TY - JOUR A1 - Sieber, Melanie Jutta A1 - Yaxley, Gregory M. A1 - Hermann, Jörg T1 - Investigation of fluid-driven carbonation of a hydrated, forearc mantle wedge using serpentinite cores in high-pressure experiments JF - Journal of petrology N2 - High-pressure experiments were performed to investigate the effectiveness, rate and mechanism of carbonation of serpentinites by a carbon-saturated COH fluid at 1.5-2.5 GPa and 375-700 degrees C. This allows a better understanding of the fate and redistribution of slab-derived carbonic fluids when they react with the partially hydrated mantle within and above the subducting slab under pressure and temperature conditions corresponding to the forearc mantle. Interactions between carbon-saturated CO2-H2O-CH4 fluids and serpentinite were investigated using natural serpentinite cylinders with natural grain sizes and shapes in piston-cylinder experiments. The volatile composition of post-run fluids was quantified by gas chromatography. Solid phases were examined by Raman spectroscopy, electron microscopy and laser ablation inductively coupled plasma mass spectrometry. Textures, porosity and phase abundances of recovered rock cores were visualized and quantified by three-dimensional, high-resolution computed tomography. We find that carbonation of serpentinites is efficient at sequestering CO2 from the interacting fluid into newly formed magnesite. Time-series experiments demonstrate that carbonation is completed within similar to 96 h at 2 GPa and 600 degrees C. With decreasing CO2, aq antigorite is replaced first by magnesite + quartz followed by magnesite + talc + chlorite in distinct, metasomatic fronts. Above antigorite stability magnesite + enstatite + talc + chlorite occur additionally. The formation of fluid-permeable reaction zones enhances the reaction rate and efficiency of carbonation. Carbonation probably occurs via an interface-coupled replacement process, whereby interconnected porosity is present within reaction zones after the experiment. Consequently, carbonation of serpentinites is self-promoting and efficient even if fluid flow is channelized into veins. We conclude that significant amounts of carbonates may accumulate, over time, in the hydrated forearc mantle. KW - serpentinite carbonation KW - deep carbon cycle KW - COH fluid KW - forearc KW - CO2 KW - sequestration Y1 - 2020 U6 - https://doi.org/10.1093/petrology/egaa035 SN - 0022-3530 SN - 1460-2415 VL - 61 IS - 3 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Liu, Qi A1 - Adler, Karsten A1 - Lipus, Daniel A1 - Kämpf, Horst A1 - Bussert, Robert A1 - Plessen, Birgit A1 - Schulz, Hans-Martin A1 - Krauze, Patryk A1 - Horn, Fabian A1 - Wagner, Dirk A1 - Mangelsdorf, Kai A1 - Alawi, Mashal T1 - Microbial signatures in deep CO2-saturated miocene sediments of the active Hartousov mofette system (NW Czech Republic) JF - Frontiers in microbiology N2 - The Hartousov mofette system is a natural CO2 degassing site in the central Cheb Basin (Eger Rift, Central Europe). In early 2016 a 108 m deep core was obtained from this system to investigate the impact of ascending mantle-derived CO2 on indigenous deep microbial communities and their surrounding life habitat. During drilling, a CO2 blow out occurred at a depth of 78.5 meter below surface (mbs) suggesting a CO2 reservoir associated with a deep low-permeable CO2-saturated saline aquifer at the transition from Early Miocene terrestrial to lacustrine sediments. Past microbial communities were investigated by hopanoids and glycerol dialkyl glycerol tetraethers (GDGTs) reflecting the environmental conditions during the time of deposition rather than showing a signal of the current deep biosphere. The composition and distribution of the deep microbial community potentially stimulated by the upward migration of CO2 starting during Mid Pleistocene time was investigated by intact polar lipids (IPLs), quantitative polymerase chain reaction (qPCR), and deoxyribonucleic acid (DNA) analysis. The deep biosphere is characterized by microorganisms that are linked to the distribution and migration of the ascending CO2-saturated groundwater and the availability of organic matter instead of being linked to single lithological units of the investigated rock profile. Our findings revealed high relative abundances of common soil and water bacteria, in particular the facultative, anaerobic and potential iron-oxidizing Acidovorax and other members of the family Comamonadaceae across the whole recovered core. The results also highlighted the frequent detection of the putative sulfate-oxidizing and CO2-fixating genus Sulfuricurvum at certain depths. A set of new IPLs are suggested to be indicative for microorganisms associated to CO2 accumulation in the mofette system. KW - geo-bio interaction KW - CO2 KW - mofette systems KW - Eger Rift KW - microbial lipid KW - biomarker KW - microbial diversity KW - deep biosphere KW - saline groundwater Y1 - 2020 U6 - https://doi.org/10.3389/fmicb.2020.543260 SN - 1664-302X VL - 11 PB - Frontiers Media CY - Lausanne ER - TY - GEN A1 - Lara, Mark J. A1 - Nitze, Ingmar A1 - Grosse, Guido A1 - Martin, Philip A1 - McGuire, A. David T1 - Reduced arctic tundra productivity linked with landform and climate change interactions T2 - Postprints der Universität Potsdam Mathematisch-Naturwissenschaftliche Reihe N2 - Arctic tundra ecosystems have experienced unprecedented change associated with climate warming over recent decades. Across the Pan-Arctic, vegetation productivity and surface greenness have trended positively over the period of satellite observation. However, since 2011 these trends have slowed considerably, showing signs of browning in many regions. It is unclear what factors are driving this change and which regions/landforms will be most sensitive to future browning. Here we provide evidence linking decadal patterns in arctic greening and browning with regional climate change and local permafrost-driven landscape heterogeneity. We analyzed the spatial variability of decadal-scale trends in surface greenness across the Arctic Coastal Plain of northern Alaska (similar to 60,000 km(2)) using the Landsat archive (1999-2014), in combination with novel 30 m classifications of polygonal tundra and regional watersheds, finding landscape heterogeneity and regional climate change to be the most important factors controlling historical greenness trends. Browning was linked to increased temperature and precipitation, with the exception of young landforms (developed following lake drainage), which will likely continue to green. Spatiotemporal model forecasting suggests carbon uptake potential to be reduced in response to warmer and/or wetter climatic conditions, potentially increasing the net loss of carbon to the atmosphere, at a greater degree than previously expected. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 550 KW - winter warming events KW - permafrost KW - Alaska KW - trends KW - ice KW - CO2 KW - degradation KW - landscapes KW - ecosystem KW - exchange Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-423132 SN - 1866-8372 IS - 550 ER - TY - GEN A1 - Langerwisch, Fanny A1 - Walz, Ariane A1 - Rammig, Anja A1 - Tietjen, Britta A1 - Thonicke, Kirsten A1 - Cramer, Wolfgang T1 - Deforestation in Amazonia impacts riverine carbon dynamics T2 - Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe N2 - Fluxes of organic and inorganic carbon within the Amazon basin are considerably controlled by annual flooding, which triggers the export of terrigenous organic material to the river and ultimately to the Atlantic Ocean. The amount of carbon imported to the river and the further conversion, transport and export of it depend on temperature, atmospheric CO2, terrestrial productivity and carbon storage, as well as discharge. Both terrestrial productivity and discharge are influenced by climate and land use change. The coupled LPJmL and RivCM model system (Langerwisch et al., 2016) has been applied to assess the combined impacts of climate and land use change on the Amazon riverine carbon dynamics. Vegetation dynamics (in LPJmL) as well as export and conversion of terrigenous carbon to and within the river (RivCM) are included. The model system has been applied for the years 1901 to 2099 under two deforestation scenarios and with climate forcing of three SRES emission scenarios, each for five climate models. We find that high deforestation (business-as-usual scenario) will strongly decrease (locally by up to 90 %) riverine particulate and dissolved organic carbon amount until the end of the current century. At the same time, increase in discharge leaves net carbon transport during the first decades of the century roughly unchanged only if a sufficient area is still forested. After 2050 the amount of transported carbon will decrease drastically. In contrast to that, increased temperature and atmospheric CO2 concentration determine the amount of riverine inorganic carbon stored in the Amazon basin. Higher atmospheric CO2 concentrations increase riverine inorganic carbon amount by up to 20% (SRES A2). The changes in riverine carbon fluxes have direct effects on carbon export, either to the atmosphere via outgassing or to the Atlantic Ocean via discharge. The outgassed carbon will increase slightly in the Amazon basin, but can be regionally reduced by up to 60% due to deforestation. The discharge of organic carbon to the ocean will be reduced by about 40% under the most severe deforestation and climate change scenario. These changes would have local and regional consequences on the carbon balance and habitat characteristics in the Amazon basin itself as well as in the adjacent Atlantic Ocean. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 535 KW - Global vegetation model KW - Climate-Change KW - Brazilian Amazon KW - organic-matter KW - land-use KW - secondary forests KW - seed dispersal KW - Atlantic-Ocean KW - basin KW - CO2 Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-410225 SN - 1866-8372 IS - 535 ER - TY - GEN A1 - Langerwisch, F. A1 - Walz, Ariane A1 - Rammig, A. A1 - Tietjen, B. A1 - Thonicke, Kirsten A1 - Cramer, Wolfgang T1 - Climate change increases riverine carbon outgassing, while export to the ocean remains uncertain T2 - Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe N2 - Any regular interaction of land and river during flooding affects carbon pools within the terrestrial system, riverine carbon and carbon exported from the system. In the Amazon basin carbon fluxes are considerably influenced by annual flooding, during which terrigenous organic material is imported to the river. The Amazon basin therefore represents an excellent example of a tightly coupled terrestrial-riverine system. The processes of generation, conversion and transport of organic carbon in such a coupled terrigenous-riverine system strongly interact and are climate-sensitive, yet their functioning is rarely considered in Earth system models and their response to climate change is still largely unknown. To quantify regional and global carbon budgets and climate change effects on carbon pools and carbon fluxes, it is important to account for the coupling between the land, the river, the ocean and the atmosphere. We developed the RIVerine Carbon Model (RivCM), which is directly coupled to the well-established dynamic vegetation and hydrology model LPJmL, in order to account for this large-scale coupling. We evaluate RivCM with observational data and show that some of the values are reproduced quite well by the model, while we see large deviations for other variables. This is mainly caused by some simplifications we assumed. Our evaluation shows that it is possible to reproduce large-scale carbon transport across a river system but that this involves large uncertainties. Acknowledging these uncertainties, we estimate the potential changes in riverine carbon by applying RivCM for climate forcing from five climate models and three CO2 emission scenarios (Special Report on Emissions Scenarios, SRES). We find that climate change causes a doubling of riverine organic carbon in the southern and western basin while reducing it by 20% in the eastern and northern parts. In contrast, the amount of riverine inorganic carbon shows a 2- to 3-fold increase in the entire basin, independent of the SRES scenario. The export of carbon to the atmosphere increases as well, with an average of about 30 %. In contrast, changes in future export of organic carbon to the Atlantic Ocean depend on the SRES scenario and are projected to either decrease by about 8.9% (SRES A1B) or increase by about 9.1% (SRES A2). Such changes in the terrigenous-riverine system could have local and regional impacts on the carbon budget of the whole Amazon basin and parts of the Atlantic Ocean. Changes in riverine carbon could lead to a shift in the riverine nutrient supply and pH, while changes in the exported carbon to the ocean lead to changes in the supply of organic material that acts as a food source in the Atlantic. On larger scales the increased outgassing of CO2 could turn the Amazon basin from a sink of carbon to a considerable source. Therefore, we propose that the coupling of terrestrial and riverine carbon budgets should be included in subsequent analysis of the future regional carbon budget. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 526 KW - global vegetation model KW - Amazon-River KW - organic-matter KW - seed dispersal KW - Atlantic-Ocean KW - water-balance KW - forest KW - CO2 KW - wetlands KW - system Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-410177 SN - 1866-8372 IS - 526 ER - TY - JOUR A1 - Holl, Frank T1 - Alexander von Humboldt und der Klimawandel BT - Mythen und Fakten JF - HiN : Alexander von Humboldt im Netz ; international review for Humboldtian studies N2 - Hat Alexander von Humboldt vor den dramatischen Folgen des vom Menschen verursachten Klimawandels gewarnt? Ausgehend von dieser Frage befasst sich der Beitrag mit seinen Klimastudien und zeigt dabei, welch enorme Wirkung diese für viele Länder der Welt hatten. Zahlreiche Aufforstungsmaßnahmen wurden im 19. Jahrhundert durch Humboldts Studien angeregt. Humboldt hat zudem – wohl als erster – die klimaverändernde Wirkung von „großen Dampf- und Gasmassen an den Mittelpunkten der Industrie“ erkannt und außerdem im 3. Band des Kosmos auch den Treibhauseffekt beschrieben. Die Bedrohungen des stetig zunehmenden anthropogenen Klimawandels jedoch konnte er nicht ahnen. Seine und auch die Erkenntnisse der anderen Klimaforscher des 19. Jhds. gerieten Anfang des 20. Jhds. in Vergessenheit. Der gerissene Rezeptionsfaden wurde erst mit der Umweltbewegung in den 1970er Jahren wieder aufgenommen und Alexander von Humboldt als Klimaforscher und „erster Ökologe“ neu bewertet. N2 - Did Alexander von Humboldt warn about the dramatic consequences of man-made climate change? Based on this question, the article deals with his climate studies and shows the enormous impact this had for many countries in the world. Numerous afforestation attempts were initiated in the 19th century by Humboldt's studies. In addition, Humboldt was the first to recognize the climate-changing effect of "large vapor and gas masses at the centers of industry", and also described the greenhouse effect in Volume 3 of the Cosmos. However, he could not foresee the threats of increasing anthropogenic climate change. His and also the findings of the other climate researchers of the 19th century fell into oblivion at the beginning of the 20th century. The ripped reception thread was then resumed with the environmental movement in the 1970s and Alexander von Humboldt was reassessed as climate researcher and "first ecologist". N2 - ¿Advirtió Alexander von Humboldt sobre las dramáticas consecuencias del cambio climático provocado por el hombre? Con base en esta pregunta, el artículo trata sobre sus estudios climáticos y muestra el enorme impacto que esto tuvo en muchos países del mundo. Numerosas medidas de forestación se iniciaron en el siglo XIX gracias a los estudios de Humboldt. Además, Humboldt fue el primero en reconocer el efecto de cambio climático de las „grandes masas de vapor y gas en los centros de la industria“, y también describió el efecto invernadero en el Volumen 3 de su obra Cosmos. Sin embargo, él no podía prever las amenazas de un cambio climático antropogénico. Sus hallazgos y los de otros investigadores sobre el clima en el siglo XIX cayeron en el olvido a principios del siglo XX. El hilo roto de la recepción se reanudó con el movimiento ecologista en la década de 1970 y Alexander von Humboldt fue reevaluado como investigador del clima y „primer ecólogo“. KW - Nachhaltigkeit KW - Klimawandel KW - Klimafaktoren KW - Waldrodung KW - Abholzung KW - Wasserhaushalt KW - Valencia-See KW - Klimastudien KW - Treibhauseffekt KW - Treibhausgase KW - CO2 KW - Erderwärmung KW - Wiederaufforstung KW - Temperaturanstieg KW - Umweltschutz KW - Naturschutz Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-434441 SN - 1617-5239 SN - 2568-3543 VL - XIX IS - 37 SP - 37 EP - 56 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - GEN A1 - Hoffmann, Mathias A1 - Schulz-Hanke, Maximilian A1 - Alba, Juana Garcia A1 - Jurisch, Nicole A1 - Hagemann, Ulrike A1 - Sachs, Torsten A1 - Sommer, Michael A1 - Augustin, Jürgen T1 - A simple calculation algorithm to separate high-resolution CH4 flux measurements into ebullition- and diffusion-derived components T2 - Postprints der Universität Potsdam : Mathematisch Naturwissenschaftliche Reihe N2 - Processes driving the production, transformation and transport of methane (CH4) in wetland ecosystems are highly complex. We present a simple calculation algorithm to separate open-water CH4 fluxes measured with automatic chambers into diffusion- and ebullition-derived components. This helps to reveal underlying dynamics, to identify potential environmental drivers and, thus, to calculate reliable CH4 emission estimates. The flux separation is based on identification of ebullition-related sudden concentration changes during single measurements. Therefore, a variable ebullition filter is applied, using the lower and upper quartile and the interquartile range (IQR). Automation of data processing is achieved by using an established R script, adjusted for the purpose of CH4 flux calculation. The algorithm was validated by performing a laboratory experiment and tested using flux measurement data (July to September 2013) from a former fen grassland site, which converted into a shallow lake as a result of rewetting. Ebullition and diffusion contributed equally (46 and 55 %) to total CH4 emissions, which is comparable to ratios given in the literature. Moreover, the separation algorithm revealed a concealed shift in the diurnal trend of diffusive fluxes throughout the measurement period. The water temperature gradient was identified as one of the major drivers of diffusive CH4 emissions, whereas no significant driver was found in the case of erratic CH4 ebullition events. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 604 KW - water methane emissions KW - chamber system KW - CO2 KW - lake KW - fen KW - exchange KW - mechanism KW - turbulence KW - transport KW - reservior Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-416659 SN - 1866-8372 IS - 604 SP - 109 EP - 118 ER -