TY - JOUR A1 - Blanchard, Ingrid A1 - Abeykoon, Sumith A1 - Frost, Daniel J. A1 - Rubie, David C. T1 - Sulfur content at sulfide saturation of peridotitic melt at upper mantle conditions JF - American mineralogist : an international journal of earth and planetary materials / Mineralogical Society of America N2 - The concentration of sulfur that can be dissolved in a silicate liquid is of fundamental importance because it is closely associated with several major Earth-related processes. Considerable effort has been made to understand the interplay between the effects of silicate melt composition and its capac-ity to retain sulfur, but the dependence on pressure and temperature is mostly based on experiments performed at pressures and temperatures below 6 GPa and 2073 K. Here we present a study of the effects of pressure and temperature on sulfur content at sulfide saturation of a peridotitic liquid. We performed 14 multi-anvil experiments using a peridotitic starting composition, and we produced 25 new measurements at conditions ranging from 7 to 23 GPa and 2173 to 2623 K. We analyzed the recovered samples using both electron microprobe and laser ablation ICP-MS. We compiled our data together with previously published data that were obtained at lower P-T conditions and with various silicate melt compositions. We present a new model based on this combined data set that encompasses the entire range of upper mantle pressure-temperature conditions, along with the effect of a wide range of silicate melt compositions. Our findings are consistent with earlier work based on extrapolation from lower-pressure and lower-temperature experiments and show a decrease of sulfur content at sulfide saturation (SCSS) with increasing pressure and an increase of SCSS with increasing temperature. We have extrapolated our results to pressure-temperature conditions of the Earth's primitive magma ocean, and show that FeS will exsolve from the molten silicate and can effectively be extracted to the core by a process that has been termed the "Hadean Matte." We also discuss briefly the implications of our results for the lunar magma ocean. KW - Peridotitic melts KW - sulfur solubility KW - high pressure KW - high temperature KW - magma ocean Y1 - 2021 U6 - https://doi.org/10.2138/am-2021-7649 SN - 0003-004X SN - 1945-3027 VL - 106 IS - 11 SP - 1835 EP - 1843 PB - Mineralogical Society of America CY - Washington, DC [u.a.] ER - TY - JOUR A1 - Hosseinzadeh, Griffin A1 - Cowperthwaite, Philip S. A1 - Gomez, Sebastian A1 - Villar, Victoria Ashley A1 - Nicholl, Matt A1 - Margutti, Raffaella A1 - Berger, Edo A1 - Chornock, Ryan A1 - Paterson, Kerry A1 - Fong, Wen-fai A1 - Savchenko, Volodymyr A1 - Short, Phil A1 - Alexander, Kate D. A1 - Blanchard, Peter K. A1 - Braga, Joao A1 - Calkins, Michael L. A1 - Cartier, Regis A1 - Coppejans, Deanne L. A1 - Eftekhari, Tarraneh A1 - Laskar, Tanmoy A1 - Ly, Chun A1 - Patton, Locke A1 - Pelisoli, Ingrid Domingos A1 - Reichart, Daniel E. A1 - Terreran, Giacomo A1 - Williams, Peter K. G. T1 - Follow-up of the Neutron Star Bearing Gravitational-wave Candidate Events S190425z and S190426c with MMT and SOAR JF - The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters N2 - On 2019 April 25.346 and 26.640 UT the Laser Interferometer Gravitational-Wave Observatory (LIGO) and Virgo gravitational-wave (GW) observatory announced the detection of the first candidate events in Observing Run 3 that contained at least one neutron star (NS). S190425z is a likely binary neutron star (BNS) merger at d(L) = 156 +/- 41 Mpc, while S190426c is possibly the first NS-black hole (BH) merger ever detected, at d(L) = 377 +/- 100 Mpc, although with marginal statistical significance. Here we report our optical follow-up observations for both events using the MMT 6.5 m telescope, as well as our spectroscopic follow-up of candidate counterparts (which turned out to be unrelated) with the 4.1 m SOAR telescope. We compare to publicly reported searches, explore the overall areal coverage and depth, and evaluate those in relation to the optical/near-infrared (NIR) kilonova emission from the BNS merger GW170817, to theoretical kilonova models, and to short gamma-ray burst (SGRB) afterglows. We find that for a GW170817-like kilonova, the partial volume covered spans up to about 40% for S190425z and 60% for S190426c. For an on-axis jet typical of SGRBs, the search effective volume is larger, but such a configuration is expected in at most a few percent of mergers. We further find that wide-field gamma-ray and X-ray limits rule out luminous on-axis SGRBs, for a large fraction of the localization regions, although these searches are not sufficiently deep in the context of the gamma-ray emission from GW170817 or off-axis SGRB afterglows. The results indicate that some optical follow-up searches are sufficiently deep for counterpart identification to about 300 Mpc, but that localizations better than 1000 deg(2) are likely essential. KW - binaries: close KW - gravitational waves KW - methods: observational KW - stars: black holes KW - stars: neutron Y1 - 2019 U6 - https://doi.org/10.3847/2041-8213/ab271c SN - 2041-8205 SN - 2041-8213 VL - 880 IS - 1 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Blanchard, Ingrid A1 - Petitgirard, Sylvain A1 - Laurenz, Vera A1 - Miyajima, Nobuyoshi A1 - Wilke, Max A1 - Rubie, David C. A1 - Lobanov, Sergey S. A1 - Hennet, Louis A1 - Morgenroth, Wolfgang A1 - Tucoulou, Rémi A1 - Bonino, Valentina A1 - Zhao, Xuchao A1 - Franchi, Ian T1 - Chemical analysis of trace elements at the nanoscale in samples recovered from laser-heated diamond anvil cell experiments JF - Physics and chemistry of minerals N2 - High pressure and high temperature experiments performed with laser-heated diamond anvil cells (LH-DAC) are being extensively used in geosciences to study matter at conditions prevailing in planetary interiors. Due to the size of the apparatus itself, the samples that are produced are extremely small, on the order of few tens of micrometers. There are several ways to analyze the samples and extract physical, chemical or structural information, using either in situ or ex situ methods. In this paper, we compare two nanoprobe techniques, namely nano-XRF and NanoSIMS, that can be used to analyze recovered samples synthetized in a LH-DAC. With these techniques, it is possible to extract the spatial distribution of chemical elements in the samples. We show the results for several standards and discuss the importance of proper calibration for the acquisition of quantifiable results. We used these two nanoprobe techniques to retrieve elemental ratios of dilute species (few tens of ppm) in quenched experimental molten samples relevant for the formation of the iron-rich core of the Earth. We finally discuss the applications of such probes to constrain the partitioning of trace elements between metal and silicate phases, with a focus on moderately siderophile elements, tungsten and molybdenum. KW - NanoSIMS KW - Nano-XRF KW - Diamond anvil cell KW - Focused ion beam Y1 - 2022 U6 - https://doi.org/10.1007/s00269-022-01193-7 SN - 0342-1791 SN - 1432-2021 VL - 49 IS - 6 PB - Springer CY - New York ER -