TY  - JOUR
A1  - Jay, Raphael M.
A1  - Eckert, Sebastian
A1  - Mitzner, Rolf
A1  - Fondell, Mattis
A1  - Föhlisch, Alexander
T1  - Quantitative evaluation of transient valence orbital occupations in a 3d transition metal complex as seen from the metal and ligand perspective
JF  - Chemical physics letters
N2  - It is demonstrated for the case of photo-excited ferrocyanide how time-resolved soft X-ray absorption spectroscopy in transmission geometry at the ligand K-edge and metal L-3-edge provides quantitatively equivalent valence electronic structure information, where signatures of photo-oxidation are assessed locally at the metal as well as the ligand. This allows for a direct and independent quantification of the number of photo-oxidized molecules at two soft X-ray absorption edges highlighting the sensitivity of X-ray absorption spectroscopy to the valence orbital occupation of 3d transition metal complexes throughout the soft X-ray range.
KW  - iron cyanides
KW  - photochemistry
KW  - soft X-ray absorption
Y1  - 2020
U6  - https://doi.org/10.1016/j.cplett.2020.137681
SN  - 0009-2614
SN  - 1873-4448
VL  - 754
PB  - Elsevier
CY  - Amsterdam
ER  -