TY  - JOUR
A1  - de Espinosa, Lucas Montero
A1  - Meier, Michael A. R.
A1  - Ronda, Juan C.
A1  - Galiß, Marina
A1  - Cßdiz, Virginia
T1  - Phosphorus-containing renewable polyester-polyols via ADMET polymerization : synthesis, functionalization, and radical crosslinking
N2  - An alpha,omega-diene containing hydroxyl groups was prepared from plant oil-derived platform chemicals. The acyclic diene metathesis copolymerization (ADMET) of this monomer with a phosphorus-containing alpha,omega-cliene (DOPO II), also plant oil derived, afforded a series of phosphorus containing linear polyesters, which have been fully characterized. The backbone hydroxyls of these polyesters have been acrylated and radically polymerized to produce crosslinked polymers. The thermomechanical and mechanical properties, the thermal stability, and the flame retardancy of these phosphorus-based thermosets have been studied. Moreover, methyl 10-undecenoate has been used as chain stopper in selected ADMET polymerizations to study the effect of the prepolymers' molecular weights on the different properties of the final materials.
Y1  - 2010
UR  - http://www3.interscience.wiley.com/journal/117932467/tocgroup
U6  - https://doi.org/10.1002/Pola.23887
SN  - 0887-624X
ER  - 
TY  - JOUR
A1  - de Espinosa, Lucas Montero
A1  - Meier, Michael A. R.
T1  - Synthesis of star- and block-copolymers using ADMET head-to-tail selectivity during step-growth polymerization
JF  - Chemical communications
N2  - Control over molecular architectures obtained via ADMET polymerization is limited by the step-growth nature of this technique. A new approach to this polycondensation method is described allowing for the synthesis of diblock and star-shaped polymers with molecular weight control by using the selectivity of olefin cross-metathesis between acrylates and terminal olefins.
Y1  - 2011
U6  - https://doi.org/10.1039/c0cc04161k
SN  - 1359-7345
VL  - 47
IS  - 6
SP  - 1908
EP  - 1910
PB  - Royal Society of Chemistry
CY  - Cambridge
ER  - 
TY  - JOUR
A1  - Mutlu, Hatice
A1  - de Espinosa, Lucas Montero
A1  - Meier, Michael A. R.
T1  - Acyclic diene metathesis a versatile tool for the construction of defined polymer architectures
JF  - Chemical Society reviews
N2  - Two decades have passed since the metathesis polymerisation of alpha,omega-dienes was successfully demonstrated by the group of Wagener and the term acyclic diene metathesis (ADMET) polymerisation was coined. Since then, the advances of metathesis chemistry have allowed to expand the scope of this versatile polymerisation reaction that nowadays finds applications in different fields, such as polymer, material, or medicinal chemistry. This critical review provides an insight into the historical aspects of ADMET and a detailed overview of the work done to date applying this versatile polymerisation reaction (221 references).
Y1  - 2011
U6  - https://doi.org/10.1039/b924852h
SN  - 0306-0012
VL  - 40
IS  - 3
SP  - 1404
EP  - 1445
PB  - Royal Society of Chemistry
CY  - Cambridge
ER  -