TY  - JOUR
A1  - Albrecht, Steve
A1  - Schindler, Wolfram
A1  - Kurpiers, Jona
A1  - Kniepert, Juliane
A1  - Blakesley, James C.
A1  - Dumsch, Ines
A1  - Allard, Sybille
A1  - Fostiropoulos, Konstantinos
A1  - Scherf, Ullrich
A1  - Neher, Dieter
T1  - On the field dependence of free charge carrier generation and recombination in blends of PCPDTBT/PC70BM influence of solvent additives
JF  - The journal of physical chemistry letters
N2  - We have applied time-delayed collection field (TDCF) and charge extraction by linearly increasing voltage (CELIV) to investigate the photogeneration, transport, and recombination of charge carriers in blends composed of PCPDTBT/PC70BM processed with and without the solvent additive diiodooctane. The results suggest that the solvent additive has severe impacts on the elementary processes involved in the photon to collected electron conversion in these blends. First, a pronounced field dependence of the free carrier generation is found for both blends, where the field dependence is stronger without the additive. Second, the fate of charge carriers in both blends can be described with a rather high bimolecular recombination coefficients, which increase with decreasing internal field. Third, the mobility is three to four times higher with the additive. Both blends show a negative field dependence of mobility, which we suggest to cause bias-dependent recombination coefficients.
Y1  - 2012
U6  - https://doi.org/10.1021/jz3000849
SN  - 1948-7185
VL  - 3
IS  - 5
SP  - 640
EP  - 645
PB  - American Chemical Society
CY  - Washington
ER  -