TY - JOUR A1 - Lepetit, Petra A1 - Viereck, Lothar A1 - Piper, John D. A. A1 - Sudo, Masafumi A1 - Gurel, Ali A1 - Copuroglu, Ibrahim A1 - Gruber, Manuela A1 - Mayer, Bernhard A1 - Koch, Michael A1 - Tatar, Orhan A1 - Gursoy, Halil T1 - Ar-40/Ar-39 dating of ignimbrites and plinian air-fall layers from Cappadocia, Central Turkey: Implications to chronostratigraphic and Eastern Mediterranean palaeoenvironmental record JF - Chemie der Erde : interdisciplinary journal for chemical problems of the geo-sciences and geo-ecology N2 - Magmatism forming the Central Anatolian Volcanic Province of Cappadocia, central Turkey, records the last phase of Neotethyan subduction after similar to 11 Ma. Thirteen large calc-alkaline ignimbrite sheets form marker bands within the volcano-sedimentary succession (the Urgup Formation) and provide a robust chronostratigraphy for paleoecologic evaluation of the interleaved paleosols. This paper evaluates the chronologic record in the context of the radiometric, magnetostratigraphic and lithostratigraphic controls. Previous inconsistencies relating primarily to K/Ar evidence were reason for the initiation of an integrated study which includes Ar-40/Ar-39 dating, palaeomagnetic and stratigraphic evidence. The newly determined Ar-40/Ar-39-ages (Lepetit, 2010) are in agreement with Ar/Ar and U/Pb data meanwhile published by Pauquette and Le Pennec (2012) and Aydar et al. (2012). The Ar-40/Ar-39-ages restrict the end of the Urgup Formation to the late Miocene. The paleosol sequence enclosed by the ignimbrites is thus restricted to the late Miocene, the most intense formation of pedogene calcretes correlating with the Messinian Salinity Crisis. KW - Ar-40/Ar-39 dating KW - Tephrostratigraphy KW - Neogene KW - Cappadocia KW - Turkey Y1 - 2014 U6 - https://doi.org/10.1016/j.chemer.2014.05.001 SN - 0009-2819 SN - 1611-5864 VL - 74 IS - 3 SP - 471 EP - 488 PB - Elsevier CY - Jena ER - TY - JOUR A1 - Halama, Ralf A1 - Konrad-Schmolke, Matthias A1 - Sudo, Masafumi A1 - Marschall, Horst R. A1 - Wiedenbeck, Michael T1 - Effects of fluid-rock interaction on Ar-40/Ar-39 geochronology in high-pressure rocks (Sesia-Lanzo Zone, Western Alps) JF - Geochimica et cosmochimica acta : journal of the Geochemical Society and the Meteoritical Society N2 - In situ UV laser spot Ar-40/Ar-39 analyses of distinct phengite types in eclogite-facies rocks from the Sesia-Lanzo Zone (Western Alps, Italy) were combined with SIMS boron isotope analyses as well as boron (B) and lithium (Li) concentration data to link geochronological information with constraints on fluid-rock interaction. In weakly deformed samples, apparent Ar-40/Ar-39 ages of phengite cores span a range of similar to 20 Ma, but inverse isochrons define two distinct main high-pressure (HP) phengite core crystallization periods of 88-82 and 77-74 Ma, respectively. The younger cores have on average lower B contents (similar to 36 mu g/g) than the older ones (similar to 43-48 mu g/g), suggesting that loss of B and resetting of the Ar isotopic system were related. Phengite cores have variable delta B-11 values (-18 parts per thousand to -10 parts per thousand), indicating the lack of km scale B homogenization during HP crystallization. Overprinted phengite rims in the weakly deformed samples generally yield younger apparent Ar-40/Ar-39 ages than the respective cores. They also show variable effects of heterogeneous excess 40 Ar incorporation and Ar loss. One acceptable inverse isochron age of 77.1 +/- 1.1 Ma for rims surrounding older cores (82.6 +/- 0.6 Ma) overlaps with the second period of core crystallization. Compared to the phengite cores, all rims have lower B and Li abundances but similar delta B-11 values (-15 parts per thousand to -9 parts per thousand), reflecting internal redistribution of B and Li and internal fluid buffering of the B isotopic composition during rim growth. The combined observation of younger Ar-40/Ar-39 ages and boron loss, yielding comparable values of both parameters only in cores and rims of different samples, is best explained by a selective metasomatic overprint. In low permeability samples, this overprint caused recrystallization of phengite rims, whereas higher permeability in other samples led to complete recrystallization of phengite grains. Strongly deformed samples from a several km long, blueschist-facies shear zone contain mylonitic phengite that forms a tightly clustered group of relatively young apparent Ar-40/Ar-39 ages (64.7-68.8 Ma), yielding an inverse isochron age of 65.0 +/- 3.0 Ma. Almost complete B and Li removal in mylonitic phengite is due to leaching into a fluid. The B isotopic composition is significantly heavier than in phengites from the weakly deformed samples, indicating an external control by a high-delta B-11 fluid (delta B-11 = + 7 +/- 4 parts per thousand). We interpret this result as reflecting phengite recrystallization related to deformation and associated fluid flow in the shear zone. This event also caused partial resetting of the Ar isotope system and further B loss in more permeable rocks of the adjacent unit. We conclude that geochemical evidence for pervasive or limited fluid flow is crucial for the interpretation of Ar-40/Ar-39 data in partially metasomatized rocks. Y1 - 2014 U6 - https://doi.org/10.1016/j.gca.2013.10.023 SN - 0016-7037 SN - 1872-9533 VL - 126 SP - 475 EP - 494 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Pingel, Heiko A1 - Alonso, Ricardo N. A1 - Mulch, Andreas A1 - Rohrmann, Alexander A1 - Sudo, Masafumi A1 - Strecker, Manfred T1 - Pliocene orographic barrier uplift in the southern Central Andes JF - Geology N2 - Sedimentary basin fills along the windward flanks of orogenic plateaus are valuable archives of paleoenvironmental change with the potential to resolve the history of surface uplift and orographic barrier formation. The intermontane basins of the southern Central Andes contain thick successions of sedimentary material that are commonly interbedded with datable volcanic ashes. We relate variations in the hydrogen isotopic composition of hydrated volcanic glass (delta D-g) of Neogene to Quaternary fills in the semiarid intermontane Humahuaca Basin (Eastern Cordillera, northwest Argentina) to spatiotemporal changes in topography and associated orographic effects. delta D values from volcanic glass in the basin strata (-117 parts per thousand to -98 parts per thousand) show two main trends that accompany observed tectonosedimentary events in the study area. Between 6.0 and 3.5 Ma, delta D-g values decrease by similar to 17 parts per thousand; this is associated with surface uplift in the catchment area. After 3.5 Ma, delta D-g values show abrupt deuterium enrichment, which we associate with (1) the attainment of threshold elevations for blocking moisture transport in the basin-bounding ranges to the east, and (2) the onset of semiarid conditions in the basin. Such orographic barriers throughout the eastern flanks of the Central Andes have impeded moisture transport into the orogen interior; this has likely helped maintain aridity and internal drainage conditions on the adjacent Andean Plateau. Y1 - 2014 U6 - https://doi.org/10.1130/G35538.1 SN - 0091-7613 SN - 1943-2682 VL - 42 IS - 8 SP - 691 EP - 694 PB - American Institute of Physics CY - Boulder ER - TY - JOUR A1 - Montero-Lopez, Carolina A1 - Strecker, Manfred A1 - Schildgen, Taylor F. A1 - Hongn, Fernando D. A1 - Guzman, Silvina A1 - Bookhagen, Bodo A1 - Sudo, Masafumi T1 - Local high relief at the southern margin of the Andean plateau by 9 Ma: evidence from ignimbritic valley fills and river incision JF - Terra nova N2 - A valley-filling ignimbrite re-exposed through subsequent river incision at the southern margin of the Andean (Puna) plateau preserves pristine geological evidence of pre-late Miocene palaeotopography in the north western Argentine Andes. Our new Ar-40/(39) Ar dating of the Las Papas Ignimbrites yields a plateau age of 9.24 +/- 0.03 Ma, indicating valley-relief and orographic-barrier conditions comparable to the present-day. A later infill of Plio-Pleistocene coarse conglomerates has been linked to wetter conditions, but resulted in no additional net incision of the Las Papas valley, considering that the base of the ignimbrite remains unexposed in the valley bottom. Our observations indicate that at least 550 m of local plateau margin relief (and likely > 2 km) existed by 9 Ma at the southern Puna margin, which likely aided the efficiency of the orographic barrier to rainfall along the eastern and south eastern flanks of the Puna and causes aridity in the plateau interior. Y1 - 2014 U6 - https://doi.org/10.1111/ter.12120 SN - 0954-4879 SN - 1365-3121 VL - 26 IS - 6 SP - 454 EP - 460 PB - Wiley-Blackwell CY - Hoboken ER -