TY - JOUR A1 - Anoop, Ambili A1 - Prasad, Sushma A1 - Krishnan, R. A1 - Naumann, Rudolf A1 - Dulski, Peter T1 - Intensified monsoon and spatiotemporal changes in precipitation patterns in the NW Himalaya during the early-mid holocene JF - Quaternary international : the journal of the International Union for Quaternary Research N2 - We have undertaken a high resolution palaeoclimate reconstruction on radiocarbon dated palaeolake sediments from the Spiti valley, NW Himalaya. This site lies in the climatically sensitive winter westerlies and Indian Summer Monsoon (ISM) transitional regime and provides an opportunity to reconstruct the precipitation seasonality, and extreme precipitation events that are characterised by intensified erosion. The lake sediments reveal distinct lithofacies that provide evidence of changes in depositional environment and climate during early to mid Holocene (8.7-6.1 cal ka BP). We have identified three stages during the period of lake's existence: the Stage I (8.7-7.6 cal ka BP) is marked by lake establishment; Stage II (similar to 7.6-6.8 cal ka BP) by sustained cooler periods and weakened summer monsoon, and Stage III (similar to 6.8-6.1 cal ka BP) by a shift from colder to warmer climate with stronger ISM. We have identified several short term cooler periods at ca. 8.7, 8.5, 8.3 and 7.2-6.9 cal ka BP. Based on an overview of regional climate records we show that there is an abrupt switch in precipitation seasonality ca. 6.8 cal ka BP that is followed by the onset of the intensified monsoon in the NW Himalaya. (C) 2013 Elsevier Ltd and INQUA. All rights reserved. Y1 - 2013 U6 - https://doi.org/10.1016/j.quaint.2013.08.014 SN - 1040-6182 VL - 313 SP - 74 EP - 84 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Mishra, Praveen Kumar A1 - Anoop, Ambili A1 - Schettler, Georg A1 - Prasad, Sushma A1 - Jehangir, Arshid A1 - Menzel, Peter A1 - Naumann, Rudolf A1 - Yousuf, A. R. A1 - Basavaiah, Nathani A1 - Deenadayalan, Kannan A1 - Wiesner, Martin G. A1 - Gaye, Birgit T1 - Reconstructed late Quaternary hydrological changes from Lake Tso Moriri, NW Himalaya JF - Quaternary international : the journal of the International Union for Quaternary Research N2 - We present the results of our investigations on the radiocarbon dated core sediments from the Lake Tso Moriri, NW Himalaya aimed at reconstructing palaeohydrological changes in this climatically sensitive region. Based on the detailed geochemical, mineralogical and sedimentological analysis, we recognise several short-term fluctuations superimposed upon seven major palaeohydrological stages identified in this lake since similar to 26 cal ka. Stage I (>20.2 cal ka): shallow lake characterised by input of coarse-grained detrital sediments; Stage II (20.2-16.4 cal ka): lake deepening and intensification of this trend ca. 18 cal ka; Stage III (16.4-11.2 cal ka): rising lake levels with a short term wet phase (13.1-11.7 cal ka); Stage IV (11.2-8.5 cal ka): early Holocene hydrological maxima and highest lake levels inferred to have resulted from early Holocene Indian monsoon intensification, as records from central Asia indicate weaker westerlies during this interval; Stage V (8.5-5.5 cal ka): mid-Holocene climate deterioration; Stage VI (5.5-2.7 cal ka): progressive lowering of lake level; Stage VII (2.7-0 cal ka): onset of modern conditions. The reconstructed hydrological variability in Lake Tso Moriri is governed by temperature changes (meltwater inflow) and monsoon precipitation (increased runoff). A regional comparison shows considerable differences with other palaeorecords from peninsular India during late Holocene. (C) 2014 Elsevier Ltd and INQUA. All rights reserved. KW - Authigenic carbonates KW - Holocene KW - Indian summer monsoon KW - Lake sediments KW - Tso Moriri Lake KW - Westerlies Y1 - 2015 U6 - https://doi.org/10.1016/j.quaint.2014.11.040 SN - 1040-6182 SN - 1873-4553 VL - 371 SP - 76 EP - 86 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Wilke, Franziska Daniela Helena A1 - Vasquez, Monica A1 - Wiersberg, Thomas A1 - Naumann, Rudolf A1 - Erzinger, Jörg T1 - On the interaction of pure and impure supercritical CO2 with rock forming minerals in saline aquifers: An experimental geochemical approach JF - Applied geochemistry : journal of the International Association of Geochemistry and Cosmochemistry N2 - The aim of this experimental study was to evaluate and compare the geochemical impact of pure and impure CO2 on rock forming minerals of possible CO2 storage reservoirs. This geochemical approach takes into account the incomplete purification of industrial captured CO2 and the related effects during injection, and provides relevant data for long-term storage simulations of this specific greenhouse gas. Batch experiments were conducted to investigate the interactions of supercritical CO2, brine and rock-forming mineral concentrates (albite, microcline, kaolinite, biotite, muscovite, calcite, dolomite and anhydrite) using a newly developed experimental setup. After up to 42 day (1000 h) experiments using pure and impure supercritical CO2 the dissolution and solution characteristics were examined by XRD, XRF, SEM and EDS for the solid, and ICP-MS and IC for the fluid reactants, respectively. Experiments with mixtures of supercritical CO2 (99.5 vol.%) and SO2 or NO2 impurities (0.5 vol.%) suggest the formation of H2SO4 and HNO3, reflected in pH values between 1 and 4 for experiments with silicates and anhydrite and between 5 and 6 for experiments with carbonates. These acids should be responsible for the general larger amount of cations dissolved from the mineral phases compared to experiments using pure CO2. For pure CO2 a pH of around 4 was obtained using silicates and anhydrite, and 7-8 for carbonates. Dissolution of carbonates was observed after both pure and impure CO2 experiments. Anhydrite was corroded by approximately 50 wt.% and gypsum precipitated during experiments with supercritical CO2 + NO2. Silicates do not exhibit visible alterations during all experiments but released an increasing amount of cations in the reaction fluid during experiments with impure CO2. Nonetheless, precipitated secondary carbonates could not be identified. Y1 - 2012 U6 - https://doi.org/10.1016/j.apgeochem.2012.04.012 SN - 0883-2927 VL - 27 IS - 8 SP - 1615 EP - 1622 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Wilke, Franziska Daniela Helena A1 - Vieth-Hillebrand, Andrea A1 - Naumann, Rudolf A1 - Erzinger, Jörg A1 - Horsfield, Brian T1 - Induced mobility of inorganic and organic solutes from black shales using water extraction: Implications for shale gas exploitation JF - Applied geochemistry : journal of the International Association of Geochemistry and Cosmochemistry N2 - The study reported here evaluates the degree to which metals, salt anions and organic compounds are released from shales by exposure to water, either in its pure form or mixed with additives commonly employed during shale gas exploitation. The experimental conditions used here were not intended to simulate the exploitation process itself, but nevertheless provided important insights into the effects additives have on solute partition behaviour under oxic to sub-oxic redox conditions. In order to investigate the mobility of major (e.g. Ca, Fe) and trace (e.g. As, Cd, Co, Mo, Pb, U) elements and selected organic compounds, we performed leaching tests with black shale samples from Bornholm, Denmark and Lower Saxony, Germany. Short-term experiments (24 h) were carried out at ambient pressure and temperatures of 100 degrees C using five different lab-made stimulation fluids. Two long-term experiments under elevated pressure and temperature conditions at 100 degrees C/100 bar were performed lasting 6 and 2 months, respectively, using a stimulation fluid containing commercially-available biocide, surfactant, friction reducer and clay stabilizer. Our results show that the amount of dissolved constituents at the end of the experiment is independent of the pH of the stimulation fluid but highly dependent on the composition of the black shale and the buffering capacity of specific components, namely pyrite and carbonates. Shales containing carbonates buffer the solution at pH 7-8. Sulphide minerals (e.g. pyrite) become oxidized and generate sulphuric acid leading to a pH of 2-3. This low pH is responsible for the overall much larger amount of cations dissolved from shales containing pyrite but little to no carbonate. The amount of elements released into the fluid is also dependent on the residence time, since as much as half of the measured 23 elements show highest concentrations within four days. Afterwards, the concentration of most of the elemental species decreased pointing to secondary precipitations. Generally, in our experiments less than 15% of each analysed element contained in the black shale was mobilised into the fluid. (C) 2015 Elsevier Ltd. All rights reserved. KW - Unconventional gas KW - Black shales KW - Stimulation fluids KW - Element mobility KW - Batch experiments Y1 - 2015 U6 - https://doi.org/10.1016/j.apgeochem.2015.07.008 SN - 0883-2927 VL - 63 SP - 158 EP - 168 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Wolff, Christian Michael A1 - Kristen-Jenny, Iris A1 - Schettler, Georg A1 - Plessen, Birgit A1 - Meyer, Hanno A1 - Dulski, Peter A1 - Naumann, Rudolf A1 - Brauer, Achim A1 - Verschuren, Dirk A1 - Haug, Gerald H. T1 - Modern seasonality in Lake Challa (Kenya/Tanzania) and its sedimentary documentation in recent lake sediments JF - Limnology and oceanography N2 - From November 2006 to January 2010, a sediment trap that was cleared monthly was deployed in Lake Challa, a deep stratified freshwater lake on the eastern slope of Mt. Kilimanjaro in southern Kenya. Geochemical data from sediment trap samples were compared with a broad range of limnological and meteorological parameters to characterize the effect of single parameters on productivity and sedimentation processes in the crater basin. During the southern hemisphere summer (November-March), when the water temperature is high and the lake is biologically productive (nondiatom algae), calcite predominated in the sediment trap samples. During the "long rain" season (March-May) a small amount of organic matter and lithogenic material caused by rainfall appeared. This was followed by the cool and windy months of the southern hemisphere winter (June-October) when diatoms were the main component, indicating a diatom bloom initiated by improvement of nutrient availability related to upwelling processes. The sediment trap data support the hypothesis that the light-dark lamination couplets, which are abundant in Lake Challa cores, reflect seasonal delivery to the sediments of diatom-rich particulates during the windy months and diatom-poor material during the wet season. However, interannual and spatial variability in upwelling and productivity patterns, as well as El Nino-Southern Oscillation (ENSO)-related rainfall and drought cycles, exert a strong influence on the magnitude and geochemical composition of particle export to the hypolimnion of Lake Challa. Y1 - 2014 U6 - https://doi.org/10.4319/lo.2014.59.5.1621 SN - 0024-3590 SN - 1939-5590 VL - 59 IS - 5 SP - 1621 EP - 1636 PB - Wiley CY - Waco ER -