank A1 - Bier, Frank Fabian A1 - Markower, Alexander A1 - Neumann, Barbara A1 - Wollenberger, Ursula A1 - Kurochkin, Iliya N. A1 - Eremenko, Arkadi V. A1 - Barmin, Anatoli V. A1 - Klußmann, Sven A1 - Fürste, Jens-Peter A1 - Erdmann, Volker A. A1 - Mansuy, D. T1 - New recognition elements in biosensing Y1 - 1998 ER - TY - JOUR A1 - Neumann, Mike A1 - Noeske, Robert A1 - Taubert, Andreas A1 - Tiersch, Brigitte A1 - Strauch, Peter T1 - Highly structured, biomorphous beta-SiC with high specific surface area from Equisetaceae JF - Journal of materials chemistry N2 - Mesoporous, highly structured silicon carbide (beta-SiC) was synthesised from renewable plant materials (two Equisetaceae species) in a one-step carbothermal process at remarkably low temperatures down to 1200 degrees C. The SiC precursor is a silicon-carbon mixture with finely dispersed carbon prepared by pyrolysis of the organic plant matrix. Yields are 3 to 100% (omega(Si/Si) related to the silicon deposited in the plant material), depending on reaction temperature and time. IR spectroscopy, X-ray diffraction, and nitrogen sorption prove the formation of high-purity beta-SiC with minor inorganic impurities after purification and a high specific surface area of up to 660 m(2) g(-1). Scanning electron microscopy shows that the plant morphology is maintained in the final SiC. Sedimentation analysis finds a mean particle size (diameters d(50)) of 20 mu m. Y1 - 2012 U6 - https://doi.org/10.1039/c2jm30253e SN - 0959-9428 VL - 22 IS - 18 SP - 9046 EP - 9051 PB - Royal Society of Chemistry CY - Cambridge ER - TY - RPRT A1 - Huber, Bettina A1 - Miechielsen, Milena A1 - Otto, Antje A1 - Schmidt, Katja A1 - Ullrich, Susann A1 - Deppermann, Lara-Helene A1 - Eckersley, Peter A1 - Haupt, Wolfgang A1 - Heidenreich, Anna A1 - Kern, Kristine A1 - Lipp, Torsten A1 - Neumann, Nina A1 - Schneider, Philipp A1 - Sterzel, Till A1 - Thieken, Annegret T1 - Instrumente und Maßnahmen der kommunalen Klimaanpassung T1 - Instruments and measures of municipal climate adaptation BT - Empirische Befunde für einen erfolgreichen Transfer BT - Empirical findings for a successful transfer N2 - Städte sind aufgrund ihrer Agglomeration von Bevölkerung, Sachwerten und Infrastrukturen in besonderem Maße von extremen Wetterereignissen wie Starkregen und Hitze betroffen. Zahlreiche Überflutungsereignisse infolge von Starkregen traten in den letzten Jahren in verschiedenen Regionen Deutschlands auf und führten nicht nur zu Schäden in zwei- bis dreistelliger Millionenhöhe, sondern auch zu Todesopfern. Und auch Hitzewellen, wie sie in den vergangenen Jahren vermehrt aufgetreten sind, bergen gesundheitliche Risiken, welche sich auch in verschiedenen Schätzungen zu Hitzetodesfällen wiederfinden. Um diesen Risiken zu begegnen und Schäden infolge von Wetterextremen zu reduzieren, entwickeln viele Kommunen bereits Strategien und Konzepte im Kontext der Klimaanpassung und/oder setzen Anpassungsmaßnahmen um. Neben der Entwicklung und Umsetzung eigener Ideen orientieren sich Städte dabei u. a. an Leitfäden und Beispielen aus der Literatur, Erfahrungen aus anderen Städten oder an Ergebnissen aus Forschungsprojekten. Dieser Lern- und Transferprozess, der eine Übertragung von Maßnahmen oder Instrumenten der Klimaanpassung von einem Ort auf einen anderen beinhaltet, ist bislang noch unzureichend erforscht und verstanden. Der vorliegende Bericht untersucht deshalb ebendiesen Lern- und Transferprozess zwischen sowie innerhalb von Städten sowie das Transferpotenzial konkreter Wissenstransfer-Medien, Instrumente und Maßnahmen. Damit wird das Ziel verfolgt, ein besseres Verständnis dieser Prozesse zu entwickeln und einen Beitrag zur Verbesserung des Transfers von kommunalen Klimaanpassungsaktivitäten zu leisten. Der vorliegende Inhalt baut dabei auf einer vorangegangenen Analyse des Forschungsstands zum Transfer von Policies durch Haupt et al. (2021) auf und versucht, den bereits generierten Wissensstand auf der Ebene von Policies nun um die Ebene konkreter Instrumente und Maßnahmen zu ergänzen sowie durch empirische Befunde zu ausgewählten Maßnahmen zu untermauern. Die Wissens- und Datengrundlage dieses Berichts umfasst einen Mix aus verschiedenen (Online)-Befragungen und Interviews mit Vertreter:innen relevanter Akteursgruppen, vor allem Vertreter:innen von Stadtverwaltungen, sowie den Erfahrungswerten der drei ExTrass-Fallstudienstädte Potsdam, Remscheid und Würzburg. Nach einer Einleitung beschäftigt sich Kapitel 2 mit übergeordneten Faktoren der Übertragbarkeit bzw. des Transfers. Kapitel 2.1 bietet hierbei eine Zusammenfassung zum aktuellen Wissensstand hinsichtlich des Transfers von Policies im Bereich der städtischen Klimapolitik gemäß Haupt et al. (2021). Hier werden zentrale Kriterien für einen erfolgreichen Transfer herausgearbeitet, um einen Anknüpfungspunkt für die folgenden Inhalte und empirischen Befunde auf der Ebene konkreter Instrumente und Maßnahmen zu bieten. Kapitel 2.2 schließt hieran an und präsentiert Erkenntnisse aus einer weitreichenden Kommunalbefragung. Hierbei wurde untersucht ob und welche Klimaanpassungsmaßnahmen in den Städten bereits umgesetzt werden, welche fördernden und hemmenden Aspekte es dabei gibt und welche Erfahrungen beim Transfer von Wissen und Ideen bereits vorliegen. Kapitel 3 untersucht die Rolle verschiedener Medien des Wissenstransfers und widmet sich dabei beispielhaft Leitfäden zur Klimaanpassung und Maßnahmensteckbriefen. Kapitel 3.1 beantwortet dabei Fragen nach der Relevanz und Zugänglichkeit von Leitfäden, deren Stärken und Schwächen, sowie konkreten Anforderungen vonseiten befragter Personen. Außerdem werden acht ausgewählte Leitfäden vorgestellt und komprimiert auf ihre Transferpotenziale hin eingeschätzt. Kapitel 3.2 betrachtet Maßnahmensteckbriefe als Medien des Wissenstransfers und arbeitet zentrale Aspekte für einen praxisrelevanten inhaltlichen Aufbau heraus, um basierend darauf einen Muster-Maßnahmensteckbrief für Klimaanpassungsmaßnahmen zu entwickeln und vorzuschlagen. Kapitel 4 beschäftigt sich mit sehr konkreten kommunalen Erfahrungen rund um den Transfer von sieben ausgewählten Instrumenten und Maßnahmen und bietet zahlreiche empirische Befunde aus den Kommunen, basierend auf der Kommunalbefragung, verschiedenen Interviews und den Erfahrungen aus der Projektarbeit. Die folgenden sieben Instrumente und Maßnahmen wurden ausgewählt, um eine große Breite städtischer Klimaanpassungsaktivitäten zu betrachten: 1) Klimafunktionskarten (Stadtklimakarten), 2) Starkregengefahrenkarten, 3) Checklisten zur Klimaanpassung in der Bauleitplanung, 4) Verbot von Schottergärten in Bebauungsplänen, 5) Fassadenbegrünungen, 6) klimaangepasste Gestaltung von Grün- und Freiflächen sowie 7) Handlungsempfehlungen für Betreuungseinrichtungen zum Umgang mit Hitze und Starkregen. Für jede dieser Klimaanpassungsaktivitäten wird auf Ebene der Kommunen Ziel, Verbreitung und Erscheinungsformen, Umsetzung anhand konkreter Beispiele, fördernde und hemmende Faktoren sowievorliegende Erfahrungen zu und Hinweisen auf Transfer dargestellt. Kapitel 5 schließt den vorliegenden Bericht ab, indem zentrale Transfer-Barrieren aus den gewonnenen Erkenntnissen aufgegriffen und entsprechende Empfehlungen an verschiedene Ebenen der Politik ausgesprochen werden. Diese Empfehlungen zur Verbesserung des Transfers von klimaanpassungsrelevanten Instrumenten, Strategien und Maßnahmen umfassen 1) die Verbesserung des Austauschs zwischen verschiedenen Städten, 2) die Verbesserung der Zugänglichkeit von Wissen und Erfahrungen, 3) die Schaffung von Vernetzungsstrukturen innerhalb von Städten sowie 4) bestehende Wissenslücken zu schließen. Die Autor:innen des vorliegenden Berichts hoffen, durch die vielfältigen Untersuchungsaspekte einen Beitrag zum besseren Verständnis der Lern- und Transferprozesse und zur Verbesserung des Transfers kommunaler Klimaanpassungsaktivitäten zu leisten. N2 - Due to their agglomeration of population, material assets and infrastructures, cities are particularly affected by extreme weather events such as heavy rain and heat. Numerous flooding events as a result of heavy rainfall occurred in various regions of Germany in the last years, not only resulted in losses in the double- to triple-digit million range, but also in fatalities. And heat waves which became more frequent in recent years pose health risks, including numerous cases of death. To counter these risks and to reduce damage resulting from weather extremes, many cities are already developing strategies and concepts in the context of climate adaptation and/or implement measures. In addition to developing and implementing their own ideas, cities are guided by guidelines and examples from literature, experiences from other cities, or results from research projects, among other things. This learning and transfer process, which involves the transfer of climate adaptation measures or instruments from one place to another, has not yet been sufficiently researched and understood. This report therefore examines this learning and transfer process between and within cities as well as the transfer potential of specific knowledge transfer media, instruments and measures. The aim is to develop a better understanding of these processes and to contribute to improving the transfer of municipal climate adaptation activities. This content builds on a previous analysis of the state of research on policy transfer by Haupt et al. (2021) and attempts to complement the already generated state of knowledge on the level of policies with the level of concrete instruments and measures and to substantiate it with empirical findings. The knowledge and data basis of this report comprises a mix of various (online) surveys and interviews with representatives of relevant stakeholder groups, especially representatives of city administrations, as well as the experiences of the three case study cities within the ExTrass-project, namely Potsdam, Remscheid and Würzburg. After an introduction, chapter 2 deals with overarching factors of transferability. Chapter 2.1 provides a summary of the current state of knowledge regarding the transfer of policies in the field of urban climate policy according to Haupt et al. (2021). Here, central criteria for a successful transfer are elaborated in order to provide a starting point for the following contents and empirical findings on the level of concrete instruments and measures. Chapter 2.2 follows on from this and presents findings from a wide-ranging municipal survey. Here, it was investigated whether and which climate adaptation measures are already implemented in the cities, which supporting and inhibiting aspects are present in this context, and which experiences regarding the transfer of knowledge and ideas already exist. Chapter 3 examines the role of different knowledge transfer media, focusing on guidelines on climate adaptation and fact sheets for adaptation measures as examples. Chapter 3.1 answers questions about the relevance and accessibility of guidelines, their strengths and weaknesses, as well as concrete requirements articulated by interviewees. In addition, eight selected guidelines are shortly presented and assessed in terms of their transfer potential. Chapter 3.2 looks at fact sheets for adaptation measures and elaborates central aspects for a practicable content structure and ultimately results in a proposed template fact sheet for climate adaptation measure. Chapter 4 deals with very concrete municipal experiences regarding the transfer of seven selected instruments and measures and offers numerous empirical findings from municipalities, based on the municipal survey, various interviews and the experiences drawn from the project work. The following seven tools and measures were selected to look at a broad range of urban climate adaptation activities: 1) climate function maps (urban climate maps), 2) heavy rainfall hazard maps, 3) climate adaptation checklists in urban land use planning, 4) prohibition of gravel gardens in development plans, 5) facade greening, 6) climate-adapted design of green and open spaces, and 7) recommendations for care facilities to deal with heat and heavy rain. For each of these instruments or measures at the municipality level the purpose or goal, its dissemination and manifestations, its implementation through practical examples, its supporting and inhibiting factors as well as existing experiences with and evidence of transfer are presented. Chapter 5 concludes this report by addressing key transfer barriers and making formulating recommendations for different political levels. These recommendations for improving the transfer of climate adaptation-related instruments, strategies and measures include: 1) improving the exchange between different cities, 2) improving the accessibility of knowledge and experience, 3) creating networking structures within cities and 4) closing existing knowledge gaps. The authors of this report hope to contribute to a better understanding of the learning and transfer processes and to the improvement of the transfer of municipal climate adaptation activities through the manifold aspects of this study. KW - Klimaanpassung KW - Übertragbarkeit KW - Anpassungsmaßnahmen KW - Wissenstransfer KW - Climate adaptation KW - Transferablity KW - adapatation measures KW - knowledge transfer KW - Modellstadt KW - model city KW - Pilotmaßnahmen KW - pilot measures Y1 - 2022 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-563456 ER - TY - JOUR A1 - Penschke, Christopher A1 - Edler von Zander, Robert A1 - Beqiraj, Alkit A1 - Zehle, Anna A1 - Jahn, Nicolas A1 - Neumann, Rainer A1 - Saalfrank, Peter T1 - Water on porous, nitrogen-containing layered carbon materials BT - the performance of computational model chemistries JF - Physical chemistry, chemical physics : PCCP ; a journal of European chemical societies / RSC, Royal Society of Chemistry N2 - Porous, layered materials containing sp(2)-hybridized carbon and nitrogen atoms, offer through their tunable properties, a versatile route towards tailormade catalysts for electrochemistry and photochemistry. A key molecule interacting with these quasi two-dimensional materials (2DM) is water, and a photo(electro)chemical key reaction catalyzed by them, is water splitting into H-2 and O-2, with the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER) as half reactions. The complexity of some C/N-based 2DM in contact with water raises special needs for their theoretical modelling, which in turn is needed for rational design of C/N-based catalysts. In this work, three classes of C/N-containing porous 2DM with varying pore sizes and C/N ratios, namely graphitic carbon nitride (g-C3N4), C2N, and poly(heptazine imides) (PHI), are studied with various computational methods. We elucidate the performance of different models and model chemistries (the combination of electronic structure method and basis set) for water and water fragment adsorption in the low-coverage regime. Further, properties related to the photo(electro)chemical activity like electrochemical overpotentials, band gaps, and optical excitation energies are in our focus. Specifically, periodic models will be tested vs. cluster models, and density functional theory (DFT) vs. wavefunction theory (WFT). This work serves as a basis for a systematic study of trends for the photo(electro)chemical activity of C/N-containing layered materials as a function of water content, pore size and density. Y1 - 2022 U6 - https://doi.org/10.1039/d2cp00657j SN - 1463-9076 SN - 1463-9084 VL - 24 IS - 24 SP - 14709 EP - 14726 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Wirth, Jonas A1 - Neumann, Rainer A1 - Antonietti, Markus A1 - Saalfrank, Peter T1 - Adsorption and photocatalytic splitting of water on graphitic carbon nitride: a combined first principles and semiempirical study JF - Physical chemistry, chemical physics : a journal of European Chemical Societies N2 - Graphitic carbon nitride, g-C3N4, is a promising organic photo-catalyst for a variety of redox reactions. In order to improve its efficiency in a systematic manner, however, a fundamental understanding of the microscopic interaction between catalyst, reactants and products is crucial. Here we present a systematic study of water adsorption on g-C3N4 by means of density functional theory and the density functional based tight-binding method as a prerequisite for understanding photocatalytic water splitting. We then analyze this prototypical redox reaction on the basis of a thermodynamic model providing an estimate of the overpotential for both water oxidation and H+ reduction. While the latter is found to occur readily upon irradiation with visible light, we derive a prohibitive overpotential of 1.56 eV for the water oxidation half reaction, comparing well with the experimental finding that in contrast to H-2 production O-2 evolution is only possible in the presence of oxidation cocatalysts. Y1 - 2014 U6 - https://doi.org/10.1039/c4cp02021a SN - 1463-9076 SN - 1463-9084 VL - 16 IS - 30 SP - 15917 EP - 15926 PB - Royal Society of Chemistry CY - Cambridge ER - TY - GEN A1 - Wirth, Jonas A1 - Neumann, Rainer A1 - Antonietti, Markus A1 - Saalfrank, Peter T1 - Adsorption and photocatalytic splitting of water on graphitic carbon nitride BT - a combined first principles and semiempirical study N2 - Graphitic carbon nitride, g-C₃N₄, is a promising organic photo-catalyst for a variety of redox reactions. In order to improve its efficiency in a systematic manner, however, a fundamental understanding of the microscopic interaction between catalyst, reactants and products is crucial. Here we present a systematic study of water adsorption on g-C₃N₄ by means of density functional theory and the density functional based tight-binding method as a prerequisite for understanding photocatalytic water splitting. We then analyze this prototypical redox reaction on the basis of a thermodynamic model providing an estimate of the overpotential for both water oxidation and H⁺ reduction. While the latter is found to occur readily upon irradiation with visible light, we derive a prohibitive overpotential of 1.56 eV for the water oxidation half reaction, comparing well with the experimental finding that in contrast to H₂ production O₂ evolution is only possible in the presence of oxidation cocatalysts. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - paper 172 KW - augmented-wave method KW - hydrogen KW - initio molecular-dynamics KW - oxidation KW - photooxidation KW - reduction KW - simulations KW - tight-binding KW - transition KW - visible-light Y1 - 2014 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-74391 SP - 15917 EP - 15926 ER - TY - JOUR A1 - Wirth, Jonas A1 - Neumann, Rainer A1 - Antonietti, Markus A1 - Saalfrank, Peter T1 - Adsorption and photocatalytic splitting of water on graphitic carbon nitride BT - a combined first principles and semiempirical study JF - physical chemistry, chemical physics : PCCP N2 - Graphitic carbon nitride, g-C₃N₄, is a promising organic photo-catalyst for a variety of redox reactions. In order to improve its efficiency in a systematic manner, however, a fundamental understanding of the microscopic interaction between catalyst, reactants and products is crucial. Here we present a systematic study of water adsorption on g-C₃N₄ by means of density functional theory and the density functional based tight-binding method as a prerequisite for understanding photocatalytic water splitting. We then analyze this prototypical redox reaction on the basis of a thermodynamic model providing an estimate of the overpotential for both water oxidation and H⁺ reduction. While the latter is found to occur readily upon irradiation with visible light, we derive a prohibitive overpotential of 1.56 eV for the water oxidation half reaction, comparing well with the experimental finding that in contrast to H₂ production O₂ evolution is only possible in the presence of oxidation cocatalysts. KW - initio molecular-dynamics KW - augmented-wave method KW - visible-light KW - tight-binding KW - transition KW - oxidation KW - photooxidation KW - simulations KW - reduction KW - hydrogen Y1 - 2014 U6 - https://doi.org/10.1039/c4cp02021a SN - 1463-9076 SN - 1463-9084 VL - 2014 IS - 16 SP - 15917 EP - 15926 ER - TY - JOUR A1 - Frübing, Peter A1 - Kremmer, Alexander A1 - Neumann, Werner A1 - Gerhard, Reimund A1 - Guy, I. L. T1 - Dielectric relaxation in piezo-, pyro- and ferroelectric polyamide 11 N2 - Ferroelectric polyamide 11 films were prepared by melt-quenching, cold-drawing and electrical poling. Their ferroelectricity was studied by means of dielectric-hysteresis measurements. A remnant polarisation of up to 35 mC/m(2) and a coercive field of 75 MV/m were obtained. The piezoelectric d(33) coefficient and the pyroelectric coefficient of the films are reduced by annealing just below the melting region, but remain at about 3 pC/N and 8 muC/(m(2)K), respectively, during further heat treatment. Differential scanning calorimetry (DSC), dielectric relaxation spectroscopy (DRS) and thermally stimulated depolarisation (TSD) were applied for investigating the conformational changes induced by melt-quenching, cold-drawing and annealing. The results indicate that the cold-drawn film mainly consists of a rigid amorphous phase which exhibits considerably lower conductivity, no glass transition and consequently no dielectric a relaxation. Instead, an a, relaxation is found, which is related to chain motions in regions of the rigid amorphous phase where the amide-group dipoles are not perfectly ordered. Annealing removes imperfectly ordered structures, but does not affect the ferroelectric polarisation. Therefore, it may be concluded that essentially the a, relaxation causes the thermally non-stable part of the piezo- and pyroelectricity in polyamide 11 Y1 - 2004 ER - TY - JOUR A1 - Frübing, Peter A1 - Wegener, Michael A1 - Gerhard, Reimund A1 - Buchsteiner, Alexandra A1 - Neumann, Werner A1 - Brehmer, Ludwig T1 - Different molecular mechanisms for the dielectric hysteresis and pyroelectricity in a poly(vinyl alcohol) with azobenzene-alkoxy side chains N2 - By means of pyroelectrical measurements and dielectric spectroscopy as well as structural information from differential scanning calorimetry, it is shown that, in a poly(vinyl alcohol) with azobenzene-alkoxy side chains, pyroelctricity and dielectric hysteresis which are usually related to each other have different origins. The pyroelectric effect is explained with reversible dipole-density changes upon thermal expansion, whereas the dielectric hysteresis is proposed to result from a charge-carrier polarisation. Y1 - 1999 SN - 0277-786X ER - TY - JOUR A1 - Frübing, Peter A1 - Wegener, Michael A1 - Gerhard, Reimund A1 - Buchsteiner, Alexandra A1 - Neumann, Werner A1 - Brehmer, Ludwig A1 - Dietel, Reinhard T1 - Pyroelectric properties and dielectric hysteresis of a poly(vinylalcohol) with azobenzene alkoxy side chains Y1 - 1999 ER - TY - JOUR A1 - Renner, Swen C. A1 - Neumann, Dirk A1 - Burkart, Michael A1 - Feit, Ute A1 - Giere, Peter A1 - Groeger, Andreas A1 - Paulsch, Axel A1 - Paulsch, Cornelia A1 - Sterz, Mario A1 - Vohland, Katrin T1 - Import and export of biological samples from tropical countries-considerations and guidelines for research teams JF - Organisms, diversity & evolution : official journal of the Gesellschaft für Biologische Systematik N2 - 'Biodiversity' is increasingly perceived as an important resource for research and conservation, but also for economy. Conservation, access and sustainable use of biodiversity (genetic resources, species, samples) are negotiated on different political levels, resulting in an internationally binding legal framework. Resulting legislation is binding for all parties involved in biological sampling, i.e. researches and (and in italics) countries, and especially applies for tissue or DNA samples and dervied products thereof. Understanding and awareness of export and import permits for biological samples is increasingly important for biologists to perform research projects legally and timely. Nevertheless, some biologists are still exporting and importing biological samples ignoring or noncompliant with national and international legislation, conventions, and regulations. Resulting difficulties may not only cause serious problems during field work, but may also delay the export, import or exchange of samples. Comprehensive a priori information regarding legal requirements helps to avoid or at least diminish potential problems. We identified four major factors facilitating export/import permits: (1) good personal (mutually trusted) contacts in the country of origin, (2) understanding and compliance with all relevant laws and regulations; (3) access to information regarding knowledge on permits, regulations and laws including their circulation within the researcher communities; and (4) access to consistent and up to date regulations KW - Research samples KW - Collection KW - Export KW - Import KW - Legislation KW - Permits KW - Specimens KW - Convention on Biological Diversity CBD KW - Access and Benefit Sharing ABS KW - Convention on International Trade in Endangered Species of Wild Fauna and Flora CITES KW - European Union EU KW - Country of origin Y1 - 2012 U6 - https://doi.org/10.1007/s13127-012-0076-4 SN - 1439-6092 VL - 12 IS - 1 SP - 81 EP - 98 PB - Springer CY - Heidelberg ER -