TY  - JOUR
A1  - Yuan, Jiayin
A1  - ten Brummelhuis, Niels
A1  - Junginger, Mathias
A1  - Xie, Zailai
A1  - Lu, Yan
A1  - Taubert, Andreas
A1  - Schlaad, Helmut
T1  - Diversified applications of chemically modified 1,2-Polybutadiene
JF  - Macromolecular rapid communications
N2  - Commercially available 1,2-PB was transformed into a well-defined reactive intermediate by quantitative bromination. The brominated polymer was used as a polyfunctional macroinitiator for the cationic ring-opening polymerization of 2-ethyl-2-oxazoline to yield a water-soluble brush polymer. Nucleophilic substitution of bromide by 1-methyl imidazole resulted in the formation of polyelectrolyte copolymers consisting of mixed units of imidazolium, bromo, and double bond. These copolymers, which were soluble in water without forming aggregates, were used as stabilizers in the heterophase polymerization of styrene and were also studied for their ionic conducting properties.
KW  - emulsion polymerization
KW  - polybutadiene
KW  - polyelectrolytes
KW  - polymer modification
KW  - ring-opening polymerization
Y1  - 2011
U6  - https://doi.org/10.1002/marc.201100254
SN  - 1022-1336
VL  - 32
IS  - 15
SP  - 1157
EP  - 1162
PB  - Wiley-Blackwell
CY  - Malden
ER  -