TY  - CHAP
A1  - Curzon, Paul
A1  - Kalas, Ivan
A1  - Schubert, Sigrid
A1  - Schaper, Niclas
A1  - Barnes, Jan
A1  - Kennewell, Steve
A1  - Bröker, Kathrin
A1  - Kastens, Uwe
A1  - Magenheim, Johannes
A1  - Dagiene, Valentina
A1  - Stupuriene, Gabriele
A1  - Ellis, Jason Brent
A1  - Abreu-Ellis, Carla Reis
A1  - Grillenberger, Andreas
A1  - Romeike, Ralf
A1  - Haugsbakken, Halvdan
A1  - Jones, Anthony
A1  - Lewin, Cathy
A1  - McNicol, Sarah
A1  - Nelles, Wolfgang
A1  - Neugebauer, Jonas
A1  - Ohrndorf, Laura
A1  - Schaper, Niclas
A1  - Schubert, Sigrid
A1  - Opel, Simone
A1  - Kramer, Matthias
A1  - Trommen, Michael
A1  - Pottbäcker, Florian
A1  - Ilaghef, Youssef
A1  - Passig, David
A1  - Tzuriel, David
A1  - Kedmi, Ganit Eshel
A1  - Saito, Toshinori
A1  - Webb, Mary
A1  - Weigend, Michael
A1  - Bottino, Rosa
A1  - Chioccariello, Augusto
A1  - Christensen, Rhonda
A1  - Knezek, Gerald
A1  - Gioko, Anthony Maina
A1  - Angondi, Enos Kiforo
A1  - Waga, Rosemary
A1  - Ohrndorf, Laura
A1  - Or-Bach, Rachel
A1  - Preston, Christina
A1  - Younie, Sarah
A1  - Przybylla, Mareen
A1  - Romeike, Ralf
A1  - Reynolds, Nicholas
A1  - Swainston, Andrew
A1  - Bendrups, Faye
A1  - Sysło, Maciej M.
A1  - Kwiatkowska, Anna Beata
A1  - Zieris, Holger
A1  - Gerstberger, Herbert
A1  - Müller, Wolfgang
A1  - Büchner, Steffen
A1  - Opel, Simone
A1  - Schiller, Thomas
A1  - Wegner, Christian
A1  - Zender, Raphael
A1  - Lucke, Ulrike
A1  - Diethelm, Ira
A1  - Syrbe, Jörn
A1  - Lai, Kwok-Wing
A1  - Davis, Niki
A1  - Eickelmann, Birgit
A1  - Erstad, Ola
A1  - Fisser, Petra
A1  - Gibson, David
A1  - Khaddage, Ferial
A1  - Knezek, Gerald
A1  - Micheuz, Peter
A1  - Kloos, Carlos Delgado
ED  - Brinda, Torsten
ED  - Reynolds, Nicholas
ED  - Romeike, Ralf
ED  - Schwill, Andreas
T1  - KEYCIT 2014
BT  - key competencies in informatics and ICT
N2  - In our rapidly changing world it is increasingly important not only to be an expert in a chosen field of study but also to be able to respond to developments, master new approaches to solving problems, and fulfil changing requirements in the modern world and in the job market. In response to these needs key competencies in understanding, developing and using new digital technologies are being brought into focus in school and university programmes. The IFIP TC3 conference "KEYCIT – Key Competences in Informatics and ICT (KEYCIT 2014)" was held at the University of Potsdam in Germany from July 1st to 4th, 2014 and addressed the combination of key competencies, Informatics and ICT in detail. The conference was organized into strands focusing on secondary education, university education and teacher education (organized by IFIP WGs 3.1 and 3.3) and provided a forum to present and to discuss research, case studies, positions, and national perspectives in this field.
T3  - Commentarii informaticae didacticae (CID) - 7 
KW  - Schlüsselkompetenzen
KW  - Informatik
KW  - Bildung
KW  - ICT
KW  - Informatikdidaktik
KW  - Key Competencies
KW  - Informatics
KW  - education
KW  - ICT
KW  - Computer Science Education
Y1  - 2015
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-70325
SN  - 978-3-86956-292-6
PB  - Universitätsverlag Potsdam
CY  - Potsdam
ER  - 
TY  - JOUR
A1  - Arridge, Christopher S.
A1  - Achilleos, N.
A1  - Agarwal, Jessica
A1  - Agnor, C. B.
A1  - Ambrosi, R.
A1  - Andre, N.
A1  - Badman, S. V.
A1  - Baines, K.
A1  - Banfield, D.
A1  - Barthelemy, M.
A1  - Bisi, M. M.
A1  - Blum, J.
A1  - Bocanegra-Bahamon, T.
A1  - Bonfond, B.
A1  - Bracken, C.
A1  - Brandt, P.
A1  - Briand, C.
A1  - Briois, C.
A1  - Brooks, S.
A1  - Castillo-Rogez, J.
A1  - Cavalie, T.
A1  - Christophe, B.
A1  - Coates, Andrew J.
A1  - Collinson, G.
A1  - Cooper, J. F.
A1  - Costa-Sitja, M.
A1  - Courtin, R.
A1  - Daglis, I. A.
A1  - De Pater, Imke
A1  - Desai, M.
A1  - Dirkx, D.
A1  - Dougherty, M. K.
A1  - Ebert, R. W.
A1  - Filacchione, Gianrico
A1  - Fletcher, Leigh N.
A1  - Fortney, J.
A1  - Gerth, I.
A1  - Grassi, D.
A1  - Grodent, D.
A1  - Grün, Eberhard
A1  - Gustin, J.
A1  - Hedman, M.
A1  - Helled, R.
A1  - Henri, P.
A1  - Hess, Sebastien
A1  - Hillier, J. K.
A1  - Hofstadter, M. H.
A1  - Holme, R.
A1  - Horanyi, M.
A1  - Hospodarsky, George B.
A1  - Hsu, S.
A1  - Irwin, P.
A1  - Jackman, C. M.
A1  - Karatekin, O.
A1  - Kempf, Sascha
A1  - Khalisi, E.
A1  - Konstantinidis, K.
A1  - Kruger, H.
A1  - Kurth, William S.
A1  - Labrianidis, C.
A1  - Lainey, V.
A1  - Lamy, L. L.
A1  - Laneuville, Matthieu
A1  - Lucchesi, D.
A1  - Luntzer, A.
A1  - MacArthur, J.
A1  - Maier, A.
A1  - Masters, A.
A1  - McKenna-Lawlor, S.
A1  - Melin, H.
A1  - Milillo, A.
A1  - Moragas-Klostermeyer, Georg
A1  - Morschhauser, Achim
A1  - Moses, J. I.
A1  - Mousis, O.
A1  - Nettelmann, N.
A1  - Neubauer, F. M.
A1  - Nordheim, T.
A1  - Noyelles, B.
A1  - Orton, G. S.
A1  - Owens, Mathew
A1  - Peron, R.
A1  - Plainaki, C.
A1  - Postberg, F.
A1  - Rambaux, N.
A1  - Retherford, K.
A1  - Reynaud, Serge
A1  - Roussos, E.
A1  - Russell, C. T.
A1  - Rymer, Am.
A1  - Sallantin, R.
A1  - Sanchez-Lavega, A.
A1  - Santolik, O.
A1  - Saur, J.
A1  - Sayanagi, Km.
A1  - Schenk, P.
A1  - Schubert, J.
A1  - Sergis, N.
A1  - Sittler, E. C.
A1  - Smith, A.
A1  - Spahn, Frank
A1  - Srama, Ralf
A1  - Stallard, T.
A1  - Sterken, V.
A1  - Sternovsky, Zoltan
A1  - Tiscareno, M.
A1  - Tobie, G.
A1  - Tosi, F.
A1  - Trieloff, M.
A1  - Turrini, D.
A1  - Turtle, E. P.
A1  - Vinatier, S.
A1  - Wilson, R.
A1  - Zarkat, P.
T1  - The science case for an orbital mission to Uranus: Exploring the origins and evolution of ice giant planets
JF  - Planetary and space science
N2  - Giant planets helped to shape the conditions we see in the Solar System today and they account for more than 99% of the mass of the Sun's planetary system. They can be subdivided into the Ice Giants (Uranus and Neptune) and the Gas Giants (Jupiter and Saturn), which differ from each other in a number of fundamental ways. Uranus, in particular is the most challenging to our understanding of planetary formation and evolution, with its large obliquity, low self-luminosity, highly asymmetrical internal field, and puzzling internal structure. Uranus also has a rich planetary system consisting of a system of inner natural satellites and complex ring system, five major natural icy satellites, a system of irregular moons with varied dynamical histories, and a highly asymmetrical magnetosphere. Voyager 2 is the only spacecraft to have explored Uranus, with a flyby in 1986, and no mission is currently planned to this enigmatic system. However, a mission to the uranian system would open a new window on the origin and evolution of the Solar System and would provide crucial information on a wide variety of physicochemical processes in our Solar System. These have clear implications for understanding exoplanetary systems. In this paper we describe the science case for an orbital mission to Uranus with an atmospheric entry probe to sample the composition and atmospheric physics in Uranus' atmosphere. The characteristics of such an orbiter and a strawman scientific payload are described and we discuss the technical challenges for such a mission. This paper is based on a white paper submitted to the European Space Agency's call for science themes for its large-class mission programme in 2013.
KW  - Uranus
KW  - Magnetosphere
KW  - Atmosphere
KW  - Natural satellites
KW  - Rings
KW  - Planetary interior
Y1  - 2014
U6  - https://doi.org/10.1016/j.pss.2014.08.009
SN  - 0032-0633
VL  - 104
SP  - 122
EP  - 140
PB  - Elsevier
CY  - Oxford
ER  - 
TY  - JOUR
A1  - Verma, Meetu
A1  - Denker, Carsten
A1  - Balthasar, H.
A1  - Kuckein, Christoph
A1  - González Manrique, Sergio Javier
A1  - Sobotka, M.
A1  - Gonzalez, N. Bello
A1  - Hoch, S.
A1  - Diercke, Andrea
A1  - Kummerow, Philipp
A1  - Berkefeld, T.
A1  - Collados Vera, M.
A1  - Feller, A.
A1  - Hofmann, A.
A1  - Kneer, F.
A1  - Lagg, A.
A1  - Löhner-Böttcher, J.
A1  - Nicklas, H.
A1  - Pastor Yabar, A.
A1  - Schlichenmaier, R.
A1  - Schmidt, D.
A1  - Schmidt, W.
A1  - Schubert, M.
A1  - Sigwarth, M.
A1  - Solanki, S. K.
A1  - Soltau, D.
A1  - Staude, J.
A1  - Strassmeier, Klaus G.
A1  - Volkmer, R.
A1  - von der Lühe, O.
A1  - Waldmann, T.
T1  - Horizontal flow fields in and around a small active region The transition period between flux emergence and decay
JF  - Polymers
N2  - Context. The solar magnetic field is responsible for all aspects of solar activity. Thus, emergence of magnetic flux at the surface is the first manifestation of the ensuing solar activity. Aims. Combining high-resolution and synoptic observations aims to provide a comprehensive description of flux emergence at photospheric level and of the growth process that eventually leads to a mature active region. Methods. The small active region NOAA 12118 emerged on 2014 July 17 and was observed one day later with the 1.5-m GREGOR solar telescope on 2014 July 18. High-resolution time-series of blue continuum and G-band images acquired in the blue imaging channel (BIC) of the GREGOR Fabry-Perot Interferometer (GFPI) were complemented by synoptic line-of-sight magnetograms and continuum images obtained with the Helioseismic and Magnetic Imager (HMI) onboard the Solar Dynamics Observatory (SDO). Horizontal proper motions and horizontal plasma velocities were computed with local correlation tracking (LCT) and the differential affine velocity estimator (DAVE), respectively. Morphological image processing was employed to measure the photometric and magnetic area, magnetic flux, and the separation profile of the emerging flux region during its evolution. Results. The computed growth rates for photometric area, magnetic area, and magnetic flux are about twice as high as the respective decay rates. The space-time diagram using HMI magnetograms of five days provides a comprehensive view of growth and decay. It traces a leaf-like structure, which is determined by the initial separation of the two polarities, a rapid expansion phase, a time when the spread stalls, and a period when the region slowly shrinks again. The separation rate of 0.26 km s(-1) is highest in the initial stage, and it decreases when the separation comes to a halt. Horizontal plasma velocities computed at four evolutionary stages indicate a changing pattern of inflows. In LCT maps we find persistent flow patterns such as outward motions in the outer part of the two major pores, a diverging feature near the trailing pore marking the site of upwelling plasma and flux emergence, and low velocities in the interior of dark pores. We detected many elongated rapidly expanding granules between the two major polarities, with dimensions twice as large as the normal granules.
KW  - Sun: photosphere
KW  - Sun: magnetic fields
KW  - techniques: image processing
KW  - methods: data analysis
Y1  - 2016
U6  - https://doi.org/10.1051/0004-6361/201628380
SN  - 1432-0746
VL  - 596
PB  - EDP Sciences
CY  - Les Ulis
ER  - 
TY  - JOUR
A1  - Schubert, Mikkel
A1  - Jonsson, Hakon
A1  - Chang, Dan
A1  - Sarkissian, Clio Der
A1  - Ermini, Luca
A1  - Ginolhac, Aurelien
A1  - Albrechtsen, Anders
A1  - Dupanloup, Isabelle
A1  - Foucal, Adrien
A1  - Petersen, Bent Larsen
A1  - Fumagalli, Matteo
A1  - Raghavan, Maanasa
A1  - Seguin-Orlando, Andaine
A1  - Korneliussen, Thorfinn S.
A1  - Velazquez, Amhed M. V.
A1  - Stenderup, Jesper
A1  - Hoover, Cindi A.
A1  - Rubin, Carl-Johan
A1  - Alfarhan, Ahmed H.
A1  - Alquraishi, Saleh A.
A1  - Al-Rasheid, Khaled A. S.
A1  - MacHugh, David E.
A1  - Kalbfleisch, Ted
A1  - MacLeod, James N.
A1  - Rubin, Edward M.
A1  - Sicheritz-Ponten, Thomas
A1  - Andersson, Leif
A1  - Hofreiter, Michael
A1  - Marques-Bonet, Tomas
A1  - Gilbert, M. Thomas P.
A1  - Nielsen, Rasmus
A1  - Excoffier, Laurent
A1  - Willerslev, Eske
A1  - Shapiro, Beth
A1  - Orlando, Ludovic
T1  - Prehistoric genomes reveal the genetic foundation and cost of horse domestication
JF  - Proceedings of the National Academy of Sciences of the United States of America
Y1  - 2014
U6  - https://doi.org/10.1073/pnas.1416991111
SN  - 0027-8424
VL  - 111
IS  - 52
SP  - E5661
EP  - E5669
PB  - National Acad. of Sciences
CY  - Washington
ER  - 
TY  - JOUR
A1  - Keller, Sebastian
A1  - Wetterhorn, Karl M.
A1  - Vecellio, Alison
A1  - Seeger, Mark
A1  - Rayment, Ivan
A1  - Schubert, Torsten
T1  - Structural and functional analysis of an l-serine O-phosphate decarboxylase involved in norcobamide biosynthesis
JF  - FEBS letters : the journal for rapid publication of short reports in molecular biosciences
N2  - Structural diversity of natural cobamides (Cbas, B12 vitamers) is limited to the nucleotide loop. The loop is connected to the cobalt‐containing corrin ring via an (R)‐1‐aminopropan‐2‐ol O‐2‐phosphate (AP‐P) linker moiety. AP‐P is produced by the l‐threonine O‐3‐phosphate (l‐Thr‐P) decarboxylase CobD. Here, the CobD homolog SMUL_1544 of the organohalide‐respiring epsilonproteobacterium Sulfurospirillum multivorans was characterized as a decarboxylase that produces ethanolamine O‐phosphate (EA‐P) from l‐serine O‐phosphate (l‐Ser‐P). EA‐P is assumed to serve as precursor of the linker moiety of norcobamides that function as cofactors in the respiratory reductive dehalogenase. SMUL_1544 (SmCobD) is a pyridoxal‐5′‐phosphate (PLP)‐containing enzyme. The structural analysis of the SmCobD apoprotein combined with the characterization of truncated mutant proteins uncovered a role of the SmCobD N‐terminus in efficient l‐Ser‐P conversion.
KW  - cobamides
KW  - ethanolamine phosphate
KW  - norcobamide biosynthesis
KW  - serine phosphate decarboxylase
Y1  - 2019
U6  - https://doi.org/10.1002/1873-3468.13543
SN  - 0014-5793
SN  - 1873-3468
VL  - 593
IS  - 21
SP  - 3040
EP  - 3053
PB  - Wiley
CY  - Hoboken
ER  - 
TY  - JOUR
A1  - Freiberg, Alexander
A1  - Machner, M. P.
A1  - Pfeil, Wolfgang
A1  - Schubert, W. D.
A1  - Heinz, Dirk W.
A1  - Seckler, Robert
T1  - Folding and stability of the leucine-rich repeat domain of internalin B from Listeria monocytogenes
N2  - Internalin B (InlB), a surface protein of the human pathogen Listeria monocytogenes, promotes invasion into various host cell types by inducing phagocytosis of the entire bacterium. The N-terminal half of InlB (residues 36-321, InlB(321)), which is sufficient for this process, contains a central leucine-rich repeat (LRR) domain that is flanked by a small a-helical cap 2 and an immunoglobulin (Ig)-like domain. Here we investigated the variant lacking the Ig-like domain (lnlB(248)). The circular dichroism spectra of both protein variants in the far ultraviolet region are very similar, with a characteristic minimum found at similar to200 nm, possibly resulting from the high 3(10)-helical content in the LRR domain. Upon addition of chemical denaturants, both variants unfold in single transitions with unusually high cooperativity that are fully reversible and best described by two-state equilibria. The free energies of GdmCl-induced unfolding determined from transitions at 20degreesC are 9.9(+/- 0.8)kcal/mol for InlB(321) and 5.4(+/- 0.4) kcal/mol for InlB(248). InlB(321) is also more stable against thermal denaturation, as observed by scanning calorimetry. This suggests, that the Ig-like domain, which presumably does not directly interact with the host cell receptor during bacterial invasion, plays a critical role for the in vivo stability of InlB. (C) 2004 Elsevier Ltd. All rights reserved
Y1  - 2004
SN  - 0022-2836
ER  - 
TY  - JOUR
A1  - Vandewal, Koen
A1  - Albrecht, Steve
A1  - Hoke, Eric T.
A1  - Graham, Kenneth R.
A1  - Widmer, Johannes
A1  - Douglas, Jessica D.
A1  - Schubert, Marcel
A1  - Mateker, William R.
A1  - Bloking, Jason T.
A1  - Burkhard, George F.
A1  - Sellinger, Alan
A1  - Frechet, Jean M. J.
A1  - Amassian, Aram
A1  - Riede, Moritz K.
A1  - McGehee, Michael D.
A1  - Neher, Dieter
A1  - Salleo, Alberto
T1  - Efficient charge generation by relaxed charge-transfer states at organic interfaces
JF  - Nature materials
N2  - carriers on illumination. Efficient organic solar cells require a high yield for this process, combined with a minimum of energy losses. Here, we investigate the role of the lowest energy emissive interfacial charge-transfer state (CT1) in the charge generation process. We measure the quantum yield and the electric field dependence of charge generation on excitation of the charge-transfer (CT) state manifold viaweakly allowed, low-energy optical transitions. For a wide range of photovoltaic devices based on polymer: fullerene, small-molecule:C-60 and polymer: polymer blends, our study reveals that the internal quantum efficiency (IQE) is essentially independent of whether or not D, A or CT states with an energy higher than that of CT1 are excited. The best materials systems show an IQE higher than 90% without the need for excess electronic or vibrational energy.
Y1  - 2014
U6  - https://doi.org/10.1038/NMAT3807
SN  - 1476-1122
SN  - 1476-4660
VL  - 13
IS  - 1
SP  - 63
EP  - 68
PB  - Nature Publ. Group
CY  - London
ER  - 
TY  - GEN
A1  - Liu, W.
A1  - Tkachov, R.
A1  - Komber, H.
A1  - Senkovskyy, V.
A1  - Schubert, M.
A1  - Wei, Z.
A1  - Facchetti, A.
A1  - Neher, Dieter
A1  - Kiriy, A.
T1  - Chain-growth polycondensation of perylene diimide-based copolymers
BT  - a new route to regio-regular perylene diimide-based acceptors for all-polymer solar cells and n-type transistors
N2  - Herein, we report the chain-growth tin-free room temperature polymerization method to synthesize n-type perylene diimide-dithiophene-based conjugated polymers (PPDIT2s) suitable for solar cell and transistor applications. The palladium/electron-rich tri-tert-butylphosphine catalyst is effective to enable the chain-growth polymerization of anion-radical monomer Br-TPDIT-Br/Zn to PPDIT2 with a molecular weight up to Mw ≈ 50 kg mol−1 and moderate polydispersity. This is the second example of the polymerization of unusual anion-radical aromatic complexes formed in a reaction of active Zn and electron-deficient diimide-based aryl halides. As such, the discovered polymerization method is not a specific reactivity feature of the naphthalene-diimide derivatives but is rather a general polymerization tool. This is an important finding, given the significantly higher maximum external quantum efficiency that can be reached with PDI-based copolymers (32–45%) in all-polymer solar cells compared to NDI-based materials (15–30%). Our studies revealed that PPDIT2 synthesized by the new method and the previously published polymer prepared by step-growth Stille polycondensation show similar electron mobility and all-polymer solar cell performance. At the same time, the polymerization reported herein has several technological advantages as it proceeds relatively fast at room temperature and does not involve toxic tin-based compounds. Because several chain-growth polymerization reactions are well-suited for the preparation of well-defined multi-functional polymer architectures, the next target is to explore the utility of the discovered polymerization in the synthesis of end-functionalized polymers and block copolymers. Such materials would be helpful to improve the nanoscale morphology of polymer blends in all-polymer solar cells.
T3  - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 273 
Y1  - 2014
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-98724
ER  - 
TY  - JOUR
A1  - Sini, Gjergji
A1  - Schubert, Marcel
A1  - Risko, Chad
A1  - Roland, Steffen
A1  - Lee, Olivia P.
A1  - Chen, Zhihua
A1  - Richter, Thomas V.
A1  - Dolfen, Daniel
A1  - Coropceanu, Veaceslav
A1  - Ludwigs, Sabine
A1  - Scherf, Ullrich
A1  - Facchetti, Antonio
A1  - Frechet, Jean M. J.
A1  - Neher, Dieter
T1  - On the Molecular Origin of Charge Separation at the Donor-Acceptor Interface
JF  - Advanced energy materials
N2  - Fullerene-based acceptors have dominated organic solar cells for almost two decades. It is only within the last few years that alternative acceptors rival their dominance, introducing much more flexibility in the optoelectronic properties of these material blends. However, a fundamental physical understanding of the processes that drive charge separation at organic heterojunctions is still missing, but urgently needed to direct further material improvements. Here a combined experimental and theoretical approach is used to understand the intimate mechanisms by which molecular structure contributes to exciton dissociation, charge separation, and charge recombination at the donor-acceptor (D-A) interface. Model systems comprised of polythiophene-based donor and rylene diimide-based acceptor polymers are used and a detailed density functional theory (DFT) investigation is performed. The results point to the roles that geometric deformations and direct-contact intermolecular polarization play in establishing a driving force ( energy gradient) for the optoelectronic processes taking place at the interface. A substantial impact for this driving force is found to stem from polymer deformations at the interface, a finding that can clearly lead to new design approaches in the development of the next generation of conjugated polymers and small molecules.
KW  - donor-acceptor interfaces
KW  - energy gradients
KW  - geometrical deformations
KW  - nonfullerene acceptors
KW  - organic photovoltaics
KW  - photocurrent generation
KW  - polymer solar cells
Y1  - 2018
U6  - https://doi.org/10.1002/aenm.201702232
SN  - 1614-6832
SN  - 1614-6840
VL  - 8
IS  - 12
PB  - Wiley-VCH
CY  - Weinheim
ER  - 
TY  - JOUR
A1  - Liu, W.
A1  - Tkachov, R.
A1  - Komber, H.
A1  - Senkovskyy, V.
A1  - Schubert, M.
A1  - Wei, Z.
A1  - Facchetti, A.
A1  - Neher, Dieter
A1  - Kiriy, A.
T1  - Chain-growth polycondensation of perylene diimide-based copolymers: a new route to regio-regular perylene diimide-based acceptors for all-polymer solar cells and n-type transistors
JF  - Polymer Chemistry
N2  - Herein, we report the chain-growth tin-free room temperature polymerization method to synthesize n-type perylene diimide-dithiophene-based conjugated polymers (PPDIT2s) suitable for solar cell and transistor applications. The palladium/electron-rich tri-tert-butylphosphine catalyst is effective to enable the chain-growth polymerization of anion-radical monomer Br-TPDIT-Br/Zn to PPDIT2 with a molecular weight up to M-w approximate to 50 kg mol(-1) and moderate polydispersity. This is the second example of the polymerization of unusual anion-radical aromatic complexes formed in a reaction of active Zn and electron-deficient diimide-based aryl halides. As such, the discovered polymerization method is not a specific reactivity feature of the naphthalene-diimide derivatives but is rather a general polymerization tool. This is an important finding, given the significantly higher maximum external quantum efficiency that can be reached with PDI-based copolymers (32-45%) in all-polymer solar cells compared to NDI-based materials (15-30%). Our studies revealed that PPDIT2 synthesized by the new method and the previously published polymer prepared by step-growth Stille polycondensation show similar electron mobility and all-polymer solar cell performance. At the same time, the polymerization reported herein has several technological advantages as it proceeds relatively fast at room temperature and does not involve toxic tin-based compounds. Because several chain-growth polymerization reactions are well-suited for the preparation of well-defined multi-functional polymer architectures, the next target is to explore the utility of the discovered polymerization in the synthesis of end-functionalized polymers and block copolymers. Such materials would be helpful to improve the nanoscale morphology of polymer blends in all-polymer solar cells.
Y1  - 2014
U6  - https://doi.org/10.1039/c3py01707a
SN  - 1759-9954
SN  - 1759-9962
VL  - 5
IS  - 10
SP  - 3404
EP  - 3411
PB  - Royal Society of Chemistry
CY  - Cambridge
ER  - 
TY  - JOUR
A1  - Wei, Qing
A1  - Mühlhausen, D.
A1  - Schubert-Bischoff, P.
A1  - Macht, M.-P.
T1  - Kristallisation der massiven, amorphen Legierung Zr41Ti14Cu12,5Ni10Be22,5
Y1  - 1995
ER  -