TY  - JOUR
A1  - Wessig, Pablo
A1  - Gerngroß, Maik
A1  - Pape, Simon
A1  - Bruhns, Philipp
A1  - Weber, Jens
T1  - Novel porous materials based on oligospiroketals (OSK)
JF  - RSC Advances : an international journal to further the chemical sciences
N2  - New porous materials based on covalently connected monomers are presented. The key step of the synthesis is an acetalisation reaction. In previous years we used acetalisation reactions extensively to build up various molecular rods. Based on this approach, investigations towards porous polymeric materials were conducted by us. Here we wish to present the results of these studies in the synthesis of 1D polyacetals and porous 3D polyacetals. By scrambling experiments with 1D acetals we could prove that exchange reactions occur between different building blocks (evidenced by MALDI-TOF mass spectrometry). Based on these results we synthesized porous 3D polyacetals under the same mild conditions.
KW  - microporous organic polymers
KW  - molecular rods
KW  - construction
KW  - frameworks
KW  - membranes
KW  - sorption
KW  - models
Y1  - 2014
U6  - https://doi.org/10.1039/c4ra04437a
SN  - 2046-2069
VL  - 2014
IS  - 4
SP  - 31123
EP  - 31129
ER  - 
TY  - GEN
A1  - Wessig, Pablo
A1  - Gerngroß, Maik
A1  - Pape, Simon
A1  - Bruhns, Philipp
A1  - Weber, Jens
T1  - Novel porous materials based on oligospiroketals (OSK)
N2  - New porous materials based on covalently connected monomers are presented. The key step of the synthesis is an acetalisation reaction. In previous years we used acetalisation reactions extensively to build up various molecular rods. Based on this approach, investigations towards porous polymeric materials were conducted by us. Here we wish to present the results of these studies in the synthesis of 1D polyacetals and porous 3D polyacetals. By scrambling experiments with 1D acetals we could prove that exchange reactions occur between different building blocks (evidenced by MALDI-TOF mass spectrometry). Based on these results we synthesized porous 3D polyacetals under the same mild conditions.
T3  - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - paper 175 
KW  - construction
KW  - frameworks
KW  - membranes
KW  - microporous organic polymers
KW  - models
KW  - molecular rods
KW  - sorption
Y1  - 2014
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-74466
SP  - 31123
EP  - 31129
ER  - 
TY  - THES
A1  - Gerngroß, Maik
T1  - Untersuchungen zur Herstellung poröser Materialien durch Acetalisierungsreaktionen
Y1  - 2014
ER  - 
TY  - JOUR
A1  - Wessig, Pablo
A1  - Gerngross, Maik
A1  - Freyse, Daniel
A1  - Bruhn, P.
A1  - Przezdziak, Marc
A1  - Schilde, Uwe
A1  - Kelling, Alexandra
T1  - Molecular Rods Based on Oligo-spiro-thioketals
JF  - The journal of organic chemistry
N2  - We report on an extension of the previously established concept of oligospiroketal (OSK) rods by replacing a part or all ketal moieties by thioketals leading to oligospirothioketal (OSTK) rods. In this way, some crucial problems arising from the reversible formation of ketals are circumvented. Furthermore, the stability of the rods toward hydrolysis is considerably improved. To successfully implement this concept, we first developed a number of new oligothiol building blocks and improved the synthetic accessibility of known oligothiols, respectively. Another advantage of thioacetals is that terephthalaldehyde (TAA) sleeves, which are too flexible in the case of acetals can be used in OSTK rods. The viability of the OSTK approach was demonstrated by the successful preparation of some OSTK rods with a length of some nanometers.
Y1  - 2016
U6  - https://doi.org/10.1021/acs.joc.5b02670
SN  - 0022-3263
VL  - 81
SP  - 1125
EP  - 1136
PB  - American Chemical Society
CY  - Washington
ER  - 
TY  - JOUR
A1  - Wessig, Pablo
A1  - Gerngross, Maik
A1  - Pape, Simon
A1  - Bruhns, Philipp
A1  - Weber, Jens
T1  - Novel porous materials based on oligospiroketals (OSK)
JF  - RSC Advances
N2  - New porous materials based on covalently connected monomers are presented. The key step of the synthesis is an acetalisation reaction. In previous years we used acetalisation reactions extensively to build up various molecular rods. Based on this approach, investigations towards porous polymeric materials were conducted by us. Here we wish to present the results of these studies in the synthesis of 1D polyacetals and porous 3D polyacetals. By scrambling experiments with 1D acetals we could prove that exchange reactions occur between different building blocks (evidenced by MALDI-TOF mass spectrometry). Based on these results we synthesized porous 3D polyacetals under the same mild conditions.
Y1  - 2014
U6  - https://doi.org/10.1039/c4ra04437a
SN  - 2046-2069
VL  - 4
IS  - 59
SP  - 31123
EP  - 31129
PB  - Royal Society of Chemistry
CY  - Cambridge
ER  -