TY  - JOUR
A1  - Vaskova, Zuzana
A1  - Kitanovski, Nives
A1  - Jaglicic, Zvonko
A1  - Strauch, Peter
A1  - Ruzickova, Zdenka
A1  - Valigura, Dusan
A1  - Koman, Marian
A1  - Kozlevcar, Bojan
A1  - Moncol, Jan
T1  - Synthesis and magneto-structural characterization of copper(II) nitrobenzoate complexes containing nicotinamide or methylnicotinamide ligands
JF  - Polyhedron : the international journal of inorganic and organometallic chemistry
N2  - Three new copper(II) 4-nitrobenzoato coordination compounds (4-NO(2)bz(-) = 4-nitrobenzoate anions) with N-methylnicotinamide (mna) [Cu(4-NO(2)bz)(2)(mna)(2)(H2O)] (1), [Cu(4-NO(2)bz)(2)(mu-mna)(H2O)](2) (2) and [Cu(mu-4-NO(2)bz)(2)(mna)](2) (3) were synthesized and characterized. Due to a comparison, additional two related compounds [Cu(3,5-(NO2)(2)bz)(2)(mna)(2)(H2O)] (4) (nia = nicotinamide, 3,5-(NO2)(2)bz(-) = 3,5-dinitrobenzoate anions) and [Cu(mu-2-NO(2)bz)(2)(mna)](2) (5) (2-NO(2)bz(-) = 2-nitrobenzoate anions) were isolated. The mononuclear compounds with mna 1 and nia 4 show CuO2N2O chromophores with the water molecule placed at the apex of the square pyramid. The square-pyramidal coordination sphere CuO3NO in 2 differs to CuO2N2O in 1 and 4. Differently, the water molecule is in 2 at the basal-plane, while two mna molecules serve also as bridges via N-py and 0-amido enabling a dinuclear molecular structure 1, 2 and 4 are paramagnetic though a dinuclear structure is seen in 2, while a clear-cut strong antiferromagnetic (AFM) coupling (2J -300 cm(-1)) is found for the compounds 3 and 5. (C) 2014 Elsevier Ltd. All rights reserved.
KW  - Copper(II)
KW  - Nicotinamide
KW  - N-methylnicotinamide
KW  - Crystal structure
KW  - Magnetic properties
Y1  - 2014
U6  - https://doi.org/10.1016/j.poly.2014.07.017
SN  - 0277-5387
VL  - 81
SP  - 555
EP  - 563
PB  - Elsevier
CY  - Oxford
ER  -