TY - BOOK A1 - Hermanns, Jolanda A1 - Böhme, Katrin A1 - Meyering, Meike A1 - Fuchs, Isabelle A1 - Wagner, Simon A1 - Krauskopf, Karsten A1 - Knigge, Michel A1 - Rother, Stefanie A1 - Tosch, Frank A1 - Wendland, Mirko A1 - Wulff, Peter A1 - Mientus, Lukas A1 - Nowak, Anna A1 - Borowski, Andreas A1 - Baer, Ella A1 - Bosch, Jannis A1 - Wilbert, Jürgen A1 - Bräsel, Tim A1 - Fenn, Monika A1 - Kortenkamp, Ulrich A1 - Kuzle, Ana A1 - Reitz-Koncebovski, Karen A1 - Burg, Paula A1 - Lampart, Fabian A1 - Leubner, Martin A1 - Freitag-Hild, Britta A1 - Bitmann, Anna A1 - Reinhardt, Susanne A1 - Roos, Jana A1 - Hußner, Isabell A1 - Börner, Dustin A1 - Lazarides, Rebecca A1 - Glowinski, Ingrid A1 - Autenrieth, Marijke A1 - Radke, Thea A1 - Ehlert, Antje A1 - Menke, Anne A1 - Haupenthal, Anna A1 - Schramm, Satyam Antonio A1 - Kruse, Julia A1 - Körner, Dorothea A1 - Fischer, Jakob Thomas A1 - Kayser, Daniela Niesta ED - Hermanns, Jolanda T1 - PSI-Potsdam BT - Ergebnisbericht zu den Aktivitäten im Rahmen der Qualitätsoffensive Lehrerbildung (2019-2023) T3 - Potsdamer Beiträge für Lehrkräftebildung und Bildungsforschung N2 - An der Universität Potsdam wird seit 2015 im Rahmen der „Qualitätsoffensive Lehrerbildung“ das Projekt „Professionalisierung – Schulpraktische Studien – Inklusion“ (PSI-Potsdam) durchgeführt und am Zentrum für Lehrerbildung und Bildungsforschung (ZeLB) koordiniert. Zur ersten Projektförderphase (2015-2018) erschien der Band „PSI-Potsdam – Ergebnisbericht zu den Aktivitäten im Rahmen der Qualitätsoffensive Lehrerbildung (2015-2018)“ zum Auftakt der Reihe „Potsdamer Beiträge zur Lehrerbildung und Bildungsforschung“. Der vorliegende Band aus der gleichen Reihe gibt in den Kapiteln „Erhebungen“, „Lehrkonzepte“ und „Vernetzungen“ einen Überblick über alle Teilprojekte der zweiten Projektförderphase (2019-2023). Wissenschaftler:innen aus verschiedenen Fachdidaktiken, Fachwissenschaften sowie aus den Bildungswissenschaften und der Inklusionspädagogik haben im Rahmen des Projektes kooperiert. Sowohl praxisnahe Forschung als auch die Entwicklung neuer Lehrkonzepte sowie Strategien zur Vernetzung innerhalb der Lehrkräftebildung stehen im Fokus dieses Bandes. Die Praxisphasen, die im Rahmen des „Potsdamer Modells der Lehrerbildung“ eine zentrale Rolle spielen, wurden in einer großen Studie über alle Praxisphasen untersucht. Der Band gibt interessante Einblicke in die Ergebnisse der Teilprojekte und Anregungen sowohl für die eigene Forschung als auch für Entwicklungsarbeit wie zum Beispiel die Entwicklung neuer Lehrkonzepte. Herausgegeben wird dieser Band von PD Dr. Jolanda Hermanns (Gesamtkoordinatorin PSI-Potsdam und Chemiedidaktikerin). T3 - Potsdamer Beiträge zur Lehrkräftebildung und Bildungsforschung - 3 KW - Lehrerbildung KW - Evaluation KW - Testinstrumente KW - Konzepte KW - Vernetzung KW - teacher education KW - evaluation KW - test instruments KW - concepts KW - networking Y1 - 2023 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-601875 SN - 978-3-86956-568-2 SN - 2626-3556 SN - 2626-4722 IS - 3 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - JOUR A1 - Khattari, Z. A1 - Ruschel, Y. A1 - Wen, H. Z. A1 - Fischer, Anna A1 - Fischer, T. M. T1 - Compactification of a myelin mimetic Langmuir monolayer upon adsorption and unfolding of myelin basic protein N2 - The surface shear viscosity of a myelin mimetic Langmuir monolayer is investigated upon adsorption of myelin basic protein (MBP). We measure an increase of the surface shear viscosity at picomolar concentrations of the protein, suggesting that the globular conformation of MBP changes upon adsorption at the monolayer. The conformational change enables hydrodynamic interactions of the proteins, with a typical separation of hundreds of nanometers. This unfolding is essential for the compactification of the myelin sheath, serving an enhanced saltatory signal transduction in vertebrates. The viscometry used extends the sensitivity of standard surface viscometers toward lower viscosities Y1 - 2005 SN - 1520-6106 ER - TY - CHAP A1 - Fischer, Martin H. A1 - Matheja, Anna T1 - Grenzüberschreitungen in der Kognition BT - Wahrnehmung, Denken und Handeln T2 - Grenzen im Fokus der Wissenschaften Y1 - 2016 SP - 197 EP - 212 PB - Trafo CY - Berlin ER - TY - BOOK A1 - Klose, Dagmar A1 - Klostermann, Anke A1 - Engelmann, Anna-Maria A1 - Jeltsch, Gesche A1 - Dowall, Kathrin A1 - Meyer, Georg A1 - Glados, Andrea A1 - Fischer, Raul A1 - Hoffmann, Katrin A1 - Kaiser, Christoph A1 - Ladewig, Marco A1 - Skouras, Andreas A1 - Wienert, Christian A1 - Wilkening, Gregor A1 - Klaudius, Mathias A1 - Goldbeck, Johanna A1 - Duch, Sven A1 - Werfel, Claudia A1 - Viebig, Wenke A1 - Neumann, Katharina A1 - Dammnik, Sabine ED - Klose, Dagmar T1 - Antike so fern und doch so nah N2 - Historisches Denken entwickeln am Gegenstand der altorientalischen,griechischen und römischen Antike, das ist Anliegen der didaktischen Handreichung für die gymnasiale Oberstufe. Didaktisch-methodische Überlegungen, Sachinformationen und ein handlungsorientierter Materialteil bieten für Lehrer und Schüler ein ideenreiches Angebot zur Auswahl für einen interessegeleiteten Geschichtsunterricht. T3 - Perspektiven historischen Denkens und Lernens - 2 KW - Historisches Denken KW - Antike KW - Handlungsorientierung KW - Geschichtsunterricht in der gymnasialen Oberstufe Y1 - 2006 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-11179 SN - 978-3-939469-37-7 ER - TY - JOUR A1 - Neumann, Bettina A1 - Kielb, Patrycja A1 - Rustam, Lina A1 - Fischer, Anna A1 - Weidinger, Inez M. A1 - Wollenberger, Ulla T1 - Bioelectrocatalytic Reduction of Hydrogen Peroxide by Microperoxidase-11 Immobilized on Mesoporous Antimony-Doped Tin Oxide JF - ChemElectrChem N2 - The heme-undecapeptide microperoxidase-11 (MP-11) was immobilized on mesoporous antimony-doped tin oxide (ATO) thin-film electrodes modified with the positively charged binding promotor polydiallyldimethylammonium chloride. Surface concentrations of MP-11 of 1.5 nmol cm(-2) were sufficiently high to enable spectroelectrochemical analyses. UV/Vis spectroscopy and resonance Raman spectroscopy revealed that immobilized MP-11 adopts a six-coordinated low-spin conformation, as in solution in the presence of a polycation. Cathodic reduction of hydrogen peroxide at potentials close to +500mV versus Ag/AgCl indicates that the reaction proceeds via a Compound I-type like intermediate, analogous to natural peroxidases, and confirms mesoporous ATO as a suitable host material for adsorbing the heme-peptide in its native state. A hydrogen peroxide sensor is proposed by using the bioelectrocatalytic properties of the MP-11-modified ATO. KW - electrochemistry KW - enzyme catalysis KW - mesoporous materials KW - microperoxidase KW - spectroelectrochemistry Y1 - 2017 U6 - https://doi.org/10.1002/celc.201600776 SN - 2196-0216 VL - 4 IS - 4 SP - 913 EP - 919 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Hetenyi, Gyorgy A1 - Molinari, Irene A1 - Clinton, John A1 - Bokelmann, Gotz A1 - Bondar, Istvan A1 - Crawford, Wayne C. A1 - Dessa, Jean-Xavier A1 - Doubre, Cecile A1 - Friederich, Wolfgang A1 - Fuchs, Florian A1 - Giardini, Domenico A1 - Graczer, Zoltan A1 - Handy, Mark R. A1 - Herak, Marijan A1 - Jia, Yan A1 - Kissling, Edi A1 - Kopp, Heidrun A1 - Korn, Michael A1 - Margheriti, Lucia A1 - Meier, Thomas A1 - Mucciarelli, Marco A1 - Paul, Anne A1 - Pesaresi, Damiano A1 - Piromallo, Claudia A1 - Plenefisch, Thomas A1 - Plomerova, Jaroslava A1 - Ritter, Joachim A1 - Rumpker, Georg A1 - Sipka, Vesna A1 - Spallarossa, Daniele A1 - Thomas, Christine A1 - Tilmann, Frederik A1 - Wassermann, Joachim A1 - Weber, Michael A1 - Weber, Zoltan A1 - Wesztergom, Viktor A1 - Zivcic, Mladen A1 - Abreu, Rafael A1 - Allegretti, Ivo A1 - Apoloner, Maria-Theresia A1 - Aubert, Coralie A1 - Besancon, Simon A1 - de Berc, Maxime Bes A1 - Brunel, Didier A1 - Capello, Marco A1 - Carman, Martina A1 - Cavaliere, Adriano A1 - Cheze, Jerome A1 - Chiarabba, Claudio A1 - Cougoulat, Glenn A1 - Cristiano, Luigia A1 - Czifra, Tibor A1 - Danesi, Stefania A1 - Daniel, Romuald A1 - Dannowski, Anke A1 - Dasovic, Iva A1 - Deschamps, Anne A1 - Egdorf, Sven A1 - Fiket, Tomislav A1 - Fischer, Kasper A1 - Funke, Sigward A1 - Govoni, Aladino A1 - Groschl, Gidera A1 - Heimers, Stefan A1 - Heit, Ben A1 - Herak, Davorka A1 - Huber, Johann A1 - Jaric, Dejan A1 - Jedlicka, Petr A1 - Jund, Helene A1 - Klingen, Stefan A1 - Klotz, Bernhard A1 - Kolinsky, Petr A1 - Kotek, Josef A1 - Kuhne, Lothar A1 - Kuk, Kreso A1 - Lange, Dietrich A1 - Loos, Jurgen A1 - Lovati, Sara A1 - Malengros, Deny A1 - Maron, Christophe A1 - Martin, Xavier A1 - Massa, Marco A1 - Mazzarini, Francesco A1 - Metral, Laurent A1 - Moretti, Milena A1 - Munzarova, Helena A1 - Nardi, Anna A1 - Pahor, Jurij A1 - Pequegnat, Catherine A1 - Petersen, Florian A1 - Piccinini, Davide A1 - Pondrelli, Silvia A1 - Prevolnik, Snjezan A1 - Racine, Roman A1 - Regnier, Marc A1 - Reiss, Miriam A1 - Salimbeni, Simone A1 - Santulin, Marco A1 - Scherer, Werner A1 - Schippkus, Sven A1 - Schulte-Kortnack, Detlef A1 - Solarino, Stefano A1 - Spieker, Kathrin A1 - Stipcevic, Josip A1 - Strollo, Angelo A1 - Sule, Balint A1 - Szanyi, Gyongyver A1 - Szucs, Eszter A1 - Thorwart, Martin A1 - Ueding, Stefan A1 - Vallocchia, Massimiliano A1 - Vecsey, Ludek A1 - Voigt, Rene A1 - Weidle, Christian A1 - Weyland, Gauthier A1 - Wiemer, Stefan A1 - Wolf, Felix A1 - Wolyniec, David A1 - Zieke, Thomas T1 - The AlpArray seismic network BT - a large-scale european experiment to image the alpine orogen JF - Surveys in Geophysics N2 - The AlpArray programme is a multinational, European consortium to advance our understanding of orogenesis and its relationship to mantle dynamics, plate reorganizations, surface processes and seismic hazard in the Alps-Apennines-Carpathians-Dinarides orogenic system. The AlpArray Seismic Network has been deployed with contributions from 36 institutions from 11 countries to map physical properties of the lithosphere and asthenosphere in 3D and thus to obtain new, high-resolution geophysical images of structures from the surface down to the base of the mantle transition zone. With over 600 broadband stations operated for 2 years, this seismic experiment is one of the largest simultaneously operated seismological networks in the academic domain, employing hexagonal coverage with station spacing at less than 52 km. This dense and regularly spaced experiment is made possible by the coordinated coeval deployment of temporary stations from numerous national pools, including ocean-bottom seismometers, which were funded by different national agencies. They combine with permanent networks, which also required the cooperation of many different operators. Together these stations ultimately fill coverage gaps. Following a short overview of previous large-scale seismological experiments in the Alpine region, we here present the goals, construction, deployment, characteristics and data management of the AlpArray Seismic Network, which will provide data that is expected to be unprecedented in quality to image the complex Alpine mountains at depth. KW - Seismology KW - Alps KW - Seismic network KW - Geodynamics KW - Seismic imaging KW - Mountain building Y1 - 2018 U6 - https://doi.org/10.1007/s10712-018-9472-4 SN - 0169-3298 SN - 1573-0956 VL - 39 IS - 5 SP - 1009 EP - 1033 PB - Springer CY - Dordrecht ER - TY - JOUR A1 - Guiet, Amandine A1 - Goebel, Caren A1 - Klingan, Katharina A1 - Lublow, Michael A1 - Reier, Tobias A1 - Vainio, Ulla A1 - Kraehnert, Ralph A1 - Schlaad, Helmut A1 - Strasser, Peter A1 - Zaharieva, Ivelina A1 - Dau, Holger A1 - Driess, Matthias A1 - Polte, Joerg A1 - Fischer, Anna T1 - Hydrophobic Nanoreactor Soft-Templating: A Supramolecular Approach to Yolk@Shell Materials JF - Advanced functional materials N2 - Due to their unique morphology-related properties, yolk@shell materials are promising materials for catalysis, drug delivery, energy conversion, and storage. Despite their proven potential, large-scale applications are however limited due to demanding synthesis protocols. Overcoming these limitations, a simple soft-templated approach for the one-pot synthesis of yolk@shell nanocomposites and in particular of multicore metal nanoparticle@metal oxide nanostructures (M-NP@MOx) is introduced. The approach here, as demonstrated for Au-NP@ITOTR (ITOTR standing for tin-rich ITO), relies on polystyrene-block-poly(4-vinylpyridine) (PS-b-P4VP) inverse micelles as two compartment nanoreactor templates. While the hydrophilic P4VP core incorporates the hydrophilic metal precursor, the hydrophobic PS corona takes up the hydrophobic metal oxide precursor. As a result, interfacial reactions between the precursors can take place, leading to the formation of yolk@shell structures in solution. Once calcined these micelles yield Au-NP@ITOTR nanostructures, composed of multiple 6 nm sized Au NPs strongly anchored onto the inner surface of porous 35 nm sized ITOTR hollow spheres. Although of multicore nature, only limited sintering of the metal nanoparticles is observed at high temperatures (700 degrees C). In addition, the as-synthesized yolk@shell structures exhibit high and stable activity toward CO electrooxidation, thus demonstrating the applicability of our approach for the design of functional yolk@shell nanocatalysts. KW - inverse micelles KW - nanoreactor KW - polystyrene-block-poly(4-vinylpyridine) KW - soft-templating KW - tin-rich ITO KW - yolk@shell materials Y1 - 2015 U6 - https://doi.org/10.1002/adfm.201502388 SN - 1616-301X SN - 1616-3028 VL - 25 IS - 39 SP - 6228 EP - 6240 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Guiet, Amandine A1 - Unmüssig, Tobias A1 - Göbel, Caren A1 - Vainio, Ulla A1 - Wollgarten, Markus A1 - Driess, Matthias A1 - Schlaad, Helmut A1 - Polte, Jörg A1 - Fischer, Anna T1 - Yolk@Shell Nanoarchitectures with Bimetallic Nanocores - Synthesis and Electrocatalytic Applications JF - Earth & planetary science letters KW - AgAu alloy nanoparticles KW - tin-rich ITO KW - yolk@shell materials KW - nanoreactor KW - soft-templating KW - inverse micelles KW - polystyrene-block-poly(4-vinylpyridine) Y1 - 2016 U6 - https://doi.org/10.1021/acsami.6b06595 SN - 1944-8244 VL - 8 SP - 28019 EP - 28029 PB - American Chemical Society CY - Washington ER - TY - THES A1 - Fischer, Anna T1 - "Reactive hard templating" : from carbon nitrides to metal nitrides T1 - Synthese von Metallnitrid Nanostrukturen durch "Reaktives Hardtemplating" N2 - Nanostructured inorganic materials are routinely synthesized by the use of templates. Depending on the synthesis conditions of the product material, either “soft” or “hard” templates can be applied. For sol-gel processes, usually “soft” templating techniques are employed, while “hard” templates are used for high temperature synthesis pathways. In classical templating approaches, the template has the unique role of structure directing agent, in the sense that it is not participating to the chemical formation of the resulting material. This work investigates a new templating pathway to nanostructured materials, where the template is also a reagent in the formation of the final material. This concept is described as “reactive templating” and opens a synthetic path toward materials which cannot be synthesised on a nanometre scale by classical templating approaches. Metal nitrides are such kind of materials. They are usually produced by the conversion of metals or metal oxides in ammonia flow at high temperature (T > 1000°C), which make the application of classical templating techniques difficult. Graphitic carbon nitride, g-C3N4, despite its fundamental and theoretical importance, is probably one of the most promising materials to complement carbon in material science and many efforts are put in the synthesis of this material. A simple polyaddition/elimination reaction path at high temperature (T = 550°C) allows the polymerisation of cyanamide toward graphitic carbon nitride solids. By hard templating, using nanostructured silica or aluminium oxide as nanotemplates, a variety of nanostructured graphitic carbon nitrides such as nanorods, nanotubes, meso- and macroporous powders could be obtained by nanocasting or nanocoating. Due to the special semi-conducting properties of the graphitic carbon nitride matrix, the nanostructured graphitic carbon nitrides show unexpected catalytic activity for the activation of benzene in Friedel-Crafts type reactions, making this material an interesting metal free catalyst. Furthermore, due to the chemical composition of g-C3N4 and the fact that it is totally decomposed at temperatures between 600°C and 800°C even under inert atmosphere, g-C3N4 was shown to be a good nitrogen donor for the synthesis of early transition metal nitrides at high temperatures. Thus using the nanostructured carbon nitrides as “reactive templates” or “nanoreactors”, various metal nitride nanostructures, such as nanoparticles and porous frameworks could be obtained at high temperature. In this approach the carbon nitride nanostructure played both the role of the nitrogen source and of the exotemplate, imprinting its size and shape to the resulting metal nitride nanostructure. N2 - Die Nanostrukturierung anorganischer Materialien, d.h. die Kontrolle ihrer Form und Größe auf der Nanometerebene durch unterschiedliche Herstellungsverfahren, ist ein sich immer noch erweiterndes Forschungsgebiet. Eine solche Nanostrukturierung wird oft über sogenannte Templatierungsverfahren erreicht: Hier werden Formgeber (Template) mit definierter Morphologie und Größe verwendet und deren Struktur in ein neues Material abgebildet. Templatierungsverfahren können, je nach der Beschaffenheit des Templats, zwischen „weich“ und „hart“ unterschieden werden. Die Begriffe beziehen sich dabei vor allem auf die mechanische und thermische Stabilität der Template, d.h. weiche Template sind vornehmlich organischer, harte Template anorganischer Natur. Wo weiche Template in milden chemischen Verfahren eingesetzt werden, werden harte Template zur Herstellung von Materialien bei Hochtemperaturverfahren verwendet (z. B. poröse Kohlenstoffe). Allgemein dienen Template ausschließlich als Strukturgeber und gehen in keiner Weise in Form einer chemischen Reaktion in die Synthese des gewünschten Materials mit ein. Gegenstand dieser Arbeit ist ein neues Templatierungsverfahren: Die „reaktive Templatierung“. Hierbei wird das Templat - neben seiner Funktion als Strukturgeber – auch als Reagenz für die Synthese des Produktes verwendet. Dieser Synthese-Ansatz öffnet damit neue Wege für die Synthese von nanostrukturierten Materialien, die durch klassische Templatierungsansätze schwer zugänglich sind. Hierzu zählen zum Beispiel die Metallnitride. Üblicherweise werden Metallnitride über die Umsetzung von Metallen oder Metalloxiden in einem Ammoniakstrom bei Mindesttemperaturen von 1000°C gewonnen, was die Anwendung klassischer Templatierungsverfahren beinahe unmöglich macht. Darüber hinaus sind konzentrierte Lauge oder Flusssäure, welche zur Entfernung klassischer harter Template benötigt werden auch Aufschlussmittel für Metallnitride. Graphitisches Kohlenstoffnitrid, g-C3N4, ist wohl eines der meistversprechendsten Materialien um Kohlenstoff in der Materialwissenschaft zu ergänzen. Es wurden bereits viele potentielle Syntheseansätze beschrieben. Eine durch Groenewolt M. erstellte Route ist die thermisch induzierte Polykondensation von Cyanamid (NCNH2) bei 550°C. Da g-C3N4 sich zwischen 600°C und 800°C vollständig in NH3 und CxNyH-Gase zersetzt, ist es eine geeignete Festkörper-Stickstoffquelle für die Herstellung von Metalnitriden. Daher boten sich nanostrukturierte graphitische Kohlenstoffnitride als geeignete reaktive Template oder Nanoreaktoren zur Herstellung von nano-strukturierten Metalnitriden an. Die Templatierung der g-C3N4-Matrix wurde über klassische Harttemplatierungsverfahren erreicht. So konnte eine Vielzahl nano-strukturierter g-C3N4 Materialien synthetisiert werden wie zum Beispiel Nanostäbchen, Nanoröhren, mesoporöse oder makroporöse graphitische Kohlenstoffnitride. Diese haben sich interessanterweise, als metalfreie Katalysatoren für die Aktivierung von Benzol in Friedel-Crafts-Acylierung und -Alkylierung erwiesen. Durch die Infiltrierung der nano-strukturierten g-C3N4-Materialien mit diversen Metal-Präkursoren und nachfolgendem Tempern bei 800°C unter Schutzgas, konnten entsprechende nano-strukturierte Metalnitride, als Nanoabdrücke der vorgegebenen Kohlenstoffnitrid Nanostrukturen hergestellt werden. So konnten TiN, VN, GaN, AlGaN und TiVN Nanopartikel synthetisiert werden, macroporöse TiN/Kohlenstoff Komposite sowie TiN Hohlkugeln. Die so hergestellten Materialien erwiesen sich als effektive basische Katalysatoren für Aldol-Kondensations Reaktionen. KW - Kohlenstoffnitride KW - Metallnitride KW - nano KW - Templatierung KW - Carbonitrides KW - metal nitrides KW - reactive templating KW - confinement KW - nano Y1 - 2008 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-19777 ER - TY - JOUR A1 - Frasca, Stefano A1 - Milan, Anabel Molero A1 - Guiet, Amandine A1 - Goebel, Caren A1 - Perez-Caballero, Fernando A1 - Stiba, Konstanze A1 - Leimkühler, Silke A1 - Fischer, Anna A1 - Wollenberger, Ursula T1 - Bioelectrocatalysis at mesoporous antimony doped tin oxide electrodes-Electrochemical characterization and direct enzyme communication JF - ELECTROCHIMICA ACTA N2 - In this paper we report immobilization and bioelectrocatalysis of human sulfite oxidase (hSO) on nanostructured antimony doped tin oxide (ATO) thin film electrodes. Two types of ATO thin film electrodes were prepared via evaporation induced self-assembly of ATO nanoparticle sols. The use of a porogen results in different porosity and film thickness. Nevertheless both electrode types reveal similar quasi reversible electrochemical behavior for positive and negatively charged small mediators. Facile and durable immobilization of catalytically active enzyme in a direct electron transfer configuration was achieved without further chemical modification of the ATO surfaces. Interestingly, the binding of hSO onto the ATO surface seems to be not only of electrostatic nature, but also originates from a strong interaction between the histidine-tag of the enzyme and the supporting material. This is suggested from stable sulfite dependent bioelectrocatalytic signals at high ionic strength and imidazole desorption experiments. As such, ATO appears as a promising conductive platform for the immobilization of complex enzymes and their application in bioelectrocatalysis. (C) 2013 Elsevier Ltd. All rights reserved. KW - Antimony doped tin dioxide KW - Sulfite oxidase KW - Direct electrochemistry KW - Biosensor KW - Bioelectrocatalysis Y1 - 2013 U6 - https://doi.org/10.1016/j.electacta.2013.03.144 SN - 0013-4686 SN - 1873-3859 VL - 110 IS - 2 SP - 172 EP - 180 PB - PERGAMON-ELSEVIER SCIENCE LTD CY - OXFORD ER - TY - JOUR A1 - Sivanesan, Arumugam A1 - Kalaivani, Govindasamy A1 - Fischer, Anna A1 - Stiba, Konstanze A1 - Leimkühler, Silke A1 - Weidinger, Inez M. T1 - Complementary surface-enhanced resonance raman Spectroscopic Biodetection of mixed protein solutions by Chitosan- and Silica-Coated Plasmon-Tuned Silver Nanoparticles JF - Analytical chemistry N2 - Silver nanoparticles with identical plasmonic properties but different surface functionalities are synthesized and tested as chemically selective surface-enhanced resonance Raman (SERR) amplifiers in a two-component protein solution. The surface plasmon resonances of the particles are tuned to 413 nm to match the molecular resonance of protein heme cofactors. Biocompatible functionalization of the nanoparticles with a thin film of chitosan yields selective SERR enhancement of the anionic protein cytochrome b(5), whereas functionalization with SiO2 amplifies only the spectra of the cationic protein cytochrome c. As a result, subsequent addition of the two differently functionalized particles yields complementary information on the same mixed protein sample solution. Finally, the applicability of chitosan-coated Ag nanoparticles for protein separation was tested by in situ resonance Raman spectroscopy. Y1 - 2012 U6 - https://doi.org/10.1021/ac301001a SN - 0003-2700 VL - 84 IS - 13 SP - 5759 EP - 5764 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Yarman, Aysu A1 - Nagel, Thomas A1 - Gajovic-Eichelmann, Nenad A1 - Fischer, Anna A1 - Wollenberger, Ursula A1 - Scheller, Frieder W. T1 - Bioelectrocatalysis by Microperoxidase-11 in a Multilayer Architecture of Chitosan Embedded Gold Nanoparticles JF - Electroanalysis : an international journal devoted to fundamental and practical aspects of electroanalysis N2 - We report on the redox behaviour of the microperoxidase-11 (MP-11) which has been electrostatically immobilized in a matrix of chitosan-embedded gold nanoparticles on the surface of a glassy carbon electrode. MP-11 contains a covalently bound heme c as the redox active group that exchanges electrons with the electrode via the gold nanoparticles. Electroactive surface concentration of MP-11 at high scan rate is between 350+/-50 pmol cm(-2), which reflects a multilayer process. The formal potential (E degrees') of MP-11 in the gold nanoparticles-chitosan film was estimated to be -(267.7+/-2.9) mV at pH 7.0. The heterogeneous electron transfer rate constant (k(s)) starts at 1.21 s(-1) and levels off at 6.45 s(-1) in the scan rate range from 0.1 to 2.0 V s(-1). Oxidation and reduction of MP-11 by hydrogen peroxide and superoxide, respectively have been coupled to the direct electron transfer of MP-11. KW - Microperoxidase KW - Direct electron transfer KW - Nanoparticles KW - Hydrogen peroxide KW - Superoxide KW - Bioelectrocatalysis Y1 - 2011 U6 - https://doi.org/10.1002/elan.201000535 SN - 1040-0397 VL - 23 IS - 3 SP - 611 EP - 618 PB - Wiley-Blackwell CY - Malden ER - TY - JOUR A1 - Fischer, Anna S. T1 - Horomedon und Laokoon BT - Raum und Zeit in plastischer Kunst und Poesie bei Maksimilian A. Vološin und Gotthold Ephraim Lessing JF - Texturen – Identitäten – Theorien : Ergebnisse des Arbeitstreffens des Jungen Forums Slavistische Literaturwissenschaft in Trier 2010 N2 - - Horomedon - Laokoon - Raum und Zeit - Plastische Künste - Fazit Y1 - 2011 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-58976 SP - 425 EP - 441 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - GEN A1 - Borghi, Anna M. A1 - Shaki, Samuel A1 - Fischer, Martin H. T1 - Concrete constraints on abstract concepts-editorial T2 - Psychological research : an international journal of perception, attention, memory, and action N2 - This special issue, "Concrete constraints of abstract concepts", addresses the role of concrete determinants, both external and internal to the human body, in acquisition, processing and use of abstract concepts while at the same time presenting to the readers an overview of methods used to assess their representation. Y1 - 2022 U6 - https://doi.org/10.1007/s00426-022-01685-9 SN - 0340-0727 SN - 1430-2772 VL - 86 SP - 2366 EP - 2369 PB - Springer CY - Heidelberg ER - TY - JOUR A1 - Borghi, Anna M. A1 - Shaki, Samuel A1 - Fischer, Martin H. T1 - Abstract concepts: external influences, internal constraints, and methodological issues JF - Psychological research : an international journal of perception, attention, memory, and action N2 - There is a longstanding and widely held misconception about the relative remoteness of abstract concepts from concrete experiences. This review examines the current evidence for external influences and internal constraints on the processing, representation, and use of abstract concepts, like truth, friendship, and number. We highlight the theoretical benefit of distinguishing between grounded and embodied cognition and then ask which roles do perception, action, language, and social interaction play in acquiring, representing and using abstract concepts. By reviewing several studies, we show that they are, against the accepted definition, not detached from perception and action. Focussing on magnitude-related concepts, we also discuss evidence for cultural influences on abstract knowledge and explore how internal processes such as inner speech, metacognition, and inner bodily signals (interoception) influence the acquisition and retrieval of abstract knowledge. Finally, we discuss some methodological developments. Specifically, we focus on the importance of studies that investigate the time course of conceptual processing and we argue that, because of the paramount role of sociality for abstract concepts, new methods are necessary to study concepts in interactive situations. We conclude that bodily, linguistic, and social constraints provide important theoretical limitations for our theories of conceptual knowledge. Y1 - 2022 U6 - https://doi.org/10.1007/s00426-022-01698-4 SN - 0340-0727 SN - 1430-2772 VL - 86 SP - 2370 EP - 2388 PB - Springer CY - Heidelberg ER -